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Code Editor : dgweb-dg.txt
DGID Proper_Shipping_Name IMO_Class UN_Number KPA_Group DGProperties ----------- --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- 1 1,1,1, 2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) 2.2 3159 3 Non-flammable gas with a mild ether-like odour. Much heavier than air 2 1,1-DICHLORO-1-NITROETHANE 6.1 2650 3 Liquid.Immiscible with water. May react vigorously with oxidising substance. Decomposes when heated. Toxic if swallowed, by skin or dust inhalation. Causes tears 3 1,2-BUTYLENE OXIDE STABILIZED 3 3022 2 Colorless liquid. F/point: 15oC c.c. Explosive limits: 1.5% to 18.3%. React violently with acids, alkalis and oxidizers. Miscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes 5 1,2-DIMETHOXYETHANE 3 2252 2 Colorless liquid with an ethereal odour. F/point :1oC c.c. Explosive limits : 1.7% to 6.3%.Miscible with water 6 1,3-DICHLOROACETONE 6.1 2649 3 Crystals. Melting point : 45oC. Soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed,by skin contactor by dust inhalation. Causes tears 7 1,3-DICHLOROPROPANOL-2 6.1 2750 2 Colorless, slightly viscous liquid with a chloroform-like odour. Immiscible with water. Decomposes when heated, evolving extremely toxic fumes(phosgene). Toxic if swallowed, by skin contact or by inhalation 8 1,5,9-CYCLODODECATRIENE 6.1 2518 3 Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. 9 1,1,1-TRICHLOROETHANE 6.1 2831 3 Colorless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes(phosgene and hydrogen chloride). Toxic if swallowed, by skin contact or by inhalation. Narcotic in high concentrations 10 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) 2.1 2035 2 Flammable gases with a slight odor. Much heavier than air 11 1,1,2, 2 -TETRACHLOROETHANE 6.1 1702 3 Colorless liquid with a chloroform-like odor. Toxic if swallowed, by skin contact or by inhalation 12 1,1-DICHLOROETHANE 3 2362 3 Colourless liquid with an aromatic, ethereal odour. F/point: -10OC c.c. Explosive limits: 5.6% to ...Immiscible with water. When involved in a fire, emits toxic fumes of pgosgene. Harmful by inhalation 13 1,1-DIFLUOROETHANE (REFRIGARANT GAS R 152a) 2.1 1030 2 Flammable gas. Explosive limits: 5% to 17%. Much heavier than air (2.3) 14 1,1-DIFLUOROETHYLENE 2.1 1959 2 Flammable gas. Explosive limits: 2.3% to 25%. Much heavier than air. 15 1,1-DIMETHOXYETHANE 3 2377 2 Colourless liquid with a strong aromatic odour. Miscible with water 16 1,2-DICHLORO-1,1,2,2,-TETRAFLUOROETHANE 2.2 1958 3 Liquefied, non-flammable gas with a chloroform-like odor. Much heavier than air. Boiling point: 4oC 17 1,2, 3, 6 -TETRAHYDROPYRIDINE 3 2410 2 Colourless liquid. F/point :16oC c.c.Miscible with water. Harmful by inhalation 18 1,2,3,6-TETRAHYDROBENZALDEHYDE 3 2498 3 Colorless liquid.F/point:57oC o.c. Immiscible with water. 19 1,2-DI(DIMETHYLAMINO)ETHANE 3 2372 3 Colourless liquid. F/point: 21oC c.c. Miscible with water. Irritability to skin, eyes and mucous membranes 20 1,2-DICHLOROETHYLENE 3 1150 3 Colorless liquid with a chloroform-like odor. F/point: 6oC c.c.Explosive limits: 5.6% to 16%. Immiscible with water. Boiling range: 48oC to 61oC 21 1,2-DICHLOROPROPANE 3 1279 3 Colorless liquid. /point: 15oC c.c. Immiscible with water. Harmful by inhalation. Irritating to skin and eyes. 22 1,2-EPOXY-3-ETHYLOXYPROPANE 3 2752 3 Immiscible with water. F/point: 47oC c.c. Irritating to skin, eyes and mucous membranes. 23 1,3, 5-TRIMETHYLBENZENE 3 2325 3 Colorless liquid. F/point: 44oC c.c. Immiscible with water. Harmful by inhalation 24 1,3-DIMETHYLBUTYLAMINE 3 2379 2 Colourless liquid with an ammonia-like odour. F/point : 9oC c.c. tp 13oC c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Reract violently with acids. 25 1,4-BUTYNEDIOL 6.1 2716 3 White crystals. Melting point: 58oC. Soluble in water. Forms explosive mixtures with mercury salts, strong acid, alkaline compounds and halides. Toxic if swallowed, by skin contact or by inhalation 26 1-BROMO 3-METHYL BUTANE 3 2341 2 Colorless liquid. Flash point: 23oC to 32oC c.c. Immiscible with water 27 1-BROMOBUTANE 3 1126 3 Colorless to pale straw-colored, clear liquid. Flash point : 13oC c.c. Explosive limits: 2.6% to 6.6%. Immiscible with water. Narcotic 28 1-CHLORO-,1-DIFLUOROETHANES (REFRIGERANT GAS R 142b) 2.1 2517 2 Flammable gas. Explosive limits: 8.5% to 14%. Much heavier than air 29 1-BROMOPROPANE-3-CHLOROPROPANE 6.1 2688 3 Colorless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation 30 1-CHLOROPROPANE 3 1278 2 Colorless liquid with a chloroform-like odour. F/point: -18oC c.c.. Explosive limits: 2.6% to 10.5%. Boling point: 47oC. Immiscible with water 31 1-ETHYLPIPERIDINE 3 2386 2 Colourless liquid.F/point: 19oC c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. May cause lung damage. React violently with acids. 32 1-HEXENE 3 2370 2 Colorless liquid. Explosive limits: 1.2% to 6.9% . Immiscible with water 33 1-METHOXY-2-PROPANOL 3 3092 3 Colorless liquid. F/point : 29oC to 35oC c.c. Explosive limits: 1.7% to 11.5%. Miscible with water. Reacts with strong oxidizing substances. Irritating to skin, eyes and mucous membranes. 34 1-METHYLPIPERIDINE 3 2399 2 Colorless liquid. F/point: 3oC c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. React violently with acids. 35 1-PENTENE (normal-AMYLENE) 3 1108 2 Colourless, volatile liquid with a disagreeable odour. F/point: -20oC c.c. Explosive limits: 1.4% to 8.7%. Boiling point: 30oC. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations 36 1-PENTOL 8 2705 3 Colorless liquid with a perceptible odour. May react in contact with acids and alkalis. Causes burns to skin, eyes and mucous membranes 37 1H-TETRAZOLE 1.1D 0504 1 Substance. 38 2 2-DIMETHYLPROPANE 2.1 2044 2 Flammable hydrocarbon gas. Explosive limits : 1.4% to 7.2%. Heavier than air (2.48). 39 2 3-DIHYDROPYRAN 3 2376 2 Colorless, volatile liquid with an ethereal odour. F/point: -16oC c.c.Miscible with water 41 2,4-TOLUYLENEDIAMINE, SOLID 6.1 1709 3 White cystals or powder. Toxic if swallowed, by skin contact or by dust inhalation 42 2-(2-AMINOETHOXY)ETHANOL 8 3055 3 Colorless, slightly viscous liquid with a mild odour. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes 43 2,2-DICHLOROETHYL ETHER 6.1 1916 3 Colorless flammable liquid. F/point: 55oC c.c Immiscible with water, but reacts with it, forming corrosive and toxic fumes. Toxic if swallowed, by skin contact or by inhalation 44 2,3-DIMETHYLBUTANE 3 2457 2 Colorless liquid. F/point: -29oC c.c. Explosive limits: 1.2% to 7%. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations 45 2-AMINO-4 6-DINITROPHENOL, WETTED with not less than 20% water, by mass 4.1 3317 2 Desensitized explosive. Red crystals. Insoluble in water. Explosive in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes 46 2-AMINO-4-CHLOROPHENTOL 6.1 2673 3 Light brown ctystals. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation 47 2-AMINO-5-DIETHYLAMINOPENTANE 6.1 2946 3 Liquid with an acrid odour. Miscible in water. Toxic if swallowed, by skin contact or by inhalation 48 2-BROMO-2-NITROPROPANE-1 3-DIOL 4.1 3241 2 White crystals. Soluble in water. Decomposes when heated,evolving toxic gases.Sensitive to strong detonation shock. This substance. shall be packed in accordance with packing method OP6 49 2-BROMOBUTANE 3 2339 2 Colorless liquid with a pleasant odour. F/point: 21oC c.c. Immiscible with water. When involved in afire evolves toxic fumes. Narcotic 50 2-BROMOETHYL ETHYL ETHER 3 2340 2 Colorless liquid with an ethereal odour. Partially miscible with water. Harmful by inhalation 51 2-BROMOPENTANE 3 2343 2 Colorless or yellow liquid with a strong odour. F/point: 21oC c.c. Immiscible with water. Harmful by inhalation. 52 2-CHLOROETHANAL 6.1 2232 2 Clear colorless liquid with a pungent odour. Miscible with wqter. Highly toxic if swallowed, by skin contact or by inhalation 53 2-CHLOROPROPENE 3 2456 2 Colorless liquid. F/point: below -18oC c.c. Explosive limits: 2.5% to 12%. Boiling point: 23oC. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 54 2-CHLOROPROPIONIC ACID 8 2511 3 Colourless, aqueous solution with a specific odour. Causes burns to skin, eyes and mucous membranes 55 2-CHLOROPYRIDINE 6.1 2822 3 Colorless oily liquid. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation 56 2-CHLOROPROPANE 3 2356 2 Colourless liquid. F/point: -32oC c.c.Explosive limits: 2.8% to 10.7%. Boling point: 35oC. Immisciible with water. On contact with heat of flame, emits highly toxic phosgene gas. Can react vigorously with oxidizing materials. 57 2-DIETHYLAMINOETHANOL 8 2686 2 Colorless liquid. Miscible with water. Reacts violently with oxidising substances. Explosive limits: 1.8% to 28%. F/point: 46oC to 60oC c.c. Causes burns to skin, eyes and mucous membranes 58 2-DIMETHYLAMINOACETONITRILE 3 2378 2 Colourless liquid. F/point: 35oC c.c. Immiscible with water. On contact with water and acids, evolves toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 59 2-DIMETHYLAMINOETHANOL 8 2051 3 Colorless, flammable liquid with a fishy odour. F/point: 31oC o.c. Miscible with water. Causes burns to skin, eyes and mucous membranes 60 2-DIMETHYLAMINOETHYL METHACRYLATE 6.1 2522 3 Combustible liquid. Causes tears. Toxic if swallowed, by skin contact or by inhalation 61 2-DIMETHYLAMINOETHYL ACRYLATE,STABILIZED 6.1 3302 2 Colourless to light yellow liquid. Acrid odour. Miscible with water. Causes tears. Stabilized with hydroquionone derivatives. Hydrolyses in water to give off acrylic acid and dimethylaminoethanol. Toxic if swallowed, by skin contact or by inhalation. 62 2-ETHYLANILINE 6.1 2273 3 Brown liquid. Immiscible with water. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 63 2-ETHYLBUTANOL 3 2275 3 Colourless liquid. F/point: 57oC o.c Immiscible with water.. 64 2-ETHYLBUTRALDEHYDE 3 1178 2 Colorless liquid. F/point: 11oC c.c. Explosive limits: 1.2% to 7.7%. Immiscible with water. 65 2-ETHYLBUTYL ACETATE 3 1177 3 Colorless liquid. F/point: 54oC o.c. Immiscible with water. 66 2-ETHYLHEXYLAMINE 3 2276 3 Colorless liquid. F/point: 50oC c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 67 2-ETHYLHEXYL CHOROFORMATE 6.1 2748 2 A wide range of colorless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes an 68 2-IODOBUTANE 3 2390 2 Colourless liquid. Flashpoint: 21oC c.c. Immiscible with water 69 2-METHYL 1-BUTENE 3 2459 2 Colorless,volatile liquid with a disagreeable odour.F/point: below -18oC c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes 70 2-METHYL PENTAN-2-OL 3 2560 3 Colourless liquid. F/point: 30oC c.c. Partially miscible with water. Irritating to skin, eyes and mucous membranes 71 2-METHYL-2-BUTENE 3 2460 2 Colorles, volatile liquid with a disagreeable adour. F/point: below -18oC c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes 72 2-METHYL-2-HEPTANETHIOL 6.1 3023 2 Colorless flammable liquid with a foul odour. F/point: 31oC c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 73 2-METHYL-5-METHYLPYRIDINE 6.1 2300 3 Colourless liquid with a pungent odour. Toxic if swallowed, by skin contact or by inhalation 74 2-METHYLFURAN 3 2301 2 Colorless liquid with a sweetish odour. F/point: -30oC c.c. Immiscible with water. When involved in a fire, evolves toxic gases. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes 75 2-TRIFLUOROMETHYLANILINE 6.1 2942 3 Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation 76 3-(DIETHYLAMINO) -PROPYLAMINE 3 2684 3 Colorless liquid with a fishy odour.F/point: 59oC o.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 77 3,3-IMINOBISPROPYLAMINE 8 2269 3 Colourless combustible liquid. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 78 3,3-DIETHOXYPROPENE 3 2374 2 Colorless liquid. F/point : 15oC c.c. Partially miscible with water. Harmful by inhalation. 79 3-BROMOPROPYNE 3 2345 2 Colourless to light amber liquid with a sharp odour. F/point: 10oC c.c. Explosive limits: 3% to ...Vapour much heavier than air (4.1). The pure product is shock sensitive & decompose with explosive violence & the possibility of detonation,when heated under 81 3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID 6.1 2236 3 Colorless liquid with a pungent odour. Immiscible with water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation.Irritating to skin, eyes and mucous membranes 82 3-CHLOROPROPANOL-1 6.1 2849 3 Colourless to light-yellow liquid. Miscible with water. Mildly corrosive to steel. Toxic if swallowed, by skin contact or by inhalation. 83 3-METHYL-1-BUTENE 3 2561 2 Colourless, volatile liquid with a disagreeable odor. F/point: <-18oC c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes 84 3-METHYLBUTAN-2-ONE 3 2397 2 Colorless liquid. F/point: -3oC c.c. Explosive limits: 1.5% to 8%. Immiscible with water 85 3-NITRO-4-CHLOROBENZOTRIFLUORIDE 6.1 2307 3 Yellowish, oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation 86 3-TRIFLUOROMETHYLANILINE 6.1 2948 3 Colorless to yellowish liquid. Melting point: 5oC. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation 87 4 4'-DIAMINODIPHENYLMETHANE 6.1 2651 3 Tan-colored flakes or lumps. Slightly soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. 89 4-CHLORO-ortho-TOLUIDINE HYDROCHLORIDE, SOLID 6.1 1579 3 Dry solid or paste. Toxic if swallowed, by skin contact or by dust inhalation 90 4-MENTHOXY-4-METHYL PENTAN-2-ONE 3 2293 3 Colorless liquid. F/point: 49oC c.c. Immiscible with water 91 4-METHYLMORPHOLINE (N-METHYLMORPHOLINE) 3 2535 2 Colourless liquid with an ammonia-lik odour. F/point: 13oC c.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes 92 4-THIAPENTANAL 6.1 2785 3 Colorless liquid with an extremely foul and persistent odour. Miscible with water. Decomposes rapidly in contact with acids and bases. Toxic if swallowed, by skin contact or by inhalation 93 5-MERCAPTOTETRAZOL-1-ACETIC ACID 1.4C 0448 2 substances 94 5-METHYLHEXAN-2-ONE 3 2302 3 Colourless liquid. F/point: 43oC c.c. Immiscible with water 95 5-NITROBENZOTRIAZOL 1.1D 0385 1 substances 96 5-tertiary-BUTYL-2 4 6-TRINITRO-m-XYLENE (MUSK XYLENE) 4.1 2956 2 Insoluble in water. May explode if involved in a fire under confined conditions. Sensitive to strong detonation shock. Harmdul if swallowed or by skin contact 97 9-PHOSPHABICYCLONONANES 4.2 2940 2 Colorless, waxy solids. Melting point: 40oC to 60oC. React in contact with materials such as sawdust or other cellulose-based materials resulting in charring and evolution of toxic fumes. Irritating to skin, eyes and mucous membranes 98 ACETAL 3 1088 2 Colourless, volatile liquid with an agreeable odour. F/point: < -18oC c.c. Explosive limits: 1.6% to 10.4%. Miscible with water 99 ACETALDEHYDE 3 1089 2 Colorless liquid with a pungent, fruity odour. F/point: -27oC c.c. Explosive limits: 4% to 57%. Boiling point: 21oC. Miscible with water. Harmful if swallowed or by inhalation 100 ACETALDEHYDE AMMONIA 9 1841 3 White crystalline solid. Soluble in water. When heated, decomposes into ammonia and acetaldehyde 101 ACETIC ACID GLACIAL or ACETIC ACID SOLUTION more than 80% acid by mass 8 2789 2 Colorless flammable liquid with a pungent odor. When pure, crysrallizes below 16oC. F/point: 40oC c.c.(pure product), 60oC (80% solution). Explosive limits: 4 to 17%. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and 102 ACETIC ACID SOLUTION, more than 10% and less than 50% acid,by mass 8 2790 3 Colorless liquid with apungent odor. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and mucous membranes 103 ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid 8 2790 3 NULL 104 ACETIC ANHYDRIDE 8 1715 2 Colorless, flammable liquid with an irritating odour. F/point: 54oC c.c. Immiscible with water. In the presence of moisture, corrosive to most metals. Vapoor irritates mucous membranes 105 ACETONE 3 1090 2 Colourless, clear liquid, with a characteristic mint-like odour. F/point: -20oC to -18oC c.c.Explosive limits: 2.5% to 13%. Miscible with water 106 ACETONE CYANOHYDRIN STABILIZED 6.1 1541 2 Colorless to amber liquid evolving toxic vapor. Miscible with water. Unstable in contact with acids and alkalis, evolving hydrogen cyanide, a highly toxic and flamm gas. Highly toxic if swallowed, by skin contact or by inhalation 107 ACETONE OILS 3 1091 2 Light yellow to brownish, oily liquids. F/point: -4oC to 8oC c.c. Immiscible with water 108 ACETONITRILE 3 1648 2 Colorless ,volatile liquid. F/point: 2oC c.c. Explosive limits: 3% to 16%. Miscible with water. When involved in a fire, evolves toxic cyanide fumes. Harmful if swallowed, by skin contact or by inhalation 109 ACETYL BROMIDE 8 1716 2 Colorless liquid. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapor irritated mucous membranes 110 ACETYL CHLORIDE 3 1717 3 Colorless liq. F/point: 5oC c.c. Boiling point: 51oC. Reacts violently with water,evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes.In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes an 111 ACETYL IODIDE 8 1898 2 Colorless liq. Reacts violently with water, evolving hydrogen iodide, an irritating and corrosive ga apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapor irritates mucous membranes 112 ACETYL METHYL CARBINOL 3 2621 3 Yellow liquid with a pelaseant odour. F/point: 44 to 52oC c.c. Miscible with water. Reacts vigorously with oxidising substances. Irritating to skin, eyes and mucous membranes 113 ACETYLENE, DISSOLVED 2.1 1001 2 Flammable gas with slight odour. Explosive limits: 2.1% to 80%. Lighter than air (0.907). Rough handling & exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders should be carried with the same 114 ACRIDINE 6.1 2713 3 Small colorless to yellowish crystals o needles. Sublimes at 100oC. Practically insoluble in water. Toxic if swallowed, by skin contact or by inhalation 115 ACROLEIN DIMER STABILIZED 3 2607 3 Colorless liquid with a pungent odor. F/point: 48oC o.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes 116 ACROLEIN, STABILIZED 6.1 1092 2 Colourless or yellow liquid, with a most irritating odour. F/point:-26oC c.c. Explosive limits: 2.8% to 31%. Boiling point: 52oC. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation 118 ACRYLAMIDE, SOLID 6.1 2074 3 Crystals or powder. Soluble in water. May polymerise violently on melting. Toxic if swallowed, by skin contact or by inhalation 119 ACRYLIC ACID , STABILIZED 8 2218 2 Colourless, flammable liquid with an acrid odour. Melting point : 13oC. Flash point 54oC o.c Miscible with water. May polymerize violently, which may cause fire and explosion unless properly stabilized. Harmful if swallowed or by inhalation.Corrosive to sk 120 ACRYLONITRILE, STABILIZED 3 1093 2 Colourless mobile liquid with a mild pungent odour. F/point:-5'c c.c. Explosive limits: 3 to 17%. Partially Miscible with water. Toxic if swallowed,by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordin 121 ADHESIVE containing flammable liquid 3 1133 3 Adhesives are solutions of gums, resins etc., usually volatile due to the solvents. Miscibility with water depends upon their composition 122 ADIPONITRILE 6.1 2205 3 Colorless, odorless oil. Decomposes above 93oC, evolving hydrogen cyanide, a highly toxic and flamm gas. Toxic if swallowed, by skin contact or by inhalation 123 AEROSOL (maximum 1 litre) 2 1950 3 - 124 AEROSOL (above 1 litre) 2 1950 3 NULL 126 AIR BAG INFLATORS PYROTECHNIC or AIR BAG MODULES PYROTECHNIC or SEAT-BELT PRETENSIONERS PYROTECHNIC 1.4G 0503 2 Articles which contain prrotechnic substance and are used as life-saving vehicle air bags or seat-belts 127 AIR, COMPRESSED 2.2 1002 3 Non-flammable gas 128 AIR, REFRIGERATED LIQUID 2.2 1003 2 Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid air with combustible materials or oils may explode. May ignite organic materials 129 SAFETY DEVICES,electrically initiated 9 3268 3 130 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydazine) (M86 fuel) 3 3165 2 The mixture is miscible with water and may react dangerously with oxidizing substances. The mixture is highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes 131 ALCOHOL BEVERAGES with more than 70% alcohol by volume 3 3065 3 Aques solutions of ethanol produced and supplied as alcoholic beverages. Miscible with water. Flashpoint: -13'C c.c. or greater. 132 ALCOHOLS, N.O.S. 3 1987 3 NULL 133 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 1986 2 Toxic if swallowed, by skin contact or by inhalation 134 ALCOHOLATES SOLUTION, N.O.S. in alcohol 3 3274 2 Colorless solution. Reacts violently with water. Causes burns to skin, eyes and mucous membranes 135 ALDEHYDE N.O.S. 3 1989 2 NULL 136 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 1988 2 Toxic if swallowed, by skin contact or by inhalation 137 ALDOL 6.1 2839 3 Clear, colourless to yellow viscous liquid.Miscible with water. DEcomposes at 85oC, evolcing toxic fumes. May react vigorously with oxidising substances. Toxic if swallowed, by skin contact or by inhalation 138 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE N.O.S. 4.2 3206 2 Free-flowing hygroscopic powder. Cause burns to skin, eyes and mucous membranes 139 ALKALI METAL AMALGAM, LIQUID 4.3 1389 2 Silvery liquid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen,a flammable gas. When heated, evolves toxic vapors 141 ALKALI METAL AMIDE 4.3 1390 2 Small crystals. Decomposes in contact with water or acid, evolving ammonia vapor and producing highly caustic alkaline solutions 142 ALKALI METAL DISPERSIONS or ALKALINE EARTH METAL DISPERSION 4.3 1391 2 Finely divided alkali or alkaline earth metal,suspended in a flamm liq. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction 143 ALKALI METALS ALLOYS LIQUID, N.O.S. 4.3 1421 2 Flows like mercury at ordinary temperatures. Not volatile.Reacts violently with moisture, water or acids, evolving hydrogen, a flamm gas, & developing considerable heat which may ignite the gas 144 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 3205 2 Free-flowing hygroscopic powder. Irritating to skin,eyes and mucous membranes. 146 ALKALINE EARTH METAL AMALGAMS, LIQUID 4.3 1392 2 Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals and may contain up to 98% mercury.Reacts with moisture, water or acids, evolving hydrogen, a flamm gas. When heated, evolves toxic vapors 147 ALKALINE EARTH METALS ALLOYS, N.O.S. 4.3 1393 2 When containing a substantial proportion of alkaline earth metals, readily decomposed by water and reacts violently with acids, evolving hydrogen, which may be ignitedby the heat of the reaction 148 ALKALOIDS, LIQUID, N.O.S.or ALKALOID SALTS, LIQUID, N.O.S. 6.1 3140 2 A wide range of toxic liquids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation 149 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6.1 1544 2 A wide range of toxic solids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation 150 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 8 2430 2 A wide range of colorless to pale straw-colored solids with penetrating odors(sometime camphor-like). Some have low metlting points. Insoluble in water. Cause burns to skin, eyes and mucous membranes 151 ALKYLPHENOLS, LIQUID, N.O.S. (including C2 - C12 homologues) 8 3145 3 A wide range of colorless to pale straw-colored liqs with penetrating odors. Liq slightly miscible with water. Cause burns to skin, eyes and mucous membranes 152 ALKYLSULPHONIC ACIDS, LIQUID OR ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 8 2584 2 Liquids usually with a pungent odor. When involved in a fire, evolve highly toxic gases. Highly corrosive to most metals.Cause burns to skin,eyes and mucous membranes. 153 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 8 2586 3 Liquids usually with a pungent odor. When involved in a fire, evolve highly toxic gases. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes 154 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 8 2583 3 When involved in a fire, evolve highly toxic gases. Corrosive to most metals, especially in the presence of moisture. Cause burns to skin, eyes and mucous membranes 155 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID, with not more than 5% free sulphuric acid 8 2585 3 Crystalline solids. When involved in afire, evolve highly toxic gases. In the presence of moisture, corrosive to most metals. Cause burns to skin, eyes and mucous membranes 156 ALKYLSULPHURIC ACIDS 8 2571 2 Colourless oily liquids. React with water, evolving heat. Cause burns to skin, eyes and mucous membranes. Highly corrosive to metal 157 ALLYL ACETATE 3 2333 2 Colourless liquid. F/point: 7oC c.c. . Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Harmful if swallowed 158 ALLYL ALCOHOL 6.1 1098 2 Colourless liquid with a pungent mustard-like odour. F/point: 21oC c.c. Explosive limits: 2.5% to 18%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation 159 ALLYL BROMIDE 3 1099 2 Colourless to light yellow liquid with an irritating odour. F/point: -1oC c.c. Explosive limits: 4.4% to 7.3%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation 160 ALLYL CHLORIDE 3 1100 2 Colourless liquid with an unpleasant pungent odour. F/point: -29oC c.c. Explosive limits: 3.3.% to 11.1%. Boiling point: 44oC. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 161 ALLYL CHLOROFORMATE 6.1 1722 2 Colorless, flamm liq, extremely irritating odor, causes tears.F/point: 31oC c.c. When involved in a fire, evolves toxic gases. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns 162 ALLYL ETHYL ETHER 3 2335 2 Colourless liquid. F/point: -11oC c.c. Vapor heavier than air.Immiscible with water. Toxic if swallowed, by skin contact or by inhalation 163 ALLYL FORMATE 3 2336 2 Colorless liq. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation 164 ALLYL GLYCIDYL EITHER 3 2219 3 Colourless liquid. Flashpoint: 48oC c.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes 165 ALLYL IODIDE 3 1723 2 Yellow liq with an irritating odor. F/point: 5oC c.c. Immiscible with water. In the presence of moisture, corrosive to metals. Causes burns to skin, eyes and mucous membranes 166 ALLYL TRICHLOROSILANE, STABILIZED 8 1724 2 Colorless, flammable liquid with a pungent odour. F/point: 35oC c.c. Reacts violently with water, evolving hydrogen chloride, an irritating & corrosive gas, apparent as white fumes. When involved in fire, evolves toxic gases. In the presence of moisture, h 167 ALLYLAMINE 6.1 2334 2 Colourless to light yelow volatile liquid with a pungent odour.Flashpoint:-29oC c.c.Explosive limits:2.2% to 22%.Boiling range:55oC to 58oC.Miscible with water.When involved in a fire,evolves highly toxic gases.Highly toxic if swallowed,by skin contact or 168 ALLYL ISOTHIOCYANATE, STABILIZED 6.1 1545 2 Colourless liquid. evolving toxic vapor which is irritating and causes tears. F/point: 46oC c.c. Toxic if swallowed, by skin contact or by inhalation 169 alpha-METHYLBENZYL ALCOHOL, LIQUID 6.1 2937 3 Colorless liquid. Slightly miscible with water. Melting point:21oC (pure substance). Toxic if swallowed, by skin contact or by inhalation 171 alpha-METHYL-VALERALDEHYDE 3 2367 3 Colourless liquid. F/point: 13oC c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes 172 alpha-NAPHTHYLAMINE 6.1 2077 3 White crystals. Toxic if swallowed, by skin contact or by inhalation 174 alpha-PINENE 3 2368 3 Colourless liquid.with an odour of turpentine. F/point: 33oC c.c. Explosive limits: 0.8% to 6%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes 179 ALUMINIUM BOROHYDRIDE IN DEVICES 4.2 2870 2 liquid.Ignites spontanously in air. Reacts with water or steam to produce heat or hydrogen, which may form explosive mixtures with air 180 ALUMINIUM BOROHYDRIDE 4.2 2870 2 NULL 181 ALUMINIUM BROMIDE ANHYDROUS 8 1725 3 White to yellowish hygroscopic crystals. Forms corrosive vapors in moist air.Reacts violently with water, evolving heat & hydrogen bromide, an irritating & corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. 182 ALUMINIUM BROMIDE, SOLUTION 8 2580 3 Colourless to yellowish liq.Highly corrosive to most metals.Vapour highly irritating to skin, eyes and mucous membranes.Liq causes severe burns to skin, eyes and mucous membranes 183 ALUMINIUM CARBIDE 4.3 1394 2 Yellow crystals or powder.In contct with water, rapidly evolves methane, a flammable gas. Reacts violently with acids 184 ALUMINIUM CHLORIDE,SOLUTION 8 2581 3 Colourless to yellowish liquid.Highly corrosive to most metals.Vapour highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. 185 ALUMINIUM CHLORIDE, ANHYDROUS. 8 1726 3 White to yellowish hygroscopic crystals. Forms corrosive vapors in moist air.Reacts violently with water, evolving heat & hydrogen chloride, an irritating & corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals 186 ALUMINIUM FERROSILICON POWDER 4.3 1395 2 In contact with water, caustic alkalis or acids, evolves hydrogen, a flammable gas. Impurities may, undersimilar circumstances, produce phosphine & arrsine, which are highly toxic gases 187 ALUMINIUM HYDRIDE 4.3 2463 2 White to grey powder.In contact with water, acids or moisture, evolves hydrogen which may be ignited by the heat of the reaction 188 ALUMINIUM NITRATE 5.1 1438 3 Colorless or white crystals. Deliquescent. Soluble in water. Slightly corrosive. Mixtures with combustible material are readily ignited and may burn fiercely. harmful if swallowed 189 ALUMINIUM PHOSPHIDE 4.3 1397 2 Crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flamm and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation 190 ALUMINIUM PHOSPHIDE PESTICIDES 6.1 3048 2 Waxed pellets, adequately stabilized powder, tablets or crystals. Highly toxic if swallowed, by skin contact or by inhalation 191 ALUMINIUM POWDER, UNCOATED. 4.3 1396 2 In contact with water, caustic alkalis or aids,evolves hydrogen, a flamm gas. When finely divided aluminium dust is scattered, it is easily ignited by naked lights, causing explosion.May explode when in contact with oxidizing substance. Reacts with liquid 192 ALUMINIUM POWDER, UNCOATED 4.3 1396 2 NULL 193 ALUMINIUM POWDER, COATED 4.1 1309 2 If uncoated it possesses the property of evolving hydrogen gas when in contact with water, especially seawater;if treated with oil or wax it does not at ordinary temp. Reacts readily with acids & caustic alkalis,evolving hydrogen, a flamm gas. 194 ALUMINIUM POWDER, COATED 4.1 1309 2 NULL 195 ALUMINIUM RESINATE 4.1 2715 3 Cream to brown colored mass. Insoluble in water. Liable to spontaneously heating. Irritating to skin and mucous membranes 196 ALUMINIUM SILICON POWDER UNCOATED 4.3 1398 2 In contact with water, caustic alkalis or acids, generates heat and evolves hydrogen, a flammable gas. May also evolve silanes, which are toxic and may ignite spontaneously 197 ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 4.3 3170 2 Grey powder or lumps with some metallic inclusions. Contact with water may cause heating with possible evolution of flamm & toxic gases such as hydrogen and ammonia.This entry includes e.g.aluminium dross,aluminium skimmings, spent cathodes, spent potliner 198 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINE LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 8 2734 2 Colorless to yellowis flamm liquids or solutions with a pungent odor. miscible with water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. React violently with acids. Cause burns 199 AMINES LIQUID, CORROSIVE, N.O.S or POLYAMINES LIQUID, CORROSIVE, N.O.S. 8 2735 2 Colorless to yellowish liq or solutions with a pungent odor. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals. React violently with acids. 200 AMINES, SOLID, CORROSIVE N.O.S.or POLYAMINES, SOLID, CORROSIVE, N.O.S. 8 3259 2 Colourless to yellowish solids with a pungent odour.Miscible with or soluble in water. when involved in fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Cause burns to skin, eyes and mucous membranes. React violentl 201 AMINES, FLAMMABLE CORROSIVE N.O.S. 3 2733 2 Colourless to yellowish liquids with an unpleasant odour. Some are very volatile. Miscible with water. Corrosive to most metals, especially to copper and its alloys. When involved in a fire, evolve toxic gases. React violently with acids. Harmful by inhal 202 AMINOPHENOLS (o-,m-,p) 6.1 2512 3 White or brownish (ortho- and para-) or reddish-yellow (meta-) crystals. Soluble in water. Toxic if swallowed, by skin contact or by inhalation 203 AMINOPYRIDINES 6.1 2671 3 White powder or crystals. Melting points: 58oC to 64oC. Soluble in water. Reacts violently with acids. Toxic if swallowed, by skin contact or by dust inhalation 204 AMMONIA ANHYDROUS 2.3 1005 2 Liquefied, non-flammable, toxic & corrosive gas with a pungent odor. Lighter than air (0.6). Suffocating in low concentrations. Even though this substance has a flammability hazard under extreme fire conditions in confined areas. Reacts violently with acid 205 AMMONIA SOLUTION relative density between 0.880 and 0.957 at 15' C in water,with more than 10% but not more than 35% ammonia by mass 8 2672 3 Colorless liq with a pungent odor.Corrosive to copper,nickel, zinc & tin & their alloys such as brass. Not significantly corrosive to iron & steel. Reacts violently with acids. Liq & vapor cause burns to skin, eyes & mucous membranes 206 AMMONIA SOLUTION relative density less than 0.880 at 15`C in water with more than 50% ammonia 2.3 3318 2 Highly concentrated solution in water of non-flammable, toxic & corrosive gas with a pungent odour. Has a flammability hazard and only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids. suffocating in low con 207 AMMONIA SOLUTIONS relative density less than 0.880 at l5`C in water, with more than 35% but not more than 50% ammonia 2.2 2073 2 Solution in water of non-flammable gas with a pungent odor. Reacts violently with acids. Extremely dangerous to the eyes 208 AMMONIUM ARSENATE 6.1 1546 3 White powder or crystals. Soluble in water. Reacts with alkalis, evolving ammonia gas. Toxic if swallowed, by skin contact or by dust inhalation 209 AMMONIUM DICHROMATE 5.1 1439 2 Orange needles. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. may ignited spontaneously in contact with strong acids. Harmful if swallowed 211 AMMONIUM DINITRO-ortho-CREOSOLATE, SOLID 6.1 1843 2 May support combustion & burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals & their compunds. Toxic if swallowed, by skin contact or by inhalation 212 AMMONIUM FLUORIDE 6.1 2505 3 Colorless crystals or powder with an ammonia-like odor. Readily soluble in water. Decomposes in contact with acids, evolving hydrogen fluoride, a corrosive to most metals. Causes burns to skin, eyes & mucous membranes 213 AMMONIUM FLUOROSILICATE 6.1 2854 3 Solids which react with acids, evolving hydrogen fluoride & silicon tetrafluoride, irritating & corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation 214 AMMONIUM HYDROGENDIFLUORIDE, SOLID 8 1727 3 White deliquescent crystals. Decomposed by heat or acid, evolving hydrogen fluoride, a toxic, extremely irritating & corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials & most metals. Ca 215 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 8 2817 2 Colorless liquid. Miscible with water. Highly corrosive to most metals & glass. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes & mucous membranes 216 AMMONIUM HYDROGEN SULPHATE 8 2506 2 White, rhombic crystal. Soluble in water. When involved in a fire, evolves extrmely irritating & corrosive fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes & mucous membranes 217 AMMONIUM METAVANADATE 6.1 2859 3 White crystalline p powder. Slightly soluble in water. May act a an oxidizing substance. Toxic if swallowed, by skin contact or by inhalation 218 AMMONIUM NITRATE 1.1D 0222 1 Substance 219 AMMONIUM NITRATE with not more than 0.270 total combustible material, including any organic subs, calculated as any other added substance 5.1 1942 2 Crystals, granules or prills. Soluble in water. Supporter of combustion. A major fire aboard a ship carrying this sus may involve a risk of explosion in the event of contamination or strong confinement. An adjacent detonation may also involve the risk of 221 AMMONIUM NITRATE BASED FERTILIZERS 9 2071 3 Usually granules.Wholly or partly soluble in water. These mixtures may be subject to self-sustaining decomposition if heated.The temp in such areaction can reach 500oC. Decomposition,once initiated,may spread throughout the remainder, producing gases whic 223 AMMONIUM NITRATE BASED FERTILIZERS 5.1 2067 2 Crystals, granules or prills.Wholly or partly soluble in water.These mixtures may be subject to self-sustaining decomposition if heated.Decomposition,once initiated,may spread throughout the remainder, producing gases which are toxic 227 AMMONIUM NITRATE LIQUID (hot concentarated solution) 5.1 2426 2 Hot aqueous solution of not > than 93% ammonium nitrate with not > than 0.2% combustible material & free from any other added matter, containing at least 7% watr, while the max content of chloride ions should not exceed 0.02%. 228 AMMONIUM PERCHLORATE 1.1D 0402 1 substance 229 AMMONIUM PERCHLORATE 5.1 1442 2 White crystals or powder. Soluble in water. When heated, decomposes readily, even with explosion, evolving toxic fumes. Forms highly explosive mixtures with combustible material or powdered metals.These mixtures are sensitive to friction & are 230 AMMONIUM PERSULPHATE 5.1 1444 3 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction & are liable to ignite 231 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 1.1D 0004 1 substance 232 AMMONIUM PICRATE WETTED with not less than l0% water by mass 4.1 1310 2 Desensitized explosive. Substance in pure form consist of yellow crystals. Explosive & sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact 233 AMMONIUM POLYSULPHIDE SOLUTION 8 2818 2 Unstable yellowish liquid with a foul odour (of rotten eggs). Miscible with water. Reacts violently with acids. Decomposes in contact with acids, evolving hydrogen sulphide, a toxic & flamm gas. Toxic if swallowed, by skin contact or by inhalation. Causes 234 AMMONIUM POLYVANADATE 6.1 2861 3 Orange powder. Slightly soluble in water. May act as an oxidizing substances. Toxic if swallowed, by skin contact or by inhalation 235 AMMONIUM SULPHIDE SOLUTION 8 2683 2 Yellow liquid with a foul odour (of rotten eggs). When heated, evolves toxic & flamm vapors. Reacts violently with acids, evolving hydrogen sulphide, a toxic & flamm gas. Toxic if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes & mucou 236 AMMUNITION ILLUMINATING with or without burster, expelling charge or propelling charge 1.3G 0254 1 Ammunition designed to produce a single source if intense light for lighting up an area. the term includes illuminating cartridges, grenades & projectiles and illuminating & target identification bombs 237 AMMUNITION ILLUMINATING with or without burster,expelling charge or propelling charge 1.4G 0297 2 see above 238 AMMUNITION ILLUMINATING with or without burster expelling charge ,propelling charge 1.2G 0171 1 see above 239 AMMUNITION INCENDIARY liquid or gel with burster expelling charge or propelling charge 1.3J 0247 1 Ammunition containing li or gelatinsous incendiary subs. It also contains one or more of the following: a propelling charge with primer & igniter charge; a fuse with burster or expelling charge 240 AMMUNITION INCENDIARY WHITE PHOSPHOROUS with burster, expelling charge or propelling charge 1.2H 0243 1 Ammunition containing white phosphorus as incendiary subs. It also contains one or more of the following: a propelling charge with primer & igniter charge; a fuse with burster or expelling charge. White phosphorus ignites spontaneousy on exposure to ai 241 AMMUNITION INCENDIARY WHITE PHOSPHOROUS with burster expelling charge or propelling charge 1.3H 0244 1 see above 242 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 1.2G 0009 1 243 AMMUNITION INCENDIARY with or without burster, expelling charge or propelling charge 1.3G 0010 1 244 AMMUNITION INCENDIATRY with or without burster, expelling charge or propelling charge 1.4G 0300 2 see above 245 AMMUNITION PRACTICE 1.4G 0362 1 Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuse & propelling charge 246 AMMUNITION PROOF 1.4G 0363 2 Ammunition containg pyrotechnic subs, used to test the performance or strength of new ammunition, weapon component or assemblies 247 AMMUNITION,SMOKE with or without burster,expelling charge or propelling charge 1.3G 0016 1 Ammunition which produces dense smoke which may be toxic & is suffocating in enclosed spaces. The ammunition may contain one or more of the following: a propelling charge with primer & igniter charge 248 AMMUNITION SMOKE WHITE PHOSPHOROUS 1.3H 0246 1 Ammunition containing white phosphorus as incendiary subs. It also contains one or more of the following: a propelling charge with primer & igniter charge; a fuse with burster or expelling charge. White phosphorus ignites spontaneousy on exposure to air 249 AMMUNITION SMOKE WHITE PHOSPHOROUS with burster expelling charge or propelling charge 1.2H 0245 1 see above 250 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 1.2G 0015 1 251 AMMUNITION SMOKE with or without burster, expelling charge or propelling charge 1.4G 0303 2 see above 252 AMMUNITION TEAR PRODUCING NON-EXPLOSIVE 6.1 2017 2 Contents may evolve irritant gas or vapor with lachrymatory effects 253 AMMUNITION TEAR PRODUCING with burster expelling charge or propelling charge 1.4G 0301 2 Ammunition containing tear-producing subs; it also contains one or more of the following: a pyrotechnic subs; a propelling charge with primer & igniter charge; a fuse with burster or expelling charge 254 AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge 1.2G 0018 1 255 AMMUNITION, TEAR PRODUCING with burster, expelling charge or propelling charge 1.3G 0019 1 see above 256 AMMUNITION,TOXIC with burster,expeling charge or propelling charge 1.2K 0020 1 Ammunition containing a toxic agent. It also contains one or more of the following: a pyrotechnic subs; a propelling charge with primer & igniter charge; a fuse with burster or expelling charge 257 AMMUNITION, TOXIC with burster,expelling charge or propelling charge 1.3K 0021 1 see above 258 AMMUNITION, PRACTICE 1.3G 0488 1 Ammunition containing pyrotechnic subs, used to test the performance or strength of new ammunition, weapon component or assemblies 259 AMMUNITION, TOXIC, NON-EXPLOSIVE 6.1 2016 2 Contents may evolve toxic fumes or vapor. Gases evolved are toxic by skin contact or by inhalation 260 AMY NITRITE 3 1113 2 Yellow, transparent, volatile liquid with a fragrant fruity odour.F/point of the pure ISOAMYL NITRITE: -20oC c.c.F/point of pure normal-AMYL NITRITE: 10oC c.c. Decomposes on exposure to air, light or water, evolving toxic nitrous fumes which are orange in 261 AMYL ACETATES 3 1104 3 Colourless liquid with a pear- or banana-like odour. normal-AMY ACETATE: f/point 25oC c.c. secondary-AMYL ACETATE: f/point 32oC c.c. Immiscible with water. 262 AMYL ACID PHOSPHATE 8 2819 3 Clear colorless liquid. A mixture of primary and amyl isomers. Immiscible with water. Corrosive tto skin, eyes and mucous membranes 263 AMYL BUTYRATES 3 2620 3 Colorless liquids. F/point: 52oC to 58oC c.c. Partially miscible with water 264 AMYL CHLORIDE 3 1107 2 Colourless or light brown liquids with an aromatic odour. n-Amyl chloride: F/point:11oC c.c. Explosive limits:normal-AMYL CHLORIDE 1.4% to 8.6%.Immiscible with water. 265 AMYL FORMATES 3 1109 3 Colorless liquids with a pleasant odour. normal-AMYL FORMATE: f/point 27oC c.c. ISOAMYL FORMATE: f/point 26oC c.c. Explosive limits: 1.7% to 10%. Immiscible with water. 266 AMYL MERCAPTAN 3 1111 2 Colourless to yellow liquids with an extremely disagreeable garlic-like odour. tertiary-AMYL MERCAPTAN: f/p -7oC c.c., normal-AMYL MERCAPTAN: f/p 19oC c.c. ISOAMYL MERCAPTAN: f/p18oC c.c. Immiscible with water. These substance may leak from packagings that 267 AMYL NITRATE 3 1112 3 Colourless liquids with an ether-like odour. normal-AMYL NITRATE: f/point 48oC c.c.; ISOAMYL NITRATE: f/p 52oC c.c. Immiscible with water. Harmful by inhalation 268 AMYLAMINE 3 1106 2 Colourless, clear liquids. Explosive limits 2.2% to 22%, normal-AMYLAMINE (1-PENTYLAMINE): f/p 4oC c.c. tertiary-AMYLAMINE (3-PENTYLAMINE): f/p 2oC c.c. Miscible with water. Harmful by inhalation. Cause burns to skin, eyes and mucous membranes 269 AMYLTRICHLOROSILANE 8 1728 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating & corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals 270 ANILINE 6.1 1547 3 Colourless, oily, volatile liquid. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation 271 ANILINE HYDROCHLORIDE 6.1 1548 3 White, crystalline solid.Soluble in water. Decomposes to aniline in contact with alkalis. Toxic if swallowed, by skin contact or by inhalation 272 ANISOLE 3 2222 3 Colorless to yellow liquid. F/point: 41oC c.c. Explosive limits: 0.3% to 6.3%.Immiscible with water. Irritating to skin, eyes and mucous membranes 273 ANISOYL CHLORIDE 8 1729 2 Crystalline powder. Melting point:22oC. reacts violently with water, evolving hydrogen chloride, an irritating & corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapor irritates mucous membranes 275 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 6.1 1549 2 A wide range of toxic solids.Toxic if swallowed, by skin contact or by inhalation 276 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S 6.1 3141 2 A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation 277 ANTIMONY LACTATE 6.1 1550 3 White powder or crystals. Toxic if swallowed, by skin contact or by dust inhalation 278 ANTIMONY PENTACHLORIDE LIQUID 8 1730 3 Yellow, oily liquid with an offensive odour. May solidify by absorption of moisture. Reacts violently with water, evolving hydrogen chloride,an irritating & corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals 279 ANTIMONY PENTACHLORIDE SOLUTION 8 1731 3 Yellow liquid with an offensive odor. Corrosive to most metals. Causes burns to skin, eyes & mucous membranes. 280 ANTIMONY PENTAFLUORIDE 8 1732 2 Colourless liquid with a pungent odour. When anhydrous, mildly corrosive to glass, other siliceous materials & most metals. Reacts violently with water, evolving hydrogen fluoride, an irritating gas, highly corrosive to glass & other siliceous materials & 281 ANTIMONY POTASSIUM TARTRATE 6.1 1551 3 Colourless crystals or white powder. Toxic if swallowed, by skin contact or by dust inhalation 282 ANTIMONY POWDER 6.1 2871 3 Metallic antimony in the form of a fine grey powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation 283 ANTIMONY TRICHLORIDE 8 1733 3 Reacts slowly with water, evolving hdrogen chloride, an irritating & corrosive gas. In the presence of moisture, corrosive to most metals. 285 ARGON compressed 2.2 1006 3 Inert gas. Heavier than air 286 ARGON, REFRIGERATED LIQUID 2.2 1951 3 Liquefied, inert gas. Heavier than air (1.4). 287 ARSENIC 6.1 1558 2 Sivery, brittle, crystalline solid with the appearance of a metal. Toxic if swallowed, by skin contact or by dust inhalation 288 ARSENIC ACID LIQUID 6.1 1553 2 White, deliquescent crystals which readily become liquid. Melting point: approximately 35oC. Miscible with water. In contact with metals, may evolve arsine, an extremely toxic gas. Highly toxic if swallowed, by skin or by inhalation 289 ARSENIC ACID SOLID 6.1 1554 2 White crystals with a relatively high melting point. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation 290 ARSENIC BROMIDE 6.1 1555 2 White, deliquescent crystals. Melting point: approximately 33oC. Decomposed by water, evolving hydrogen bromide, an irritating & corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by dust inhalation 291 ARSENIC COMPOUNDS, LIQUID, N.O.S. 6.1 1556 2 A wide variety of toxic liquids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, atoxic & flammable gas. Toxic if swallowed, by skin contact or by inhalation 292 ARSENIC COMPOUNDS, SOLID, N.O.S. 6.1 1557 2 A wide variety of toxic solids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, a toxic & flammable gas. Toxic if swallowed, by skin contact or dust inhalation 293 ARSENIC PENTOXIDE 6.1 1559 3 White, deliquescent powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation 294 ARSENIC TRICHLORIDE 6.1 1560 2 Colourless, oily liquid. Fumes in moist air, evolving hydrogen chlroide, an irritating & corrosive gas, apparent as white fumes. Reacts with water. Highly toxic if swallowed, by skin contact or by inhalation 295 ARSENIC TRIOXIDE 6.1 1561 2 White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation 296 ARSENICAL DUST 6.1 1562 2 Fine powder. Toxic if swallowed, by skin contact or by dust inhalation 297 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE flash point not less than 23oC 6.1 2993 2 Liquid flammable pesticides having a f/p between 23oC & 60oC c.c., presenting a very wide range of toxic hazard. The frequently contain petroleum or coal tardistillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the comp 298 ARSENICAL PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2760 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 299 ARSENICAL PESTICIDES, LIQUID, TOXIC 6.1 2994 2 Liq pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 300 ARSENICAL PESTICIDES, SOLID, TOXIC 6.1 2759 2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation 301 ARSINE 2.3 2188 2 Flamm toxic, colorless gas with a garlic odor. Explosive limits: 3.9% to 77.8%. Much heavier than air 302 ARTICLE PYROTECHNIC for technical purpose 1.1G 0428 1 Articles which contain pyrotechnic subs and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc 303 ARTICLES EXPLOSIVE EXTREMELY INSENSITIVE (ARTICLE,EEI) 1.6N 0486 1 Articles that contain only extremely insensitive detonating sub & which demonstrate a negligible probability of accidental initiation or propagation and which have passed UN test series 7 304 ARTICLES EXPLOSIVE N.O.S 1.4C 0351 2 NULL 305 ARTICLES EXPLOSIVE N.O.S. 1.2L 0355 1 NULL 306 ARTICLES EXPLOSIVE N.O.S. 1.3L 0356 1 NULL 307 ARTICLES EXPLOSIVE N.O.S. 1.4S 0349 2 NULL 308 ARTICLES EXPLOSIVE N.O.S. 1.4B 0350 2 NULL 309 ARTICLES EXPLOSIVE N.O.S. 1.4D 0352 2 NULL 310 ARTICLES EXPLOSIVE N.O.S. 1.4G 0353 2 NULL 311 ARTICLES, PRESSURIZED PNEUMATIC or HYDRAULIC (containing non-flammable gas) 2.2 3164 3 Articles containing non-flammable, non-toxic gas necessary for their operation 312 ARTICLES PYROPHORIC 1.2L 0380 1 Articles which contain a pyrophoric subs & an explosive subs or component. The termexcludes articles containing white phosphoric 313 ARTICLES PYROTECHNIC for technical purpose. 1.3G 0430 1 see above 314 ARTICLES PYROTECHNIC for technical purpose 1.2G 0429 1 see above 315 ARTICLES PYROTECHNIC for technical purpose 1.4G 0431 2 see above 316 ARTICLES PYROTECHNIC for technical purpose 1.4S 0432 2 see above 317 ARTICLES, EXPLOSIVE, N.O.S. 1.1C 0462 1 - 318 ARTICLES, EXPLOSIVE, N.O.S. 1.2C 0466 1 - 319 ARTICLES, EXPLOSIVE, N.O.S. 1.3C 0470 1 - 320 ARTICLES, EXPLOSIVE, N.O.S. 1.1E 0464 1 - 321 ARTICLES, EXPLOSIVE, N.O.S. 1.1D 0463 1 - 322 ARTICLES, EXPLOSIVE, N.O.S. 1.2D 0467 1 - 323 ARTICLES, EXPLOSIVE, N.O.S. 1.2E 0468 1 - 324 ARTICLES, EXPLOSIVE, N.O.S. 1.4E 0471 2 - 325 ARTICLES, EXPLOSIVE, N.O.S. 1.1F 0465 1 - 326 ARTICLES, EXPLOSIVE, N.O.S. 1.2F 0469 1 - 327 ARTICLES, EXPLOSIVE, N.O.S. 1.4F 0472 2 - 328 ASBESTOS,AMPHIBOLE (amosite,tremolite,actinolite,anthophylite,crocidolite) 9 2212 3 Mineral fibres of varying length.Non-combustible. Inhalation of the dust of asbestos fibres is dangerous & therefore exposure should be avoided at all times.Crocidolite should be regarded as the most hazardous type of asbestos dust. 329 ASBESTOS, CHRYSOTILE 9 2590 3 Mineral fibres of varying length.Non-combustible. Inhalation of the dust of asbestos fibres is dangerous & therefore exposure should be avoided at all times. Always prevent the generation of asbestos dust. A safe level of airborne concentration of asbestos 330 AZODICARBONAMIDE 4.1 3242 2 Yellow or orange powder.Insoluble in water. Heat may cause exothermic decomposition, producing carbon monoxide & nitrogen. May explode if involved in a fire under confined conditions. Addition of activators may result in a decrease of thermal stability and 331 BARIUM ALLOYS PYROPHORIC 4.2 1854 2 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas 332 BARIUM AZIDE dry or wetted with less than 50% water, by mass 1.1A 0224 1 Sensitive substance used in detonators, which become extremely sensitive if they lose their wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorize 333 BARIUM AZIDE WETTED with not less than 50% water, by mass 4.1 1571 2 Desensitized explosive. White crystals or powder. Explosive and sensitive to friction in the dry state. Toxic if swallowed, by skin contact or by dust inhalation. May form extremely sensitive compounds with heavy metals or their salts 334 BARIUM BROMATE 5.1 2719 2 White crystals or powder. Slightly soluble in water. Reacts vigorously with sulphuruc acid. React fiercely with cyaniides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtur 336 BARIUM CHLORATE, SOLID 5.1 1445 2 Colourless crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. When involved in a fire may cause 337 BARIUM COMPOUNDS N.O.S. 6.1 1564 3 White powder, lumps or crystals. Toxic if swallowed, by skin contact or by inhalation 338 BARIUM CYANIDE 6.1 1565 2 White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flamm gas. Highly toxic if swallowed, by skin contact or by dust inhalation 339 BARIUM HYPOCHLORITE with more than 22% available chlorine 5.1 2741 2 White powder with pungent odour. Reacts with acids, evolving chlorine, an irritating, corrosive & toxic gas. Reacts fiercely with acyanides when heated or by frition. May form explosive mixtures with combustible material, powdered metals or ammonium compou 340 BARIUM NITRATE 5.1 1446 2 White crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by bust inhalation 341 BARIUM non-pyrophoric 4.3 1400 2 Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. Harmful if swallowed or by dust inhalation. 342 BARIUM OXIDE 6.1 1884 3 White solid. Evolves heat in contact with water. Toxic if swallowed, by skin contact or by dust inhalation 343 BARIUM PERCHLORATE, SOLID 5.1 1447 2 White crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are se 345 BARIUM PERMANGANATE 5.1 1448 2 Brownish-violet crystals. Soluble in water. Reacts vigorously with sulphuric acid & hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material 346 BARIUM PEROXIDE 5.1 1449 2 White powder. Particularly if weted with small quantities of water, a mixture with combustible material may ignite following impact or friction.When involved in a fire, or in contact with water or acids,decomposes, evolving oxygen. Toxic if swallowed, by s 347 BATTERIES CONTAINING SODIUM or CELLS CONTAINING SODIUM 4.3 3292 2 Batteries are activated by heating to between 300oC & 350oC before operating to produce electricity. Activated batteries may cause fire through short-circuit of the terminals. Bateeries or cells should not be offered for transport at a temprature such that 348 BATTERIES DRY CONTAINING POTASSIUM HYDROXIDE SOLID electric storage 8 3028 3 Series of metal plates immersed in dry potassium hydroxide in a closed receptacle. When electrically charged may cause fire through short-circuiting of terminals. Batteries need not be individually marked and labelled if the pallet bears the appropriate ma 349 BATTERIES WET FILLED WITH ACID electric storage 8 2794 3 Metal plates immersed in acid electrolyte in a glass, hard rubber or plastics receptacle.When electrically charged, may cause fire through short-circuiting of terminals. Acid electrolyte is corrosive to most metals. Cause burns to skin, eyes & mucous membr 350 BATTERIES WET FILLED WITH ALKALI electric storage 8 2795 3 Metal plates immersed in alkaline electroyte in a glass, hard rubber or plastics receptacle. When electrically charged, may cause fire through short-circuiting of terminals. ALkaline electrolyte is corrosive to aluminum, zinc & tin. Reacts violently with a 351 BATTERIES WET NON-SPILLAGE electric storage 8 2800 3 Metal plates immersed in gelled alkaline or acid electrolyte in a glass, hard rubber or plastics receptacle of a non-spillable type. When electrically charged, may cause fire through short-circuiting of terminals. Cause burns to skin, eyes and mucous memb 352 BATTERY FLUID, ALKALI 8 2797 3 Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminum ,zinc & tin 353 BENZALDEHYDE 9 1990 3 Colorless or yellowish volatile oil with a bitter almond odor. Slightly soluble in water. Irritating to skin, eyes & mucous membranes 354 BENZENE 3 1114 2 Colourless liquids with a characteristic odour. F/point: -11oC c.c. Explosive limits: 1.4% - 8%. Freezing point 5oC, flashes below its freezing point. Immiscible with water. Narcotic. Exposure to this substance may produce serious chronic effects of a toxi 355 BENZENESULPHONYL CHLORIDE 8 2225 3 Colourless to slightly yellow liquid with a pungent odour. Melting point: 12oC. Immiscible with water. Decomposes slowly in water. Harmful if swallowed or by skin contact. Highly irritating to skin, eyes & mucous membranes 356 BENZIDINE 6.1 1885 3 White, crystalline solid. Toxic if swallowed, by skin contact or by inhalation 357 BENZONITRILE 6.1 2224 3 Colourless liquids with an odour similar to oil of bitter almonds. Reacts with acids, evolving hydrogen cyanide, a highly toxic & flamm gas. Toxic if swallowed, by skin contact or by inhalation 358 BENZOQUINONE 6.1 2587 2 Yellow crystals with an irritating & penetrating odor resembling that of chlorine. SLightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation 359 BENZOTRICHLORIDE 8 2226 2 Colourless to slightly yellow or brown furning liquid.Reacts with water, evolving hydrogen chloride, an irritating & corrosive gas apparent as white fumes.In the presence of moisture, corrosive to most metals.Harmful if swallowed, by skin contact or by inh 360 BENZOTRIFLOURIDE 3 2338 3 Colourless liq with an aromatic odor. F/p: 12oC c.c. Explosive limits: 2.1% to ...Immiscible with water. Oncontact with moisture or air evolves hydrogen fluoride, which is a toxic & corrosive gas.Harmful by inhalation.Irritating to skin,eyes and mucous mem 361 BENZOYL CHLORIDE 8 1736 2 Colourless liquid, very irritating odour, causes tears. Reacts violently with water, evolving hydrogen chloride, an irritating & corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapor irritates mucous mem 362 BENZYL BROMIDE 6.1 1737 2 Colourless liquid with pungent odour, causes tears. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes & mucous membranes 363 BENZYL CHLORIDE 6.1 1738 2 Colourless liquid with pungent odour, causes tears. Immiscible with water, but hydrolyses slowly in contact with it. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by vapor inhalation.Causes burns to skin, eye 364 BENZYL CHLOROFORMATE 8 1739 2 Colourless liquid with pungent odour. Reacts with water. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes & mucous membranes 365 BENZYL IODIDE 6.1 2653 2 Colourless crystals. Melting point: 24'C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. Causes tears. 366 BENZYLDIMETHYAMINE 8 2619 2 Colourless, flammable liquid with an aromatic odour. Flashpoint: 58'C c.c. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. 367 BENZYLIDENE CHLORIDE 6.1 1886 3 Colourless liquid evolving vapour which is irritating to eyes and skin ("Tear Gas"). Toxic if swallowed, by skin contact or by inhalation. 368 BERYLLIUM COMPOUNDS N.O.S. 6.1 1566 2 A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 369 BERYLLIUM NITRATE 5.1 2464 2 White or yellow deliquescent crystals,or fine dust.Mixtures with combustible material are readily ignited and may burn fiecely.Toxic if swallowed,by skin contact or by dust inhalation. 370 BERYLLIUM POWDER 6.1 1567 2 White, metallic powder. Toxic if swallowed, by skin contact or by dust inhalation. 371 ACETALDEHYDE OXIME 3 2332 3 Colourless liquid.Flashpoint:40oC c.c.Explosive limits:4.2% to 52%.Freezing point 12oC.Miscible with water.Irritating to skin,eyes and mucous membranes. 373 beta-NAPHTHYLAMINE, SOLID 6.1 1650 3 White crystals. Toxic if swallowed, by skin contact or by inhalation. 374 BICYCLO[2.2.1]HEPTA-2,5-DIENE, STABILIZED (2,5- NORBORNADIENE, STABILIZED) 3 2251 2 Colourless, volatile liquid. Flashpoint: below - 18°c.c. Explosives limits: 1.7% to 6.3%. Immiscible with water 375 BIPYIRIDILIUM PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2782 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 376 BIPYRIDILIUM PESTICIDES, LIQUID, TOXIC, FLAMMABLE 6.1 3015 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 377 BIPYRIDILIUM PESTICIDES LIQUIDS TOXIC 6.1 3016 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 378 BIPYRIDILIUM PESTICIDES, SOLID, TOXIC 6.1 2781 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 379 BISULPHATES, AQUEOUS SOLUTION 8 2837 2 Colourless to white liquid. Miscible with water. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 380 BISULPHITESI AQUEOUS SOLUTION N.O.S. 8 2693 3 Liquid with a pungent odour. Reacts with acids, evolving sulphur dioxide, a toxic gas. Causes burns to skin, eyes and mucous membranes. 381 BLACK POWDER (GUNPOWDER) COMPRESSED or BLACK POWDER (GUNPOWDER) IN PELLETS 1.1D 0028 1 382 BLACK POWDER (GUNPOWDER) granular, or as a meal 1.1D 0027 1 383 BOMBS PHOTO FLASH 1.3G 0299 1 NULL 384 BOMBS,PHOTO-FLASH 1.1D 0038 1 385 BOMBS, PHOTO-FLASH 1.1F 0037 1 386 BOMBS, PHOTO-FLASH 1.2G 0039 1 387 BOMBS SMOKE, NON-EXPLOSIVE with corrosive liquid, without initiating device 8 2028 2 Corrosive content evolves dense smoke when in contact with air. Corrosive content may cause acid burns to skin. 388 BOMBS with bursting charge 1.2D 0035 1 NULL 389 BOMBS with bursting charge 1.1D 0034 1 NULL 390 BOMBS with bursting charge 1.1F 0033 1 NULL 391 BOMBS with bursting charge 1.2F 0291 1 NULL 392 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1.1J 0399 1 NULL 393 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1.2J 0400 1 NULL 394 BOOSTERS with detonator 1.2B 0268 1 NULL 395 BOOSTERS with detonators 1.1B 0225 1 NULL 396 BOOSTERS without detanators 1.2D 0283 1 NULL 397 BOOSTERS without detonators 1.1D 0042 1 NULL 398 BORNEOL 4.1 1312 3 White, translucent lumps.Comphor-like odour.Insoluble in water.Harmful by ingestion. 399 BORON TRIBROMIDE 8 2692 2 Colourless fuming liquid. Reacts violently with water, evolving toxic and corrosive fumes. Decomposes when heated, evolving toxic fumes. In the presence of moisture, highly corrosive to most metals. Liquid and vapour cause severe burns to skin, eyes and mu 400 BORON TRICHLORIDE 2.3 1741 2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen chloride, a irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most m 401 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 8 1742 3 Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 403 BORON TRIFLUORIDE 2.3 1008 2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass 404 BORON TRIFLUORIDE DIETHYL ETHERATE 8 2604 2 Colourless fuming flammable liquid. Flashpoint: 59'C c.c. The flashpoint will be lower when free ether is present. Reacts vigorously with oxidizing substances. Decomposes in contact with water, evolving toxic, corrosive and flammable vapour. Causes burns t 405 BORON TRIFLUORIDE DIHYDRATE 8 2851 3 Colourless, non-fuming liquid. Boiling range: 58'C to 60'C. Reacts with water, evolving corrosive and toxic fumes. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. 406 BORON TRIFLUORIDE DIMETHYL ETHERATE 4.3 2965 2 Colourless, flammable liquid. Flashpoint: 20'C c.c. but widely variable, depending upon free ether content. Freezing point: -14'C. Decomposes in contact with water, forming dimethyl ether, a flammable gas. Causes burns to skin, eyes and mucous membranes. 407 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 8 1743 3 Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 409 BROMATES, INORGANIC, AQUEOUS SOLUTION N.O.S. 5.1 3213 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 410 BROMATES INORGANIC N.O.S. 5.1 1450 2 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction, and may form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable 411 BROMINE CHLORIDE 2.3 2901 2 Reddish-yellow non-flammable, toxic and corrosive gas. When heated to decomposition, emits highly toxic and corrosive fumes of bromine and chlorine. Reacts with water, evolving toxic and corrosive fumes. Powerful oxidizing agent which may cause violent fir 412 BROMINE or BROMINE SOLUTION 8 1744 2 Very dark brown, heavy liquid with an extremely irritating odour. Density: 3.1 (pure product). Boiling point: 59'C. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Solutions 413 BROMINE PENTAFLUORIDE 5.1 1745 2 Colourless, heavy liquid with an extremely irritating odour. Boiling point: 40'C. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton and straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely 414 BROMINE TRIFLUORIDE 5.1 1746 2 Colourless, heavy liquid with an extremely irritating odour. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton and straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparen 415 BROMOPROPANES 3 2344 2 Colourless liquids.Immiscible with water.When involved in a fire,evolve toxic fumes.Harmful by inhalation. 416 BROMOACETIC ACID SOLUTION 8 1938 3 Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. 418 BROMOACETONE 6.1 1569 2 When pure, colourless liquid evolving irritating vapour ("Tear Gas"). Flashpoint: approximately 45'C c.c. Toxic if swallowed, by skin contact or by inhalation. 419 BROMOACETYL BROMIDE 8 2513 2 Clear liquid,colourless.Boiling point:150oC.Reacts violently with wate,evolving hydrogen bromide,an irritating and corrosive gas apparent as white fumes.In the presence of moisture,highly corrosive to most metals.Reacts violently with alkalis such as ammon 420 BROMOBENZENE 3 2514 3 Colourless liquid with a characteristic odour.Flashpoint:51oC c.c.Explosive limits:0.5% to 2.8%.Immiscible with water. 421 BROMOBENZYL CYANIDE, LIQUID 6.1 1694 2 Volatile liquids evolving irritating vapour ("Tear Gas"). Melting point: ortho-BROMOBENZYL CYANIDE 1'C. Highly toxic if swallowed, by skin contact or by inhalation. 423 BROMOCHLOROMETHANE 6.1 1887 3 Clear, colourless, volatile liquid with a chloroform-like odour. Immiscible with water. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 424 BROMOFORM 6.1 2515 3 Colourless liquid or crystals (melting point 9oC) with a chloroform-like odour.Toxic if swallowed,by skin contact or by inhalation.Narcotic effect. 425 BROMOMETHYLPROPANES 3 2342 2 Colourless liquids.Immiscible with water.Harmful by inhalation. 426 BROMOTRIFLUOROETHYLENE 2.1 2419 2 Liquefied,flammable,colourless gas.Much heavier than air (5.6).Boiling point:-3oC. 427 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 2.2 1009 3 Liquefied, non-flammable gas with a slight odour. Much heavier than air (5.2) 428 BRUCINE 6.1 1570 3 White crystals or powder. Highly toxic if swallowed, by skin contact or by dust inhalation. 429 BURSTERS explosive 1.1D 0043 1 NULL 430 BUTADIENE, STABILIZED or BUTEDIENES AND HYDROCARBON MIXTURE, STABILIZED, containing more than 40% butadienes. 2.1 1010 2 Liquified , flammable gas with an unpleasant odor. Explosive limits: 2% to 12%. Heavier than air (1.84) 431 BUTANE 2.1 1011 2 Flammable hydrocarbon gas. Explosive limit :1.8% to 8.4%. Heavier than air (2.11) 432 BUTANEDIONE 3 2346 3 Greenish-yellow liquid with a strong odour. Miscible with water. Flash point : 6oC c.c. 433 BUTANOLS 3 1120 2 Colorless liquids with a disagreeable odor. Explosive limits: n-Butanol :1.4% - 11.2%, flash point : 35-38oC c.c.; secondary-Butanol 1.7%-9.8%, flash point :23.8oC c.c. ; tertiary-Butanol 2.4%-8% , flash point : 11oC c.c. ;tertiary-Butanol solidifies at ab 434 BUTYL ACETATES 3 1123 3 Colorless liquids with a pineapple-like odour. Immiscible with water. normal-Butyl Acetate: Flash point 27oC c.c. Explosive limits :1.5% to 15% 435 BUTYL ACID PHOSPHATE 8 1718 3 Yellow liquid. Insoluble in water. Mildly corrosive to most metals. 436 BUTYL ACRYLATES , STABILIZED 3 2348 3 Colourless liquids with an unpleasant odour. Flash point :36oC to 41oC c.c. Explosive limits: 1.2% to 9.9%.Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 437 BUTYL BENZENES 3 2709 3 Colourless liquids with an unpleasant odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. flash point : 34oC to 60oC c.c. Explosive limits : 0.7 - 6.9% 438 BUTYL MERCAPTAN 3 2347 2 Colourless liq with a foul odor. tertiary-BUTYL MERCAPTAN: f/point -26oC c.c. secondary-BUTYL MERCAPTAN : f/point -23oC c.c. 1-BUTANETHIOL(normal-BUTYL MERCAPTAN) : f/point 12oC c.c. ISOBUTYL MERCAPTAN: f/point -9o c.c. Immiscible with water. On contact wi 439 BUTYL NITRITES 3 2351 2 Yellowish,volatile,oily liquids.Partially miscible with water.Decompose on exposure to air,light,water or heat,evolving toxic nitrous fumes.Harmful by inhalation. 440 BUTYL PROPIONATE 3 1914 3 colorless liquids. Flash point : 32oC c.c. Immiscible with water 441 BUTYL VINYL ETHER, STABILIZED 3 2352 2 Colourless, volatile liquid with a sharp ethereal odour. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point: -9oC c.c. 442 BUTYLENE 2.1 1012 2 Flammable hydrocarbon gas. Explosive limits: 1.6% to 10%. Heavier than air (2.0). 443 BUTYLTOLUENES 6.1 2667 3 Colourless liquids. Immiscible in water. Toxic if swallowed, by skin contact or by inhalation. 444 BUTYLTRICHLOROSILANE 8 1747 2 Colourless, flammable liquid with a pungent odour. Flashpoint: 52'C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of mois 445 BUTYRALDEHYDE 3 1129 2 Colorless liquid with a characteristic pungent odour. Flash point : -7oC c.c. Explosive limits : 1.4% to 12.5%. Immiscible with water 446 BUTYRALDOXIME 3 2840 3 Colourless liquid. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 58oC c.c. 447 BUTYRIC ANHYDRIDE 8 2739 3 Colourless liquid. Decomposes in water to form butyric acid. 448 BUTYRONITRILE 3 2411 2 Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Flash point : 21oC c.c. Explosive limit : 1.6% to .... 449 BUTYRYL CHLORIDE 3 2353 2 Colourless liquid with a pungent odour.Reacts with water,evolving hydrogen chloride,an irritating and corrosive gas apparent as white fumes.In the presence of moisture,highly corrosive to most metals.Causes burns to skin,eyes and mucous membranes. 450 CACODYLIC ACID 6.1 1572 3 Colourless crystals or white powder with an offensive odour. Soluble in water. May react with acids, evolving dimethylarsine, an extremely toxic gas. Toxic if swallowed, by skin contact or by dust inhalation. 451 CADMIUM COMPOUNDS 6.1 2570 3 Powder or crystals with various colours.May be soluble or insoluble in water.Toxic if swallowed,by skin contact or by inhalation. 452 CAESIUM 4.3 1407 2 Whiter, ductile, soft metal. React violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 453 CAESIUM HYDROXIDE 8 2682 2 Colourless or yellowish hygroscopic crystals. Reacts violently with acids. Reacts with ammonium salts, evolving hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes 454 CAESIUM HYDROXIDE SOLUTION 8 2681 2 Colourless liquid. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to glass, aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 455 CAESIUM NITRATE 5.1 1451 3 White powder. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 456 CALCIUM ARSENATE 6.1 1573 2 White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 457 CALCIUM ARSENATE and ARSENITE MIXTURE, SOLID 6.1 1574 2 White powder. Toxic if swallowed, by skin contact or by dust inhalation. 458 CALCIUM CARBIDE 4.3 1402 2 Solid. In contact with water, rapidly evolves acetylene, a highly flammable gas, which may be ignited by the heat of the reaction. Acetylene forms highly explosive compounds with salts of some heavy metals. React violently with acids. 459 CALCIUM CHLORATE 5.1 1452 2 White to yellowish deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These 460 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 2429 2 Colourless liquid.When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material or sulphur,danger of spontaneous combustion; .2 in contact wi 461 CALCIUM CHLORITE 5.1 1453 2 White deliquescent crystals. Soluble in water. Sensitive to heat. Reacts vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. 462 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 4.3 1403 2 Powder of granules. Contains calcium carbide as an impurity. In contact with water, evolves ammonia and acetylene, which is a highly flammable gas. React vigorously with acids. 463 CALCIUM CYANIDE 6.1 1575 2 White crystals or powder. Decomposes slowly in water to form a weak hydrogen cyanides solution. React with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 464 CALCIUM DITHIONITE(CALCIUM HYDROSULPHITE) 4.2 1923 2 Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. 465 CALCIUM HYDRIDE 4.3 1404 2 Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 466 CALCIUM HYPOCHLORITE DRY or CALCIUM HYPOCHLORITE MIXTURES, DRY with more than 39% available chlorine(8.8% available oxygen) 5.1 1748 2 White or yellowish solid (power, granules or tablets) with chlorine- like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condi 467 CALCIUM HYPOCHLORITE HYDRATED or CALCIUM HYPOCHLORITE HYDRATED MIXTURE with less than 5.5% but not more than 10% water 5.1 2880 2 White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condi 468 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine 5.1 2208 2 White or yellowish solid (powder, granules or tablets)with chlorine-like odour.Soluble in water.May cause fire in contact with organic material or ammonium compounds.Substances are liable to exothermic decomposition at elevated temperatures.This condition 469 CALCIUM MANGANESE SILICON 4.3 2844 2 In contact with water, evolves hydrogen, a flammable gas. In contact with acid, evolve silane, a spontaneously flammable gas. 470 CALCIUM NITRATE 5.1 1454 3 White deliquescent solid, soluble in water. Mixture with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 471 CALCIUM 4.3 1401 2 Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. 472 CALCIUM PERCHLORATE 5.1 1455 2 White crystals or powder. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction 473 CALCIUM PERMANGANATE 5.1 1456 2 Violet deliquescent crystals. Soluble in water. Occurs in hydrated form. Reacts vigorously with sulphuric acid and hydrogen peroxide. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered m 474 CALCIUM PEROXIDE 5.1 1457 2 White or yellowish powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or on contact with water or acids, decomposes, evolving oxygen. 475 CALCIUM PHOSPHIDE 4.3 1360 2 Red to brown crystals. React with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. React violently with oxidizing substance. Toxic if swallowed, by skin contact or by inhalat 476 CALCIUM PYROPHORIC or CALCIUM ALLOY PYROPHORIC 4.2 1855 2 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 477 CALCIUM RESINATE 4.1 1313 3 Yellowish-white,amorphous powder or lumps.Insoluble in water.Liable to spontaneous heating.Irritating to skin and mucous membranes. 478 CALCIUM RESINATE FUSED 4.1 1314 3 Yellowish-white,amorphous powder or lumps.Insoluble in water.Liable to spontaneous heating.Irritating to skin and mucous membranes. 479 CALCIUM SILICIDE 4.3 1405 2 In contact with water, evolves, hydrogen, a flammable gas. If calcium carbide is present as an impurity, acetylene will also be evolved. In contact with acids, evolves silane, a spontaneously flammable gas. 480 CAMPHOR synthetic 4.1 2717 3 Colourless or white crystals, granules or easily broken masses with a penetrating, pungent and aromatic odour. Slightly soluble in water. When heated, evolves flammable and explosive vapour. Harmful if swallowed. 481 CAMPHOR OIL 3 1130 3 Colourless oil with a characteristic odour. Flash point : 47oC c.c. Immiscible with water 482 CAPROIC ACID 8 2829 3 Oily, colourless or yellowish liquid. Melting point: -4'C. Partially miscible with water. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. 483 CARBAMATE PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2758 2 NULL 484 CARBAMATE PESTICIDES, LIQUID, TOXIC, FLAMMABLE 6.1 2991 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend up 485 CARBAMATE PESTICIDES, LIQUID, TOXIC 6.1 2992 3 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 486 CARBAMATE PESTICIDES, SOLID, TOXIC 6.1 2757 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 487 CARBON , animal or vegetable origin 4.2 1361 3 Black powder or granules. Liable to heat slowly and ignite spontaneously in air. The material as offered for shipments should have been sufficiently heat-treated and should be cooled down to ambient temperature before packing. 488 CARBON ACTIVATED 4.2 1362 3 Black powder or granules. Liable to heat slowly and ignite spontaneously in air. The material as offered for shipments should have been sufficiently heat-treated and should be cooled down to ambient temperature before packing. 489 CARBON DIOXIDE 2.2 1013 3 Liquefied, non-flammable gas. Heavier than air (1.5). Cannot remain in the liquid state above 31C 492 CARBON DIOXIDE, REFRIGERATED LIQUID 2.2 2187 3 Non-flammable,liquefied gas, colourless and odourless.Heavier than air (1.5).Cannot remain in the liquid state above 31'C. 493 CARBON DIOXIDE, SOLID (DRY ICE) 9 1845 3 NULL 494 CARBON DISULPHIDE 3 1131 2 Colourless or faintly yellow, clear liquid, almost odourless when pure; the commercial substance has a strong disagreeable odour. Boiling point: 46°C. Ignition temperature: 100°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation 496 CARBON MONOXIDE, COMPRESSED 2.3 1016 2 Flammable, toxic, odourless gas. Explosive limits: 12% to 75%. Slightly lighter than air (0.97). 497 CARBON TETRABROMIDE 6.1 2516 3 Colourless crystals.Melting point:48oC.Insoluble in water.Toxic if swallowed,by skin contact or by inhalation of dust and vopour. 498 CARBON TETRACHLORIDE 6.1 1846 3 Colourless, volatile liquid with a heavy anaesthestic vapour. Non-flammable; when involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 499 CARBONYL FLUORIDE 2.3 2417 2 Non-flammable,toxic and corrosive colourless gas with a pungent odour.Corrosive to glass and to most metals.Corrosive in the presence of water.Much heavier than air (2.3).Highly irritating to skin,eyes and mucous membranes. 500 CARBONYL SULPHIDE 2.3 2204 2 Flammable, toxic, colourless gas with a foul odour.Much heavier than air (2.1). 501 CARGO TRANSPORT UNIT UNDER FUMIGATION 9 3359 3 A 'FUMIGATED CARGO TRANSPORT UNIT' is a closed cargo transport unit containing goods or materials that either poisonous or asphyxiant. The gases are usually evolved from solid or liquid preparations distributed within the unit. 502 CARTRIDGES FOR WEAPON,BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGES FOR TOOLS, BLANK 1.4S 0014 2 503 CARTRIDGES FLASH 1.3G 0050 1 NULL 504 CARTRIDGES FOR WEAPON BLANK 1.2C 0413 1 NULL 505 CARTRIDGES FOR WEAPONS, BLANK 1.1C 0326 1 506 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 1.3C 0327 1 507 CARTRIDGES FOR WEAPONS BLANK or CARTRIDGES, SMALL ARMS, BLANK 1.4C 0338 2 508 CARTRIDGES FOR WEAPONS INERT PROJECTILE or CARTRIDGES, SMALL ARMS 1.4C 0339 2 509 CARTRIDGES FOR WEAPONS, INERT PROJECTILES or CARTRIDGES, SMALL ARMS 1.4S 0012 2 510 CARTRIDGES FOR WEAPONS with bursting charge 1.1E 0006 1 NULL 511 CARTRIDGES FOR WEAPONS with bursting charge 1.1F 0005 1 NULL 512 CARTRIDGES FOR WEAPONS with bursting charge 1.2E 0321 1 NULL 513 CARTRIDGES FOR WEAPONS with bursting charge 1.2F 0007 1 NULL 514 CARTRIDGES FOR WEAPONS with bursting charge 1.4F 0348 2 NULL 515 CARTRIDGES FOR WEAPONS with bursting charge 1.4E 0412 2 NULL 516 CARTRIDGES FOR WEAPONS with inert projectile 1.2C 0328 1 NULL 517 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 1.3C 0417 1 518 CARTRIDGES OIL WELL 1.3C 0277 1 NULL 519 CARTRIDGES OIL WELL 1.4C 0278 2 NULL 520 CARTRIDGES POWDER DEVICE 1.3C 0275 1 NULL 521 CARTRIDGES POWER DEVICE 1.2C 0381 1 NULL 522 CARTRIDGES POWER DEVICE 1.4C 0276 2 NULL 523 CARTRIDGES, POWER DEVICE 1.4S 0323 2 524 CARTRIDGES, SIGNAL 1.3G 0054 1 525 CARTRIDGES SIGNAL 1.4G 0312 2 NULL 526 CARTTRIDGES SIGNAL 1.4S 0405 2 NULL 527 CASES CARTRIDGE, EMPTY, WITH PRIMER 1.4C 0379 2 NULL 528 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1.4S 0055 1 529 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1.3C 0447 1 NULL 530 CASES,COMBUSTIBLE,EMPTY,WITHOUT PRIMER 1.4C 0446 2 NULL 531 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE 9 2969 3 Whole beans or meal. The letter is the residue remaining after the oil has been extracted from the seeds. Castor beans contain a powerful allergen which, by inhalationof dust or by skin contact with crushed bean product, can give rise to severe irritation 532 CARTRIDGES, FLASH 1.1G 0049 1 533 CAUSTIC ALKALI LIQUIDS N.O.S. 8 1719 3 Corrosive to aluminium, zinc and tin. Reacts violently with acids. Reacts with aluminium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. 534 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 4.1 2000 3 Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. 535 CELLULOID scrap 4.2 2002 2 Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. 536 CERIUM slabs, ingots or rods 4.1 1333 3 Contains 94-99% earth metals.In contact with water or moist air, evolves hydrogen, a flammable gas.Emits sparks when scratched or struck. 537 CERIUM turning or gritty powder 4.3 3078 2 Grey, ductile metal or powder. Decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. 538 CHARGES, DEPTH 1.1D 0056 1 539 CHARGES EXPLOSIVE COMMERCIAL without detonator 1.1D 0442 1 NULL 540 CHARGES EXPLOSIVE COMMERCIAL without detonator 1.2D 0443 1 NULL 541 CHARGES EXPLOSIVE COMMERCIAL without detonator 1.4S 0445 2 NULL 542 CHARGES EXPLOSIVE COMMERCIAL without detonator 1.4D 0444 2 NULL 543 CHARGES PROPELLING 1.1C 0271 1 NULL 544 CHARGES PROPELLING 1.2C 0415 1 NULL 545 CHARGES PROPELLING 1.3C 0272 1 NULL 546 CHARGES PROPELLING FOR CANNON 1.1C 0279 1 NULL 547 CHARGES PROPELLING FOR CANNON 1.2C 0414 1 NULL 548 CHARGES PROPELLING FOR CANNON 1.3C 0242 1 NULL 549 CHARGES, SHAPED without detonator 1.1D 0059 1 550 CHARGES SHAPED COMMERCIAL without detonator 1.2D 0439 1 NULL 551 CHARGES SHAPED COMMERCIAL without detonator 1.4D 0440 2 NULL 552 CHARGES SHAPED without detonator 1.4S 0441 2 553 CHARGES SHAPED FLEXIBLE LINEAR 1.4D 0237 2 NULL 554 CHARGES, SUPPLEMENTRY, EXPLOSIVE 1.1D 0060 1 555 CHARGES, BURSTING, PLASTIC-BONDED 1.1D 0457 1 NULL 556 CHARGES, BURSTING, PLASTIC-BONDED 1.2D 0458 1 NULL 557 CHARGES, BURSTING, PLASTIC-BONDED 1.4D 0459 2 NULL 558 CHARGES, BURSTING, PLASTIC-BONDED 1.4S 0460 2 NULL 559 CHARGES, DEMOLITION 1.1D 0048 1 NULL 560 CHARGES, PROPELLING 1.4C 0491 2 NULL 561 CHARGES, SHAPED, FLEXIBLE, LINEAR 1.1D 0288 1 NULL 562 CHEMICAL KIT or FIRST AID KIT 9 3316 3 NULL 563 CHEMICAL SAMPLE, TOXIC 6.1 3315 2 This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the prohibition of the Development,Production,Stockpilling and Use of Chemical Weapons and on their Destruction.The transport 565 CHLORAL ANHYDROUS, STABILIZED 6.1 2075 2 Colourless, mobile liquid, evolving toxic vapours with are considerably heavier than air.Toxic if swallowed, by skin contact or by inhalation. 566 CHLORATE and BORATE mixtures 5.1 1458 2 Solid. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to 568 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 5.1 1459 2 Deliquescent solid. React vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and a 569 CHLORATES, INORGANIC AQUEOUS SOLUTION, N.O.S. 5.1 3210 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 570 CHLORATES INORGANIC, N.O.S. 5.1 1461 2 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to 571 CHLORIC ACID AQUEOUS SOLUTION with not more than l0% chloric acid 5.1 2626 2 Colourless liquid. May decomposes, evolving chlorine and oxygen with toxic, corrosive and oxidizing effects. May form explosive mixtures with ammonium compounds, combustible material or powdered metals. Corrosive to most metals. Transport of CHLORIC ACID, 572 CHLORINE 2.3 1017 2 Non-flammable, toxic and corrosive yellow gas with a pungent odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. 573 CHLORINE PENTAFLUORIDE 2.3 2548 2 Non-flammable,toxic and corrosive gas.Forms dense,white,corrosive fumes in moist air.Reacts violently with water,evolving hydrogen fluoride,a toxic,irritating and corrosive gas apparent as white fumes.Corrosive to glass and to most metals.Powerful oxidizin 574 CHLORINE TRIFLUORIDE 2.3 1749 2 Non-flammable, toxic and corrosive gas. Forms dense, white, corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Powerful oxid 575 CHLORITE SOLUTION 8 1908 3 Colourless liquid. In contact with acids, evolves very irritating and corrosive gases. Oxidizing solution. May cause fire in contact with organic materials such as wood, cotton or straw. Mildly corrosive to most metals. Causes burns to skin, eyes and mucou 576 CHLORITES, INORGANIC, N.O.S. 5.1 1462 2 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material. powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to 577 CHLOROACETIC ACID SOLUTION 6.1 1750 2 Colourless liquid. Corrosive to most metals. Toxic if swallowed, by skin or by inhalation. Cause burns ti skin, eyes and mucous membranes. 578 CHLOROACETIC ACID, MOLTEN 6.1 3250 2 Molten liquid.Melting point may be as low as 50oC.Toxic if swallowed,by skin contact or by inhalation.Causes burns to skin,eyes and mucous membranes. 579 CHLOROACETIC ACID SOLID 6.1 1751 3 Colourless, very deliquescent crystals. Melting point may be as low as 50'C. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by dust inhalation. Causes burns to skin, eyes and mucous membranes. 580 CHLOROACETONE stabilized 6.1 1695 2 Flammable, corrosive, colourless liquid, evolving irritating vapour ("Tear Gas"). Miscible with water. Flashpoint: 25'C c.c. Highly toxic if swallowed, by skin contact or by inhalation. 581 CHLOROACETONITRILE 6.1 2668 2 Colourless flammable liquid with a pungent odour. Flashpoint: 56'C c.c. Immiscible with water. Decomposes when heated, evolving highly toxic fumes of cyanides. Reacts with steam and acids, evolving toxic and flammable vapours. Highly toxic if swallowed, by 583 CHLOROACETOPHENONE, SOLID 6.1 1697 2 White crystals evolving irritating vapour ("Tear Gas"). Melting point may be as low as 20'C. Highly if swallowed, by skin contact or by inhalation. 584 CHLOROACETYL CHLORIDE 6.1 1752 2 Colourless liquid, with extremely irritating odour, causing tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic 585 CHLOROANILINES LIQUID 6.1 2019 3 Colourless liquid. May be a mixture of two of the isomers (e.g. ortho and meta) of chloroaniline. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation. 586 CHLOROANILINES SOLID 6.1 2018 3 Crystalline solid. Melting point of pure para-chloroaniline: 70'C approximately. Toxic if swallowed, by skin contact or by dust inhalation. 587 CHLOROANISIDINES 6.1 2233 3 Crystalline solid.Melting point:52'C.Soluble in water.Toxic if swallowed,by skin contact or by dust inhalation. 588 CHLOROBENZENE 3 1134 3 Colourless liquid with an almond-like odour. Immiscible with water. Flash point : 29oC c.c. Explosive limits : 1.3% to 11% 589 CHLOROBENZOTRIFLUORIDES 3 2234 3 Colourless liquids with an aromatic odour. On contact with moisture, can evolve hydrogen fluoride, which is a toxic and corrosive gas. Harmful by inhalation. Flash point : 36 to 59 oC c.c. 590 CHLOROBUTANES 3 1127 2 Colourless liquids. tertiary-BUTYL CHLORIDE: flashpoint -30°C c.c., boiling point 51°C. Immiscible with water. 591 CHLOROCRESOLS, SOLUTION 6.1 2669 2 Solutions with a phenol-like odour. Slightly miscible with water. Decompose when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 593 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 2.2 1018 3 Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.0). 594 CHLORODIFLUOROMETHANE and CHLOROPENTAFLUOROETHANE MIXTURE 2.2 1973 3 Liquefied, non-flammable gas. Much heavier than air (4.2). 595 CHLORODIFLUROBROMOMETHANE (REFRIGERANT GAS R 12B1) 2.2 1974 3 Liquefied, non-flammable gas. Much heavier than air (5.7) 596 CHLORODINITROBENZENES, LIQUID 6.1 1577 2 Colourless liquids. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 598 CHLOROFORM 6.1 1888 3 Colourless, volatile liquid. Boiling point: 61'C. Non-flammable. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. Anaesthetic. 599 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 6.1 3277 2 React and decompose with water or heat,evolvin hydrogen chloride,an irritating and corrosive gas apparent as white fumes.Toxic if swallowed,by skin contact or by inhalation.Cause burns to skin,eyes and mucous membranes. 600 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 2742 2 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: cyclohexyl chloroformate: 53'C c.c. Toxic if swallowed, by 601 CHLOROMETHYL ETHYL ETHER 3 2354 2 Colourless liquid with a pungent odour.Partially miscible with water.Fumes in air,evolving hydorgen chloride,which is an irritating and corrosive gas.Toxic by inhalation.Strong lachrymator. 602 CHLOROMOMETHYL CHLOROFORMATE 6.1 2745 2 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to ski 603 CHLORONITROANILINES 6.1 2237 3 Yellow or orange crystalline powders or needles.Insoluble in water.Toxic if swallowed, by skin contact or by dust inhalation. 605 CHLORONITROBENZENES, SOLID 6.1 1578 3 Yellow crystals. Melting point: approximately 30'C to 80'C. Toxic if swallowed, by skin contact or by dust inhalation. 606 CHLORONITROTOLUENES, LIQUID 6.1 2433 3 Immiscible with water.Oxidizing substance which may explode or burn fiercely when in contact with organic materials.Toxic if swallowed,by skin contact or by inhation. 608 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 2.2 1020 3 Liquefied, non-flammable gas. Much heavier than air (4.7). 609 CHLOROPHENATES, SOLID or PHENOLATES, SOLID 8 2905 3 A wide range of corrosive liquids. Soluble in water. Cause burns to skin, eyes and mucous membranes. 610 CHLOROPHENATES, LIQUID, or PHENOLATES, LIQUID 8 2904 3 A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. 611 CHLOROPHENOLS LIQUID 6.1 2021 3 A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 612 CHLOROPHENOLS SOLID 6.1 2020 3 A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 613 CHLOROPHENYL TRICHLOROSILANE 8 1753 2 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 614 CHLOROPICRIN 6.1 1580 2 Colourless, oily liquid. Highly toxic if swallowed, by skin contact or by inhalation. 615 CHLOROPICRIN AND METHYL BROMIDE MIXTURE 2.3 1581 2 Extremely volatile liquid evolving highly toxic vapour. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. 616 CHLOROPICRIN and METHYL CHLORIDE mixture 2.3 1582 2 Extremely volatile liquid evolving highly toxic vapour. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. 617 CHLOROPICRIN MIXTURE N.O.S. 6.1 1583 2 A wide range of liquid mixtures. May evolve highly toxic vapour. Toxic if swallowed, by skin contact or by inhalation. 618 CHLOROPLATINIC ACID,SOLID 8 2507 3 Red-brown crystals.Soluble in water. 619 CHLOROPRENE, STABILIZED 3 1991 2 f/p: -20oC c.c. Colourless liquid. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 620 CHLOROSILANE, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 4.3 2988 2 Colourless, very volatile liquids, flammable and corrosive, with a pungent odour. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in 621 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 8 2986 2 Colourless, flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence 622 CHLOROSILANES, CORROSIVE, N.O.S. 8 2987 3 Colourless liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gases. In the presence of moistu 623 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3 2985 2 Colourless liquids with a pungent odour. When involved in a fire, evolve toxic gases. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas. In the presence of moisture, highly corrosive to most metals. Causes burns to sk 624 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 8 1754 2 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Cause severe burns to skin, eyes and muc 625 1-CHLORO-1,2,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 124) 2.2 1021 3 Liquefied, non-flammable gas. Much heavier than air (4.7). 626 1-CHLORO-2,2,2-TRIFLUOROETHANE (REFRIGERANT GAS R 133a) 2.2 1983 3 Liquefied, non-flammable gas. Much heavier than air (4.1). Boiling point: 7'C. 627 CHLOROTOLUENES 3 2238 3 Colourless to brown liquids. Immiscible with water. When involved in a fire, evolve toxic gases. Harmful by skin contact or by inhalation. Irritating to eyes and mucous membranes. Flash point : 43 to 47oC c.c. 629 CHLOROTOLUIDINES, SOLID 6.1 2239 3 Crystalline solid.Some isomers may melt at low temperature:melting range between 0'C and 24'C.Toxic if swallowed,by skin contact or by inhalation. 630 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 2.2 1022 3 Liquefied, non-flammable gas. Much heavier than air (3.6). Cannot remain in the liquid state above 29'C. 631 CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane 2.2 2599 3 Non-flammable, colourless gas. Explosive limit: 1.8% to 10%. Heavier than air (3.2). 632 CHROMIC ACID SOLUTION 8 1755 2 Orange liquid. Powerful oxidant. May cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 633 CHROMIC FLUORIDE SOLID 8 1756 3 Green or violet crystals. Slightly soluble in water. Reacts with strong acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 634 CHROMIC FLUORIDE, B1177SOLUTION 8 1757 3 Green liquid. React with strong acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 635 CHROMIUM NITRATE 5.1 2720 3 Purple crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 636 CHROMIUM OXYCHLORIDE 8 1758 2 Dark red liquid. React violently with water, evolving hydrogen chloride and chlorine, both highly irritating and corrosive gases apparent as white fumes. Oxidant; may cause fire in contact with organic materials such as wood, cotton and straw. Highly corro 637 CHROMIUM TRIOXIDE ANHYDROUS 5.1 1463 2 Dark purplish-red deliquescent crystals. Soluble in water. Mixtures with combustible material may ignite spontanenously and may even explode. In the presence of moisture, corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 638 CHROMOSULPHURIC ACID 8 2240 2 A liquid mixture of sulphuric acid and a chromuim compound (e.g chromium trioxide or sodium dichromate)and sometimes also water.Highly corrosive to most metals.Causes severe burns to skin,eyes and mucous membranes. 639 CLINICAL WASTE,UNSPECIFIED, N.O.S.or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. 6.2 3291 2 Derived from the medical treatment of animals,humans or from bio-research. 640 COAL GAS COMPRESSED 2.3 1023 2 Flammable, toxic gas. Explosive limits: 4.5% to 40%. Much lighter than air (0.4 to 0.6). 641 COAL TAR DISTILLATE, FLAMMABLE 3 1136 3 Immiscible with water. May form extremely sensitive compounds with heavy metals or their salts. 642 COATING SOLUTION (includes surface treatment or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 3 1139 3 Miscibility with water depends upon the composition. 643 COBALT NAPHTHENATES POWDER 4.1 2001 3 Brown, amorphous powder. Insoluble in water. Readily combustible. 644 COBALT RESINATE, precipitated 4.1 1318 3 Dark brownish-black solid.Insoluble in water.Readily combustible; may ignite spontaneously if contaminated with vegetable fibres (such as cotton).Irritating to skin and mucous membranes. 645 COMPONENTS, EXPLOSIVE TRAIN N.O.S. 1.2B 0382 1 NULL 646 COMPONENTS, EXPLOSIVE TRAIN, N.O.S 1.4S 0384 2 NULL 647 COMPONENTS, EXPLOSIVE TRAIN, N.O.S 1.4B 0383 2 NULL 648 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.1B 0461 1 NULL 649 COMPRESSED GAS, OXIDIZING, N.O.S. 2.2 3156 2 NULL 650 COMPRESSED GAS, TOXIC,FLAMMABLE CORROSIVE, N.O.S. 2.3 3304 2 651 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2.3 3305 2 652 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2.3 3306 2 653 COMPRESSED GAS, TOXIC OXIDIZING, N.O.S. 2.3 3303 2 654 COMPRESSED GAS, FLAMMABLE, N.O.S. 2.1 1954 2 NULL 655 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 1953 2 NULL 656 COMPRESSED GASES N.O.S. 2.2 1956 2 NULL 657 COMPRESSED GAS TOXIC N.O.S. 2.3 1955 2 NULL 658 CONTRIVANCES WATER-ACTIVATED with burster expelling charge or propelling 1.2L 0248 1 NULL 659 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling 1.3L 0249 1 660 COPPER ACETOARSENITE 6.1 1585 3 Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 661 COPPER ARSENITE 6.1 1586 3 Yellowish-green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 662 COPPER BASED PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2776 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 663 COPPER BASED PESTICIDES, LIQUID, TOXIC 6.1 3010 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 664 COPPER BASED PESTICIDES, LIQUID, TOXIC, INFLAMMABLE flashpoint not less than 23°C. 6.1 3009 2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal for distillates, or other flammable liquids. Flashpoint and miscibility with water depend u 665 COPPER BASED PESTICIDES, SOLID, TOXIC 6.1 2775 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 666 COPPER CHLORATE 5.1 2721 2 Blue-green deliquescent crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material. powdered metals or ammonium compounds. The 667 COPPER CHLORIDE 8 2802 3 White to yellow-brown crystals or powder. Partially to fully soluble in water. Corrosive to steel. Causes burns to skin, eyes and mucous membranes. 668 COPPER CYANIDE 6.1 1587 2 Green powder. Slightly soluble in water. React with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 669 COPRA 4.2 1363 3 Dried kernels of coconuts, with a penetrating rancid odour which may taint other cargoes. 670 CORD, DETONATING flexible 1.1D 0065 1 671 CORD,IGNITER 1.4G 0066 2 672 CORD (FUSE), DETONATING metal-clad 1.1D 0290 1 673 CORD (FUSE), DETONATING, metal-clad 1.2D 0102 1 674 CORD (FUSE),DETONATING, MILD EFFECT metal-clad 1.4D 0104 2 675 CORD, DETONATING, Flexible 1.4D 0289 2 NULL 676 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 3264 2 Causes burns to skin,eyes and mucous membranes. 677 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 3266 2 Reacts violently with acids.Causes burns to skin,eyes and mucous membranes. 678 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 3267 2 Reacts violently with acids.Causes burns to skin,eyes and mucous membranes. 679 CORROSIVE LIQUID, SELF-HEATING, N.O.S. 8 3301 2 Causes burns to skin,eyes and mucous membranes. 680 CORROSIVE LIQUID WATER REACTIVE, N.O.S. 8 3094 2 Causes burns to skin, eyes and mucous membranes. 681 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S 8 3265 2 Causes burns to skin,eyes and mucous membranes. 682 CORROSIVE LIQUIDS FLAMMABLE N.O.S. 8 2920 2 Causes burns to skin, eyes and mucous membranes. 683 CORROSIVE LIQUIDS N.O.S. 8 1760 3 Causes burns to skin, eyes and mucous membranes. 684 CORROSIVE LIQUIDS, OXIDIZING, N.O.S. 8 3093 2 Causes burns to skin, eyes and mucous membranes. 685 CORROSIVE LIQUIDS, TOXIC, N.O.S. 8 2922 2 Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 686 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 3260 2 Causes burns to skin,eyes and mucous membranes. 687 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 3261 2 Causes burns to skin,eyes and mucous membranes. 688 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 3262 2 Reacts violently with acids.Causes burns to skin,eyes and mucous membranes. 689 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 3263 2 Reacts violently with acids.Causes burns to skin,eyes and mucous membranes. 690 CORROSIVE SOLID N.O.S. 8 1759 3 Causes burns to skin, eyes and mucous membranes. 691 CORROSIVE SOLID SELF-HEATING NOS 8 3095 2 Causes burns to skin, eyes and mucous membranes. 692 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8 2921 2 Causes burns to skin, eyes and mucous membranes. 693 CORROSIVE SOLIDS, OXIDIZING, N.O.S. 8 3084 2 Causes burns to skin, eyes and mucous membranes. 694 CORROSIVE SOLIDS, TOXIC, N.O.S. 8 2923 2 Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 695 CORROSIVE SOLIDS, WATER REAVTIVE, N.O.S. 8 3096 2 Causes burns to skin, eyes and mucous membranes. 696 COTTON WASTE, OILY 4.2 1364 3 Fibres of vegetable origin. 697 COTTON WET 4.2 1365 3 Readily combustible, liable to ignite spontaneously according to moisture content. 698 COUMARIN DERIVATIVE PESTICIDES LIQUID, FLAMMABLE, TOXIC 3 3024 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 699 COUMARIN DERIVATIVE PESTICIDES LIQUID, TOXIC 6.1 3026 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 700 COUMARIN DERIVATIVE PESTICIDES LIQUID, TOXIC, FLAMMABLE 6.1 3025 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 701 COUMARIN DERIVATIVE PESTICIDES, SOLID, TOXIC 6.1 3027 3 NULL 702 CR0TONYLENE 3 1144 2 Colourless liquid. Boiling point: 27°C. Immiscible with water. Flash point : -53oC c.c. Explosive limits : 1.4% to .... 703 CRESOLS, LIQUID 6.1 2076 2 Colourless to light yellow liquids.Miscible with water.Melting point of meta-CRESOL:12'C.Toxic if swallowed, by skin contact or by inhalation.Cause burns to skin, eyes and mucous membranes. 705 CRESYLIC ACID 6.1 2022 3 Colourless to brownish-yellow liquid mixture with a phenolic odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. "Cresylic acid" is a generic name for mixtures of cresols and hi 706 CROTONALDEHYDE or CROTONALDEHYDE STABILIZED 6.1 1143 2 Colourless, mobile liquid with a pungent odour. Turns to pale yellow in contact with light and air. Miscible with water. Flashpoint: 13'C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause lung damage. 707 CROTONIC ACID, SOLID 8 2823 3 White crystalline solid. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. 708 CUPRIETHYLENEDIAMINE solution 8 1761 2 Dark purple liquid with an ammonia-like odour. Corrosive to copper, aluminium, zinc and tin. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 709 CUTTERS, CABLE, EXPLOSIVE 1.4S 0070 2 NULL 710 CYANIDE SOLUTIONS, N.O.S. 6.1 1935 2 Liquid evolving toxic vapour. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 711 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 1588 2 Solids. May be soluble in water. On contact with water, may form a weak hydrogen cyanides solution. React with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. The 712 CYANOGEN 2.3 1026 2 Liquefied, flammable, toxic gas with a pungent odour. Explosive limits: 6.6% to 43%. Heavier than air (1.9). 713 CYANOGEN BROMIDE 6.1 1889 2 Colourless crystals evolving toxic vapour which is irritating and causes tears. Melting point: approximately 52'C. Boiling point: approximately 62'C. In contact with water evolves hydrogen bromide and hydrogen cyanide, which are highly toxic, flammable and 714 CYANOGEN CHLORIDE STABILIZED 2.3 1589 2 Liquefied, non-flammable, toxic and corrosive gas with an irritating odour. Produces severe tearing of the eyes. On contact with water, reacts violently to give off highly toxic and corrosive fumes. Much heavier than air (2.1). Boiling point: 13'C. Toxic 715 CYANURIC CHLORIDE 8 2670 3 Colourless crystals with a pungent odour. Reacts with water, forming toxic and corrosive acids. Decomposes when heated, evolving toxic and corrosive gases. Causes burns to skin, eyes and mucous membranes. 716 CYCLOBUTANE 2.1 2601 2 Liquefied, flammable, colourless gas. Explosion limit: 1.8% to 10%. Heavier than air (1.9). Boiling point: 13'C. 717 CYCLOBUTYL CHLOROFORMATE 6.1 2744 2 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 38'C c.c. Toxic if swallowed, by skin contact or by inhalati 718 CYCLOHEPTANE 3 2241 3 Oily liquid.Immiscible with water.Narcotic. 719 CYCLOHEPTATRIENE 3 2603 2 Colourless to dark yellow liquid with a characteristic odour. Immiscible with water. Reacts vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. Flash point : 0-4oC c.c. 720 CYCLOHEPTENE 3 2242 3 Oily liquid.Immiscible with water. 721 CYCLOHEXANE 3 1145 2 Colourless, mobile liquid with a sweet aromatic odour. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. Flash point : -18oC c.c. Explosive limits : 1.2% to 8.4% 722 CYCLOHEXANONE 3 1915 3 Colorless liquids. Flash point : 38oC to 44oC c.c. Explosive limits : 1.1% to 9.4%. Immiscible with water 723 CYCLOHEXENE 3 2256 3 Colourless liquid with an aromatic odour.Immiscible with water.Slightly irritating to skin, eyes and mucous membranes. 724 CYCLOHEXENETRICHLOROSILANE 8 1762 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 725 CYCLOHEXYL ACETATE 3 2243 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 56oC c.c. 726 CYCLOHEXYL ISOCYANATE 6.1 2488 2 Yellowish liquid with an irritating odour.Flashpoint:53oC c.c.Immiscible with water.Reacts with water,evolving carbon dioxide.Highly toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 727 CYCLOHEXYL MERCAPTAN 3 3054 3 Colourless liquid with a garlic-like odour. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 49oC c.c. 728 CYCLOHEXYLAMINE 8 2357 2 Colourless or yellowish flammable liquid with a fishy odour.Flashpoint:27oC c.c.Explosive limits:0.5% to 21.7%.Miscible with water.Harmful by inhalation.Causes burns to skin and eyes.Irritating to mucous membranes. 729 CYCLOHEXYLTRICHLOROSILANE 8 1763 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 730 CYCLOOCTADIENES 3 2520 3 Colourless liquids. Immiscible with water. 1,5-CYCLOOCTADIENE: flashpoint 38°C c.c. Irritating to skin, eyes and mucous membranes. 731 CYCLOOCTATETRAENE 3 2358 2 Colourless liquid.Freezing point:-4oC.Immsicible with water. 732 CYCLOPENTANE 3 1146 2 Colourless liquid with a pungent odour. Boiling point: 49°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. Flash point : <-18oC c.c. Explosive limits : 1.4% to 8% 733 CYCLOPENTANOL 3 2244 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 51oC c.c. 734 CYCLOPENTANONE 3 2245 3 Colourless liquid. Immiscible with water. Flash point : 31oC c.c. 735 CYCLOPENTENE 3 2246 2 Colourless liquid. Boiling point: 44°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic. Flash point : -30oC c.c. 736 CYCLOPROPANE 2.1 1027 2 Flammable hydrocarbon gas. Heavier than air. 737 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX;OCTOGEN;DESENSITIZED 1.1D 0484 1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. 738 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX)(OCTOGEN), WETTED with not less than 15% water, by mass 1.1D 0226 1 Substance, Mass detonating explosive which will become more sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authoriz 739 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE) (HEXOGEN)(RDX) DESENSITIZED 1.1D 0483 1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. 740 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE),(RDX), (HEXOGEN), WETTED with not less than 15% water, by mass 1.1D 0072 1 Mass detonating explosive which becomes more sensitive if the wetting agent is lost.The substance, when containing less alcohol,water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 741 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE) (HEXOGEN) (RDX) AND CYCLOTETRAMETHYLENETETRANITRAMINE (HMX;OCTOGEN) MIXTURE WETTED 1.1D 0391 1 Substance, Mass detonating explosive which will become more sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authori 742 CYMENES 3 2046 3 Colourless liquids with an aromatic odour.Immiscible with water.Explosive limits:0.7% to 5.6%. 743 DANGEROUS GOODS IN MACHINERY or DANGEROUS GOODS IN APPARATUS 9 3363 3 Types of articles transported under this entry contain only limited quantities of dangerous goods. 744 DECABORANE 4.1 1868 2 Colourless crystals. Slightly soluble in water. Vapour may form explosive mixture in air. Forms explosive and extremely sensitive mixtures with oxidizing substances. Toxic if swallowed, by skin contact or by dust inhalation. 745 DECAHYDRONAPHTHALENE 3 1147 3 Colourless liquids with an aromatic odour. Immiscible with water. Harmful by inhalation. Flash point : 52-57oC c.c. Explosive limits : 0.7% to 4.9% 746 DEFLAGRATING METAL SALTS OF AROMATIC NITRO- DERIVATIVES, N.O.S. 1.3C 0132 1 Substance. 747 DETONATOR ASSEMBLIES NON-ELECTRIC for blasting 1.4S 0500 2 NULL 748 DETONATOR ELECTRIC for blasting 1.4B 0255 2 NULL 749 DETONATOR NON-ELECTRIC for blasting 1.4B 0267 2 NULL 750 DETONATOR NON-ELECTRIC for blasting 1.4S 0455 2 NULL 751 DETONATORS ASSEMBLIES NON-ELECTRIC for blasting 1.1B 0360 1 NULL 752 DETONATORS ASSEMBLIES NON-ELECTRIC for electric 1.4B 0361 2 NULL 753 DETONATORS FOR AMMUNITION 1.1B 0073 1 NULL 754 DETONATORS FOR AMMUNITION 1.2B 0364 1 NULL 755 DETONATORS FOR AMMUNITION 1.4S 0366 2 NULL 756 DETONATORS FOR AMMUNITION 1.4B 0365 2 NULL 757 DETONATORS, NON-ELECTRIC for blasting 1.1B 0029 1 758 DETONATORS, ELECTRIC for blasting 1.1B 0030 1 NULL 759 DETONATORS, ELECTRIC for blasting 1.4S 0456 2 NULL 760 DEUTERIUM, Compressed 2.1 1957 2 Flammable, odourless gas. Much lighter than air (0.14). 761 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device 2.1 3150 2 Various small devices used for cosmetic and other purposes,and their refills. 762 DI-n-BUTYL AMINE 8 2248 2 Colourless, flammable liquid with an anime odour.Flaspoint:39'C.Partially miscible with water.Decomposes when heated, evolving flammable and toxic gases.Liquid is corrosive to skin,eyes and mucous membranes.Vapour irritates mucous membranes. 763 DIACETONE ALCOHOL 3 1148 3 NULL 764 DIALLYL ETHER 3 2360 2 Colourless, volatile liquid with a perceptible odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Flash point : -11oC c.c. 765 DIALLYLAMINE 3 2359 2 Colourless, volatile liquid with a disagreeable odour. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Flash point : 7oC c.c 766 DIAZODINITROPHENOL, WETTED with not less than 40% water or mixture of alcohol and water, by mass 1.1A 0074 1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost.This substance, when containing less alcohol,water or phlegmatizer than specified,shall not be transported, unless specifically authorized by the compe 767 DIBENZYLDICHLOROSILANE 8 2434 2 Colourless liquid with a pungent odour.Reacts violently with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.When involved in a fire,evolves toxic gases.In the presence of moisture,highly corrosive to most metals.Vapour irritating 768 DIBORANE, compressed 2.3 1911 2 Liquefied, flammable, toxic, colourless gas with an unpleasant odour. Explosive limits: 0.9% to 98%. Lighter than air (0.95). May decompose above -18'C with the formation of hydrogen and boron hydrides. Autoignition temperature: 90'C. Toxic by inhalation; 769 DIBROMOCHLOROPROPANES 6.1 2872 3 Colourless liquid with a perceptible odour. Immiscible with water. Toxic if swallowed, by skin contactor by inhalation. 770 DIBROMODIFLUOROMETHANE 9 1941 3 Colourless, heavy liquid. Boiling point: 24'C. Immiscible with water. When involved in a fire, may evolve toxic fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 771 DIBROMOMETHANE 6.1 2664 3 Clear, colourless liquid. Immiscible in water. Toxic if swallowed, by skin contact or by inhalation. 772 DIBUTYL ETHERS 3 1149 3 Colourless liquids with a mild ether-like odour. Immiscible with water. normal - DIBUTYL ETHER: flashpoint 25°C c.c. Explosive limits : 0.9% to 8.5% 773 DICHLOROACETIC ACID 8 1764 3 Colourless liquid. Melting point: -4'C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 774 DICHLOROACETYL CHLORIDE 8 1765 2 Colourless liquid with extremely irritating odour, causing tears.. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns 775 DICHLOROANILINES, LIQUID 6.1 1590 3 Colourless liquid with a penetrating odour. Liquid mixtures of various isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24'C to 72'C. Toxic if swallowed, by skin contact or by inhalation. 777 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 21) 2.2 1028 3 Liquefied, non-flammable gas. Heavier than air (4.2). 778 DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane 2.2 2602 3 Non-flammable, colourless and odourless gas. Much heavier than air (3.7). 779 DICHLORODIMETHYL ETHER, SYMMETRICAL 6.1 2249 2 Colourless,volatile,flammable liquid.Flaspoint:42'C c.c.Immiscible with water.Decomposed by heat and water.Highly toxic if swallowed,by skin contact or by inhalation .The transport of this substance is prohibited except with special authorization granted b 780 DICHLOROFLUOROMETHANE (REFRIGARANT GAS R 21) 2.2 1029 3 Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.6). Boiling point: 9'C. 781 DICHLOROISOCYANURIC ACID DRY or DICHLOROISOCYANURIC ACID SALTS 5.1 2465 2 White crystalline powder or granules;slightly hygroscopic.Partially soluble in water.Mixtures with combustible material are sensitive to friction and liable to ignite.Harmful by inhalation.Irritating to skin,eyes and mucous membranes. 782 DICHLOROISOPROPYL ETHER 6.1 2490 3 Colourless liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 783 DICHLOROMETHANE 6.1 1593 3 NULL 784 DICHLOROPENTANES 3 1152 3 Light yellow liquids. 1,5-DICHLOROPENTANE: flashpoint 26°C c.c. Immiscible with water. 785 DICHLOROPHENYL ISOCYANATES 6.1 2250 2 Colourless to yellowish crystalline solid with an irritating odour.Insoluble in water.Reacts with water, evolving carbon dioxide.Toxic if swallowed,by skin contact or by inhalation.May be carried in the molten state.Irritating to skin,eyes and mucous membr 786 DICHLOROPHENYLTRICHLOROSILANE 8 1766 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 787 DICHLOROPROPENE 3 2047 2 Colourless or yellow liquids with a sweet odour.Explosive limits:5% to 14%.Immiscible with water.Irritating to skin,eyes and mucous membranes. 788 DICHLOROSILANE 2.3 2189 2 Flammable, toxic and corrosive gas.Reacts with water, evolving hydrogen chloride.Highly irritating to skin, eyes and mucous membranes. 789 DICHLOROTETRAFLUOROETHANE 2.2 1958 2 NULL 791 DICYCLOHEXYLAMINE 8 2565 3 Clear,colourless,combustible liquid with a fishy odour which may taint other cargoes.Immsicible with water.Causes burns to skin,eyes and mucous membranes. 792 DICYCLOHEXYLAMMONIUM NITRITE 4.1 2687 3 NULL 793 DICYCLOPENTADIENE 3 2048 3 The pure substance is a solid with a melting point of 34°C. Commercial products are liquids. Immiscible with water. Harmful if swallowed. Flash point : 26-38 oC c.c. 794 DIDYMIUM NITRATE 5.1 1465 3 Hygroscopic solid. Mixture of neodymium nitrate and praseodymium nitrate. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 795 DIETHOXYMETHANE 3 2373 2 Colourless liquid. Miscible with water. Flash point : <-5oC c.c. 797 DIETHYL CARBONATE 3 2366 3 Colourless liquid. Vapour much heavier than air (4.1). Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 25oC to 31oC c.c. 798 DIETHYL ETHER (ETHYL ETHER) 3 1155 2 Colourless, volatile and mobile liquid with a pleasant aromatic odour. Boiling point: 34°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously o 799 DIETHYL KETONE 3 1156 3 Colourless, mobile liquid. Immiscible with water. Flash point : 13'C c.c. Explosive limits : 1.6% to .... 800 DIETHYL SULPHATE 6.1 1594 3 Colourless, oily liquid. Readily hydrolysed by moisture to sulphuric acid, which is a corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. 801 DIETHYL SULPHIDE 3 2375 3 Colourless, volatile liquid with an odour of garlic. Immiscible with water. Flash point : -10oC c.c. 802 DIETHYLAMINE 3 1154 2 Colourless liquid with an ammonia-like odour. Boiling point: 55°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. Higher concentrations cause dangerous lung irritation. Flash point : -39oC c.c. Explosive limi 803 DIETHYLBENZENE 3 2049 3 Colourless liquids. Immiscible with water. The commercial product is a mixture of isomers. Flash point : 49-56 oC c.c. 804 DIETHYLDICHLOROSILANE 8 1767 2 Colourless, flammable liquid with pungent odour.Flashpoint: 25'C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moistur 805 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile water-insoluble phlegmatizer, by mass 1.1D 0075 1 This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 806 DIETHYLENETRIAMINE 8 2079 2 Yellow hygroscopic liquid with ammoniacal odour.Soluble in water.Strongly alkaline,corrosive.Can form explosive mixtures with nitric acid.Reacts with oxidizing substances.Corrosive to copper and its alloys.Reacts violently with acids.Liquid and vapour can 807 DIETHYLTHIOPHOSPHORYL CHLORIDE 8 2751 2 Colourless liquid with a perceptible odour. Reacts slowly with water, forming hydrochloric acid. When involved in a fire, evolves toxic gases (hydrogen chloride and sulphur dioxide). Vapour highly irritating to eyes and mucous membranes. Liquid causes burn 809 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 2.1 3252 2 Flammable colourless gas.Heavier than air (1.8). 810 DIFLUOROPHOSPHORIC ACID anhydrous 8 1768 3 Colourless liquid. In the presence of moisture, highly corrosive to glass and other siliceous materials. Harmful if swallowed. 811 DIISOBUTYL KETONE 3 1157 3 Colourless liquid. Immiscible with water. Flash point : 49oC c.c. Explosive limits : 0.8% to 7.1% 812 DIISOBUTYLAMINE 3 2361 3 Colourless liquid with a fishy odour. Immiscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : 29oC c.c. 813 DIISOBUTYLENE isomeric compound 3 2050 3 Colourless liquids. Immiscible with water. Flash point : -18 - 21 oC c.c. 814 DIISOOCTYL ACID PHOSPHATE 8 1902 3 Oily liquid. Mildly corrosive to most metals. 815 DIISOPROPYL ETHER 3 1159 2 Colourless liquid with an ether-like odour. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited 816 DIISOPROPYLAMINE 3 1158 2 Colourless, volatile liquid with a fishy odour. Partially miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Flash point : -7oC c.c. Explosive limits : 1.1% to 7.1% 817 DIKETENE, STABILIZED 6.1 2521 2 Colourless flammable liquid with a pungent odour.Flashpoint:44oC c.c.Immiscible with water,but hydrolyses slowly in contact with it.The presence of acids,bases or amines can initiate explosive polymerization.Highly toxic if swallowed,by skin contact or by 818 DIMETHYL CARBONATE 3 1161 3 Colourless liquid. Immiscible with water. Flash point : 18oC c.c. 819 DIMETHYL DISULPHIDE 3 2381 2 Yellow liquid with an unpleasant odour. Immiscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Flash point : 15oC c.c. 820 DIMETHYL ETHER 2.1 1033 3 Flammable gas with a chloroform-like odour. Heavier than air (1.6). 821 DIMETHYL SULFATE 6.1 1595 2 Colourless, volatile liquid evolving toxic vapour. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Cause burn to skin, eyes and mucous membranes. 822 DIMETHYL SULPHIDE 3 1164 2 Colourless liquid with a disagreeable odour. Boiling point: 37°C. Immiscible with water. When involved in a fire, evolves toxic gases. Narcotic in high concentrations. Flash point : -37oC c.c. Explosive limits : 2.2% to 19.7% 823 DIMETHYL THIOPHOSPHORYL CHLORIDE 6.1 2267 2 Colourless,combustible liquid with a pungent odour.Reacts slowly with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.May decompose above 60'C,evolving flammable gases.Toxic if swallowed by skin contact or by inhalation.Causes burn 825 DIMETHYLAMINE anhydrous 2.1 1032 2 Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.6). Boiling point: 7'C. Suffocating in low concentrations. 826 DIMETHYLAMINE AQUEOUS SOLUTION 3 1160 2 Aqueous solution of a flammable gas with an ammonia-like odour. Flashpoint for 60% solution in water: -32°C c.c. Boiling point for 60% solution in water: 36°C. Flashpoint for 25% solution in water: 0°C c.c. Miscible with water. Harmful by inhalation. Caus 827 DIMETHYLCYCLOHEXANES 3 2263 3 Colourless liquids. Immiscible with water. Flash point : 5 to 16oC c.c. 828 DIMETHYLDICHLOROSILANE 3 1162 2 Colourless liquid with a pungent odour. Immiscible with water. Reacts with water to form a complex mixture of dimethylsiloxanes and evolves hydrogen chloride, a toxic and corrosive gas. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes 829 DIMETHYLDIETHOXYSILANE 3 2380 3 Colourless liquid. Miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 13oC c.c. 830 DIMETHYLDIOXANES 3 2707 2 Colourless liquid with a pungent odour. Partially miscible with water. Reacts vigorouslt with oxidizing substances. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 831 DIMETHYLHYDRAZINE symmetrical 6.1 2382 2 Colourless,flammable,volatile liquid with an ammonia-like odour.Miscible with water.Reacts violently with acids.May react dangerously with oxidizing substances.Flaspoint:-17oC c.c.Highly toxic if swallowed,by skin contact or by inhalation. 832 DIMETHYLHYDRAZINE UNSYMMETRICAL 6.1 1163 2 Colourless liquid with an ammonia-like odour. Flashpoint: -18'C c.c. Explosive limits: 2% to 95%. Miscible with water, generating heat. Reacts violently with acids. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and 833 DINITROANILINES 6.1 1596 3 Yellow crystals in pure form. Insoluble in water. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 834 DINITROBENZENES, LIQUID 6.1 1597 3 Yellow solutions. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 836 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2.3 1067 2 Liquefied, non-flammable, toxic and corrosive gas which gives off brown vapour with a pungent odour. Strong oxiding agent. Boiling point:21'C. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect, similar to phosge 837 DINITROGLYCOLURIL (DINGU) 1.1 0489 1 Substance. 838 DINITRO-ortho-CRESOL 6.1 1598 2 Yellow crystals or crystallized mass. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 839 DINITROPHENOL dry or wetted with less than 15% water,by mass 1.1D 0076 1 Substance. 840 DINITROPHENOL SOLUTION 6.1 1599 3 NULL 841 DINITROPHENOL, WETTED with not less than 15% water, by mass 4.1 1320 2 Desensitized explosive.Substance when pure consists of yellow crystals.Slightly in water.May form extremely sensitive compounds with heavy metals or their salts.Toxic if swallowed,by skin contact or by inhalation. 842 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 4.1 1321 2 Desensitized explosives.Explosive and sensitive to friction in the dry state.May form extremely sensitive compounds with heavy metals or their salts.Toxic if swallowed, by skin contact or by inhalation. 843 DINITRORESORCINOL dry or wetted with less than 15% water,by mass 1.1D 0078 1 Substance. 844 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 4.1 1322 2 Desensitized explosive.Explosive when dry.May form extremely sensitive compounds with heavy metals or their salts.Harmful if swallowed or by skin contact. 845 DINITROSOBENZENE 1.3C 0406 1 Substance. 846 DINITROTOLUENES MOLTEN 6.1 1600 2 Molten liquid. This entry covers the 2,3-, 2,4-, 2,6-, 3,4- and 3,5- isomers having melting point between 52'C and 93'C. Toxic if swallowed, by skin contact or by inhalation. 847 DINITROTOLUENES, LIQUID 6.1 2038 3 Immiscible with water.A commercial grade consisting of a mixture of the 2,4-,3,4 and 3,5-isomers is an oily liquid.Toxic if swallowed,by skin contact or by inhalation. 849 DI-normal-AMYLAMINE 3 2841 3 Colourless liquid with an ammoniacal odour. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. Flash point : 52oC c.c. 851 DINOTROPHENOLATES alkali metals, dry or wetted with less than 15% water, by mass 1.3C 0077 1 Substance 852 DIOXANE 3 1165 3 Colourless liquid with an ether-like odour. Miscible with water. Harmful by inhalation. Flash point : 12oC c.c. Explosive limits : 2% to 22% 853 DIOXOLANE 3 1166 3 Colourless liquid. Miscible with water. Harmful by inhalation. Flash point : 2oC c.c. 854 DIPENTENE 3 2052 3 Colourless liquid with a lemon-like odour. Immiscible with water. Flash point : 43oC c.c. Explosive limits : 0.7% to 6.1% 855 DIPHENYLAMINE CHLOROARSINE 6.1 1698 2 Volatile, yellow crystals evolving irritating vapour ("Tear Gas"). Highly if swallowed, by skin contact or by inhalation. 856 DIPHENYLCHLOROARSINE, SOLID or LIQUID 6.1 1699 2 When pure, colourless liquid. The commercial product may be a dark brown liquid. Volatile liquid evolving an irritating vapour ("Tear Gas"). Highly if swallowed, by skin contact or by inhalation. 857 DIPHENYLDICHLOROSILANE 8 1769 3 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 858 DIPHENYLMETHYL BROMIDE 8 1770 3 Solid with an irritating odour. Cuases tears. Melting point: 45'C. In the presence of moisture, corrosive to most metals. Vapour irritates mucous membranes. 859 DIPICRYL SULPHIDE dry or wetted with less than 10% water by mass 1.1D 0401 1 Substance. 860 DIPICRYL SULPHIDE WETTED with not less than 10% water by mass 4.1 2852 2 Desensitive explosive. Golden-yellow, crystalline leaflets. Explosive and sensitive to shock and heat in the dry state. May form extremely sensitive compounds with heavy metals or their salts. 861 DIPROPYL KETONE 3 2710 3 Colourless liquid. Flashpoint: 49'C c.c. Immiscible with water. 862 DIPROPYLAMINE 3 2383 2 Colourless liquid with a fishy odour. Immiscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Flash point : 7oC c.c. 863 DISINFECTANTS, LIQUID, CORROSIVE, N.O.S. 8 1903 3 A wide variety of corrosive liquids. Causes burns to skin, eyes and mucous membranes. 864 DISINFECTANTS, LIQUID, TOXIC, N.O.S. 6.1 3142 3 NULL 865 DISINFECTANTS, SOLID, TOXIC, N.O.S. 6.1 1601 3 A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 866 DISODIUM TRIOXOSILICATE 8 3253 3 Colourless hygroscopic solid.Dangerous reaction with oxidizers.In the presence of moisture,reacts with aluminium,zinc,tin and their compounds,evolving hydrogen,a flammable gas.Causes burns to skin,eyes and mucous membranes.Reacts violently with acids. 867 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1 3005 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 868 THIOCARBAMATE PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2772 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 869 THIOCARBAMATE PESTICIDES, LIQUID, TOXIC 6.1 3006 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 870 THIOCARBAMATE PESTICIDES, SOLID, TOXIC 6.1 2771 3 NULL 871 DIVINYL ETHER,STABILIZED 3 1167 2 Colourless, clear liquid with a characteristic odour. Boiling point: -30°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Str 872 DODECYLTRICHLOROSILANE 8 1771 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 873 DYES, SOLID, CORROSIVE, N.O.S.or DYE INTERMEDIATES, SOLID CORROSIVE N.O.S. 8 3147 3 A wide range of corrosive solids or pastes.Cause burns to skin,eyes and mucous membranes. 874 DYES, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID,CORROSIVE,N.O.S. 8 2801 3 A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. 875 DYES, LIQUID, TOXIC, N.O.S.or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 1602 3 A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 876 DYES, SOLID, TOXIC, N.O.S.or DYES INTERMEDIATES, SOLID, TOXIC, N.O.S. 6.1 3143 3 A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 877 ELEVATED TEMPERATURE LIQUID FLAMMABLE N.O.S. with flashpoint above 60oC,at above its flahpoint 3 3256 2 878 ELEVATED TEMPERATURE LIQUID, N.O.S. at or above 100oC and below its flashpoint (including molten metals , molten salts, etc.) 9 3257 3 Any liquid which is transported at or above 100° but below its flashpoint. May cause fire if in contact with combustible material due to extreme temperature. 879 ELEVATED TEMPERATURE SOLID, NOS at or above 240 C 9 3258 2 Any solid which is transported at or above 240oC.May cause fire if in contact with combustible material due to extreme temperature. 880 ENVIRONMENTALLY HAZARDOUS SUBSTANCE , SOLID, N.O.S. 9 3077 3 NULL 881 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 9 3082 3 NULL 882 EPIBROMOHYDRIN 6.1 2558 2 Flammable liquid.Flashpoint:56oC c.c.Highly toxic if swallowed,by skin contact or by inhalation. 883 EPICHLOROHYDRIN 6.1 2023 2 Colourless flammable liquid with a chloroform-like odour. Flashpoint: approximately 32'C c.c. Toxic if swallowed, by skin contact or by inhalation. 884 ESTERS, N.O.S. 3 3272 3 885 ETHANE 2.1 1035 2 Flammable gas. Explosive limits :3% to 16%. Slightly heavier than air (1.05). 886 ETHANE REFRIGERATED LIQUID 2.1 1961 2 Liquefied, flammable gas with a faint odour. Explosive limits: 3% to 16%. Slighly heavier than air (1.05). 887 ETHANOL (ETHYL ALCOHOL)or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3 1170 3 Colorless, volatile liquids. Pure ETHANOL : flash point 13oC c.c. Explosive limits: 3.3% to 19% . Miscible with water 888 ETHANOLAMINE or ETHANOLAMINE SOLUTION 8 2491 3 Colourless.Miscible with water.Corrosive to copper,copper compounds,copper alloys and rubber.Reacts violently with acids.Liquid and vopour cause burns to skin,eyes and mucous membranes. 889 ETHERS, N.O.S. 3 3271 3 890 ETHYLENE CHLOROHYDRIN 6.1 1135 2 Colourless flammable liquid with a faint, ethereal odour. Flashpoint: 60'C o.c. Explosive limits:4.9% to 15.9%. Miscible with water. When involved in a fire,evolves extremely toxic (phosgene) and corrosive (hydrogen chloride) fumes. Highly toxic if swallow 891 ETHYL ACETATE 3 1173 3 Colorless liquid with a fragnant odor. Flash point :-4oC c.c. Explosive limits: 2.18% to 11.5% . Immiscible with water. 892 ETHYL ACRYLATE STABILIZED 3 1917 2 Colourless liquid with a pungent odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 16oC c.c. Explosive limits : 1.8% to 14% 893 ETHYL AMYL KETONES 3 2271 3 Colourless liquids. Vapour is much heavier than air (4.4). ETHYL normal-AMYL KETONE: flashpoint 43°C c.c. ETHYL secondary-AMYL KETONE: flashpoint 57°C c.c. Immiscible with water. Dissolves some types of plastics. Irritating to skin, eyes and mucous membran 894 ETHYL BORATE 3 1176 3 Colourless liquid. Immiscible with water. Flash point : 11 oC c.c. 895 ETHYL BROMIDE 6.1 1891 2 Colourless volatile liquid evolving irritating vapour with a narcotic effect. Boiling point: 38'C. Vapour can be ignited by an electric spark or similar sources of ignition. Toxic if swallowed, by skin contact or by inhalation. 896 ETHYL BROMOACETATE 6.1 1603 2 Colourless, flammable liquid evolving irritating vapour ("Tear Gas"). Flashpoint: 58'C c.c. Toxic if swallowed, by skin contact or by inhalation. 897 ETHYL BUTYL ETHER 3 1179 3 Colourless liquid. Immiscible with water. flash point : -1 oC c.c. 898 ETHYL BUTYRATE 3 1180 3 Colourless, volatile liquid with a pineapple-like odour. Immiscible with water. Flash point : 26oC c.c. 899 ETHYL CHLORIDE 2.1 1037 2 Liquefied, flammable gas. Explosive limits: 3.5% to 15%. Much heavier than air (2.2). Boiling point: 13'C 900 ETHYL CHLOROACETATE 6.1 1181 2 Colourless, flammable liquid with a pungent and fruity odour. Flashpoint: 54'C c.c. Immiscible with water. When heated, evolves toxic and corrosive fumes. Toxic if swallowed, by skin contact or by inhalation. 901 ETHYL CHLOROFORMATE 6.1 1182 2 Colourless liquid. Flashpoint:16'C c.c. React and decomposes with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, b 902 ETHYL CHLOROTHIOFORMATE 8 2826 2 Colourless, flammable liquid. Flashpoint: 29'C c.c. Causes burns to skin, eyes and mucous membranes. 903 ETHYL CROTONATE 3 1862 3 Colourless liquid with a pungent odour. Immiscible with water. Flash point : 2 oC c.c. 904 ETHYL FLUORIDE (REFRIGERANT GAS R 161) 2.1 2453 2 Liquefied,flammable,colourless gas.Explsosive limits:5% to 10%.Heavier than air (1.7).Boiling point:-37oC. 905 ETHYL FORMATE 3 1190 2 Colourless liquid with a pleasant aromatic odour. Boiling point: 54°C. Immiscible with water. Flash point : -20oC c.c. Explosive limits : 3.5% to 16.5% 906 ETHYL ISOBUTYRATE 3 2385 3 Colourless, volatile liquid with an aromatic odour. Immiscible with water. Flash point : 21oC c.c. 907 ETHYL ISOCYANATE 3 2481 2 Liquid with a pungent odour. Boiling point: 60°C. Immiscible with water but reacts violently with it. On contact with water or acids, or when heated above boiling point, evolves highly toxic nitrous fumes. Toxic by inhalation. Irritating to skin, eyes and 908 ETHYL LACTATE 3 1192 3 Colourless liquid. Flashpoint:46'C c.c. Explosive limits: 1.5% to 11.4%. Miscible with water. 909 ETHYL MERCAPTAN 3 2363 2 Volatile liquid with a strong unpleasant odour. Boiling point: 35°C. Immiscible with water. Flash point : -45oC c.c. Explosive limits : 2.8 % to 18.2% 910 ETHYL METHACRYLATE,STABILIZED 3 2277 3 Colourless liquid with a pungent odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 20oC c.c. Explosive limits : 1.8% to .... 911 ETHYL METHYL ETHER 2.1 1039 2 Liquefied, flammable gas. Explosive limits : 2% to 10%. Much heavier than air (2.1). Boiling point: 11'C. 912 ETHYL METHYL KETONE 3 1193 3 Colourless liquid. Miscible with water. Flash point : -1oC c.c. Explosive limits : 1.8% to 11.5% 913 ETHYL NITRITE SOLUTIONS 3 1194 2 Alcoholic solution of ethyl nitrite. Extremely volatile, with an aromatic, ethereal odour. Explosive limits of the pure product 3% to 50%. Boiling point of pure product: 17°C. Miscible or partially miscible with water. Decomposes under exposure to air, lig 914 ETHYL ORTOFORMATE 3 2524 3 Colourless liquid with an ethereal odour. Immiscible with water. Flash point : 30oC c.c. 915 ETHYL OXALATE 6.1 2525 3 Colourless,oily,aromatic liquid.Slowly decomposed by water.Toxic if swallowed,by skin contact or by dust inhalation. 916 ETHYL PROPIONATE 3 1195 3 Colourless liquid with a pineapple-like odour. Immiscible with water. Flash point : 12oC c.c. Explosive limits: 1.8% to 11% 917 ETHYL PROPYL ETHERS 3 2615 2 Colourless, volatile liquids. Miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : <-18 oC c.c. Explosive limits : 1.7% to 9.0% 918 ETHYL-2-CHLOROPROPIONATE 3 2935 3 Colourless liquid with a pungent odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 38oC c.c. 919 ETHYLACETYLENE, STABILIZED 2.1 2452 2 Liquefied,flammable,colourless gas with odour similar to acetylene.Heavier than air (1.9).Boiling point:8oC.Irritating to skin,eyes and mucous membranes. 920 ETHYLAMINE 2.1 1036 2 Liquefied , flammable gas with an ammonia-like odour. Explosive limits: 3.5% to 14%. Heavier than air (1.6). Boiling point: 17'C 921 ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine 3 2270 2 Aqueous solution of a flammable gas with an ammonia-like odour.Explosive limits:3.5% to 14%.ETHYLAMINE SOLUTION,concentration 50%:flaspoint -11'C c.c.boiling point 56'C.Pure ETHYLAMINE:boiling point 17'C.Miscible with water.Harmful by inhalation.Causes bur 922 ETHYLBENZENE 3 1175 3 Colourless liquid with an aromatic odour. Immiscible with water. Flash point : 22oC . Explosive limits : 1% to 6.7% 923 ETHYLDICHLOROARSINE 6.1 1892 2 Colourless liquid evolving irritating vapour ("Tear Gas"). Highly toxic if swallowed, by skin contact or by inhalation. 924 ETHYLDICHLOROSILANE 4.3 1183 2 Colourless, very volatile liquid with a pungent odour. Flashpoint: -1'C c.c. Immiscible with water. React violently with water or steam to produce heat which amy lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in cont 925 ETHYLENE,ACETHYLENE AND PROPYLENE MIXTURE REFRIGERATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetylen and not more than 6% propylene 2.1 3138 2 Liquefied, flammable, colorless mixture of gases with a garlic odour. Explosive limits: 2.7% to 36%. Lighter than air (0.96). 926 ETHYLENE compressed 2.1 1962 2 Flammable gas. Explosive limits: 3% to 34%. Slightly lighter than air (0.98). 927 ETHYLENE DIBROMIDE 6.1 1605 2 Colourless, volatile liquid. Highly toxic if swallowed, by skin contact or by inhalation. 928 ETHYLENE DICHLORIDE 3 1184 2 Colourless liquid with a chloroform-like odour. Immiscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 13oC c.c. EXplosive limits: 6.2% to 15.9% 929 ETHYLENE GLYCOL DIETHYL ETHER 3 1153 3 Colourless liquid with an ether-like odour. Immiscible with water. Flash point : 35oC c.c. 930 ETHYLENE GLYCOL MONOETHYL ETHER 3 1171 3 Colourless liquid. Miscible with water. Flash point : 40 oC c.c. Explosive limits: 1.7% to 15.6% 931 ETHYLENE GLYCOL MONOETHYLETHER ACETATE 3 1172 3 Colourless liquid. Partially miscible with water. Flash point : 51oC c.c. Explosive limits : 1.7 to 10.1% 932 ETHYLENE GLYCOL MONOMETHYL ETHER 3 1188 3 Colourless liquid. Miscible with water. Flash point : 38oC c.c. Explosive limits : 1.8 to 20% 933 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 3 1189 3 Colourless liquid with a characteristic odour. Miscible with water. Flash point : 44oC c.c. Explosive limits : 1.7 to 8.2% 934 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide 2.3 3300 2 Liquefied,non-flammable,colourless gas with an ether-like odour.Heavier than air (1.5). 935 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 2.1 1041 3 Liquefied, flammable gas with an ether-like odour. Heavier than air (1.5). 936 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 2.2 1952 3 Liquefied, non-flammable gas with an ether-like odour. Explosion limits: 31% to 52%. Heavier than air (1.5). 937 ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide 2.2 3297 3 Liquefied,non-flammable,colourless gas with an ether-like odour.Much heavier than air. 938 ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not than 12.5% ethylene oxide 2.2 3070 3 Liquefied, non-flammable gas. Much heavier than air. 939 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide 2.2 3298 3 Liquefied,non-flammable,colourless gas with an ether-like odour.Much heavier than air. 940 ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURES not more than 30% ethylene 3 2983 2 F/p : <-18oC c.c Colourless, volatile liquid with an ethereal odour. Boiling point: 23°C to 28°C. Miscible with water. Corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Irritating to eyes and mucous membranes. Exlosive limit : 2 941 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more 5.6% ethylene oxide 2.2 3299 3 Liquefied,non-flammable,colourless gas with an ether-like odour.Much heavier than air. 942 ETHYLENE OXIDE or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1MPa (10 bar) at 50'C 2.3 1040 2 NULL 943 ETHYLENE, REFRIGERATED LIQUID 2.1 1038 2 Liquefied, flammable gas. Explosive limits : 3% to 34%. Lighter than air (0.98). 944 ETHYLENEDIAMINE 8 1604 2 Volatile, colourless, hygroscopic flammable liquid with an ammonia-like odour. Flashpoint: 34'C c.c. Miscible with water. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 945 ETHYLENEIMINE, STABILIZED 6.1 1185 2 Colourless oily flammable liquid with a pungent ammonia-like odour. Flashpoint: -13'C c.c. Boiling point: 55'C. Explosive limits: 3.6% to 6.0%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 946 OCTYL ALDEHYDES 3 1191 3 Colourless liquids with a characteristic odour. Immiscible with water. flash point : 44 - 52oC c.c. Explosive limits : 0.9 to 7.2% 947 ETHYLPHENYL-DICHLOROSILANE 8 2435 2 Colourless liquid with a pungent odour.Reacts with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.When involved in a fire,evolves toxic gases.In the presence of moisture,highly corrosive to most metals.Causes burns to skin,eyes a 948 ETHYLTRICHLOROSILANE 3 1196 2 Colourless liquid with a pungent odour. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : 14oC c.c. 949 ARTICLES, EXPLOSIVE, N.O.S. 1.1L 0354 1 NULL 950 EXPLOSIVE, BLASTING, TYPE A 1.1D 0081 1 951 EXPLOSIVE, BLASTING, TYPE B 1.1D 0082 1 952 EXPLOSIVE, BLASTING, TYPE C 1.1D 0083 1 953 EXPLOSIVE, BLASTING, TYPE D 1.1D 0084 1 954 EXPLOSIVE BLASTING TYPE E 1.1D 0241 1 NULL 955 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) 1.5D 0331 1 956 EXPLOSIVE BLASTING-Type E (AGENT, BLASTING, TYPE E) 1.5D 0332 1 957 EXTRACTS, AROMATIC, LIQUID 3 1169 3 Usually consist of alcoholic solutions. Miscibility with water depends upon the composition. 958 EXTRACTS, FLAVOURING, LIQUID 3 1197 3 Usually consist of alcoholic solutions. Miscibility with water depends upon the composition. 959 FERRIC ARSENATE 6.1 1606 3 Green crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 960 FERRIC ARSENITE 6.1 1607 3 Brown or yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 961 FERRIC CHLORIDE, ANHYDROUS 8 1773 3 Brown solid. In the presence of moisture, highly corrosive to most metals. The provisions of this Code should not apply to the solid hydrated form. 962 FERRIC CHLORIDE solution 8 2582 3 Colourless to light brown liquid.Highly corrosive to most metals. 963 FERRIC NITRATE 5.1 1466 3 Violet deliquescent crystals. Soluble in water. Melting point: 47'C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive to most metals. Harmful if swallowed. 964 FERROCERIUM 4.1 1323 3 Alloy derived from cerium or mischmetal,with the addition of 10% to 65% iron.Emits sparks when struck. 965 FERROSILICON with 30% or more but less than 90% silicon 4.3 1408 2 In contact with moisture, water, alkalis or acids, may evolve hydrogen, a flammable gas, which may form explosive mixtures with air, and also arsine and phosphine, which are highly toxic gases. These gases are evolved in proportions which, under mechanical 966 FERROUS ARSENATE 6.1 1608 3 Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 967 FERROUS METAL BORING SHAVING, TURNING or CUTTING, in a form liable to self-heating 4.2 2793 3 These cargoes are liable to self-heating and to ignite spontaneously, particularly when in a finely divided form, wet or contaminated with such materials as unsaturated cutting oil, oily rags and other combustible matter. Self-heating or inadequate ventila 968 FERTILIZER AMMONIATING SOLUTION with free ammonia 2.2 1043 3 Non-flammable aqueous solution of ammonium nitrate, calcium nitrate, urea and their mixture containing ammonia gas. Emits toxic vapours of ammonia. 969 FIBRES or FABRIC, ANIMAL or VEGETABLE OR SYNTHETIC N.O.S. with oil 4.2 1373 3 Liable to ignite spontaneously according to the oil content. 970 FIBRES WITH WEAKLY NITRATED NITROCELLULOSE N.O.S. 4.1 1353 3 Toe board used in the manufacture of boots and shoes. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. 971 FIBRES, VEGETABLE, DRY 4.1 3360 3 Ingnite readily. Consigments of cotton, dry having a density not less than 360 kg/m3, flax, dry having a density not less than 400 kg/m3, sisal, dry having a density not less than 360 kg/m3 (ISO Standard 8115 (1986) and tampico fibre, dry having a density 972 FIBRES, ANIMAL or VEGETABLE burnt, wet or champ 4.2 1372 3 Liable to ignite spontaneously according to moisture content. 973 FILMS, NITROCELLULOSE BASE gelatin coated, except scrap 4.1 1324 3 Ignites readily.When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. 974 FIRE EXTINGUISHER CHARGES corrosive liquid 8 1774 3 Usually, diluted sulphuric acid in small glass receptacles. 975 FIRE EXTINGUISHER with compressed or liquified gas 2.2 1044 3 Fire extinguishers, containing compressed or liquefied gases under pressure above 175 kPa for expelling fire-extinguishing contents. 976 FIRELIGHTER SOLID with flammable liquid 4.1 2623 3 A porous solid, e.g. cellular area-formaldehyde resin, compacted wood shavings, etc., impregnated with flammable liquid, usually white spirit or kerosene, and designed to burn in a controlled manner. When heated, evolves flammable vapours. 977 FIREWORKS 1.2G 0334 1 NULL 978 FIREWORKS 1.4G 0336 2 NULL 979 FIREWORKS 1.1G 0333 1 NULL 980 FIREWORKS 1.3G 0335 2 NULL 981 FIREWORKS 1.4S 0337 2 NULL 982 FISH MEAL (FISH SCRAP), STABILIZED Anti-oxidant treated.Moisture content greater than 5% but not exceeding 12%, by mass.Fat content not more than 15% 9 2216 3 Brown to greenish-brown product obtained thrugh heating and drying of oily fish.Strong odour which may affect other cargo.Liable to heat spontaneously unless of low fat content or effectively anti-oxidant treated. 983 FISHMEAL,UNSTABILIZED FISH SCRAP, UNSTABILIZED High Hazard 4.2 1374 3 Brown to greenish-brown product derived from oily fish. Strong odour which may affect other cargo. Liable to heat and ignite spontaneously. 984 FLAMMABLE LIQUID,TOXIC, CORROSIVE N.O.S. 3 3286 2 Flammable,toxic,corrosive liquid.Toxic if swallowed,by skin contact or by inhalation.Causes burns to skin,eyes and mucous membranes. 985 FLAMMABLE LIQUID, CORROSIVE N.O.S. 3 2924 2 Causes burns to skin, eyes and mucous membranes. 986 FLAMMABLE LIQUID, TOXIC N.O.S. 3 1992 2 Flammable toxic liquid which is not specified by name, in this class or, on account of its characteristics, in some other class. Toxic if swallowed, by skin contact or by inhalation. 987 FLAMMABLE LIQUIDS N.O.S. 3 1993 2 NULL 988 FLAMMABLE SOLID, CORROSIVE, INORGANIC N.O.S. 4.1 3180 2 Causes burns to skin,eyes and mucous membranes. 989 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 3178 2 NULL 990 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 3176 2 Shipped molten above its melting point. 991 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 3179 2 Toxic if swallowed,by skin contact or by dust inhalation.Should be handled with care to minimize exposure,particularly to dust. 992 FLAMMABLE SOLID, CORROSIVE, ORGANIC N.O.S. 4.1 2925 2 Causes burns to skin, eyes and mucous membranes. 993 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 1325 2 NULL 994 FLAMMABLE SOLIDS, TOXIC, ORGANIC, N.O.S. 4.1 2926 2 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 995 FLAMMABLE SOLID, OXIDIZING, N.O.S. 4.1 3097 2 NULL 996 FLARES AERIAL 1.1G 0420 1 NULL 997 FLARES AERIAL 1.2G 0421 1 NULL 998 FLARES, AERIAL 1.3G 0093 1 999 FLARES AERIAL 1.4S 0404 2 NULL 1000 FLARES AERIAL 1.4G 0403 2 NULL 1001 FLARES SURFACE 1.1G 0418 1 NULL 1002 FLARES SURFACE 1.2G 0419 1 NULL 1003 FLARES, SURFACE 1.3G 0092 2 1004 FLASH POWDER 1.1G 0094 1 NULL 1005 FLASH POWDER 1.3G 0305 1 NULL 1006 FLOUBORIC ACID 8 1775 2 Colourless, clear liquid. Corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. 1007 FLUORINE compressed 2.3 1045 2 Non-flammable, toxic and corrosive pale yellowish gas with a pungent odour. Powerful oxidant which may cause fire. React with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Will explode when mixed with hydro 1008 FLUOROACETIC ACID 6.1 2642 2 Colourless crystals. Melting point: 33'C. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1009 FLUOROANILINE 6.1 2941 3 Liquids. Freezing point: -28'C to -2'C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1010 FLUOROBENZENE 3 2387 2 Colourless liquid with a benzene odour. Immiscible with water. Harmful by inhalation. Flash point :-15oC c.c. 1011 FLUOROPHOSPHORIC ACID anhydrous 8 1776 3 Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. 1012 FLUOROSILICATES, N.O.S. 6.1 2856 3 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 1013 FLUOROSULPHONIC ACID 8 1777 3 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen fluoride, an extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most me 1014 FLUOROTOLUENES 3 2388 2 Colourless liquids. ortho-FLUOROTOLUENE: flashpoint 9°C c.c. meta-FLUOROTOLUENE: flashpoint 12°C c.c. para-FLUOROTOLUENE: flashpoint 10°C c.c. Immiscible with water. 1015 FLUOSILICIC ACID 8 1778 3 Colourless liquid. Highly corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. 1016 FORMALDEHYDE SOLUTION FLAMMABLE 3 1198 2 Colourless liquids with a pungent odour. Miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 32 - 60oC c.c. 1017 FORMALDEHYDE SOLUTIONS with not less than 25% formaldehyde 8 2209 3 Colourless, clear liquid,with a suffocating pungent odour.Usually stabilized with methyl alcohol.Miscible with water.Causes burns to skin, eyes and mucous membranes. 1018 FORMIC ACID with more than 85% acid by mass 8 1779 3 Colourless flammable liquid with a pungent odour. Pure FORMIC ACID: flashpoint 42'C c.c. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1019 FRACTURING DEVICES, EXPLOSIVE for oil wells,without detonator 1.1D 0099 1 1020 FUEL AVIATION TURBINE ENGINE 3 1863 2 Boiling range: -14'C upwards. Immiscible with water. 1021 FUMARYL CHLORIDE 8 1780 3 Yellow liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1022 FURAN 3 2389 2 Colourless liquid with a strong odour. Boiling point: 31°C. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. Flash point :<-18oC c.c. Explosive limits: 1.3 - 14.3% 1023 FURALDEHYDES 6.1 1199 2 Colourless or reddish-brown, mobile liquids with a pungent odour. Miscible with water. Explosive limits for 2-FURALDEHYDE: 2.1% TO 19.3%. Flashpoints: 2-FURALDEHYDE 60'C c.c., 3-FURALDEHYDE 48'C c.c. Toxic if swallowed, by skin contact or by inhalation. 1024 FURFURYL ALCOHOL 6.1 2874 3 Clear, colourless, mobile liquid, becoming brown to dark-red upon exposure to light and air. Miscible with water. Reacts explosively with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1025 FURFURYLAMINE 3 2526 3 Pale yellow, oily liquid. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : 37oC c.c. 1026 FUSE, NON-DETONATING 1.3G 0101 2 1027 FUSE, IGNITER, tubular, metal-clad 1.4G 0103 2 1028 FUSE, SAFETY 1.4S 0105 3 NULL 1029 FUSEL OIL 3 1201 3 Colourless, oily liquid with a disagreeable odour. A mixture consisting of amyl alcohols. Immiscible with water. 1030 FUZES,DETONATING 1.1B 0106 1 1031 FUZES , DETONATING 1.2B 0107 1 1032 FUZES DETONATING with protective feature 1.1D 0408 1 NULL 1033 FUZES DETONATING with protective feature 1.2D 0409 1 NULL 1034 FUZES IGNITING 1.3G 0316 1 NULL 1035 FUZES, DETONATING 1.4S 0367 2 NULL 1036 FUZES, DETONATING 1.4B 0257 2 NULL 1037 FUZES, DETONATING, with protective features 1.4D 0410 2 NULL 1038 FUZES, IGNITING 1.4S 0368 2 NULL 1039 FUZES, IGNITING 1.4G 0317 2 NULL 1040 GALLIUM 8 2803 3 Silvery-white metallic element that melts at 29'C, becoming a bright, shiny liquid. Insoluble in water. Highly corrosive to aluminium. Harmful if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs when carried in 1041 GAS OIL or DIESEL OIL or HEATING OIL,LIGHT 3 1202 3 Flash point : 60-61oC c.c. Immiscible with water 1042 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 2.1 3312 2 NULL 1043 GAS, REFRIGERATED LIQUID N.O.S. 2.2 3158 2 1044 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 2.2 3311 3 1045 GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S. not refrigerated liquid 2.1 3167 2 NULL 1046 GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S. not refrigerated liquid 2.3 3168 2 NULL 1047 GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S. not refrigerated liquid 2.3 3169 2 NULL 1048 GENETICALLY MODIFIED MICRO-ORGANISMS or GENETICALLY MODIFIED ORGANISMS 9 3245 2 1049 GERMANE 2.3 2192 2 Flammable, toxic, colourless gas with a pungent odour.Much heavier than air (2.6). 1050 GLYCEROL-alpha-MONOCHLOROHYDRIN 6.1 2689 2 Colourless liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1051 GLYCIDALDEHYDE 3 2622 3 Colourless liquid with a pungent odour. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 31oC c.c. 1052 GRENADES hand or rifle with bursting charge 1.1D 0284 1 NULL 1053 GRENADES hand or rifle with bursting charge 1.1F 0292 1 NULL 1054 GRENADES hand or rifle with bursting charge 1.2D 0285 1 NULL 1055 GRENADES hand or rifle with bursting charge 1.2F 0293 1 NULL 1056 GRENADES PRACTICE hand or rifle 1.2G 0372 1 NULL 1057 GRENADES PRACTICE hand or rifle 1.3G 0318 1 NULL 1058 GRENADES, PRACTICE hand or rifle 1.4S 0110 2 1059 GRENADES, PRACTICE, hand or rifle 1.4G 0452 2 NULL 1060 GUANIDINE NITRATE 5.1 1467 3 White granules. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. NITROGUANIDINE is a different substance. 1061 GUANYL NITROSAMINO-GUANYLIDENE HYDRAZINE WETTED with not less than 30% water, by mass 1.1A 0113 1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost.This substance, when containing less alcohol, water or phlegmatizer than specified,shall not be transported,unless specifically authorized by the compe 1062 GUANYL NITROSAMINO-GUANYLTETRAZENE (TETRAZENE) WETTED with not less than 30% water, or mixture of alcohol and water, by mass 1.1A 0114 1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost.This substance, when containing less alcohol, water or phlegmatizer than specified,shall not be transported,unless specifically authorized by the compe 1063 HAFNIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present) (a)mechanically produced, particle size less than 53 microns; (b)chemically produced, particle size less than 840 microns 4.1 1326 2 Insoluble in water.Liable to spontaneous combustion when dry.Forms explosive mixtures with oxidizing substances. 1064 HAFNIUM POWDER, DRY 4.2 2545 2 Black amorphous powder.Insoluble in water.Liable to ignite spontaneously in air.Forms explosive mixtures with oxidizing substances. 1065 HAY, STRAW or BHUSA 4.1 1327 3 Ignites readily.Liable to spontaneous combustion when wet, damp or contaminated with oil. Refuce for shipment when loose,damp,wet or contaminated with oil 1066 HELIUM compressed 2.2 1046 3 Inert gas. Much lighter than air (0.14). 1067 HELIUM refrigerated liquid 2.2 1963 3 Liquefied, inert gas. Much lighter than air (0.14). 1068 HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 2.2 3296 3 Non-flammable compressed gas.Heavier than air (1.4). 1069 HEPTANES 3 1206 2 Colourless, volatile liquids. n-HEPTANE: flashpoint -4°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. Explosive limits : 1.1 to 6.7% 1070 HEXACHLOROACETONE 6.1 2661 3 Colourless to yellowish liquid. Slightly miscible with water. When heated, evolves extremely toxic fumes (phosgene). Causes tears. Toxic if swallowed, by skin contact or by inhalation. 1071 HEXACHLOROBENZENE 6.1 2729 3 White needle-like crystals. Insoluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. 1072 HEXACHLOROBUTADIENE 6.1 2279 3 Colourless liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1073 HEXACHLOROCYCLOPENTADIENE 6.1 2646 2 Pale yellow liquid with a pungent odour. Immiscible with water. Causes tears. Highly if swallowed, by skin contact or by inhalation. 1074 HEXACHLOROPHENE 6.1 2875 3 White, odourless powder or crystals. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1075 HEXADECYLTRICHLOROSILANE 8 1781 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1076 HEXADIENES 3 2458 2 Colourless liquids. 1,3-HEXADIENE: flashpoint -3°C c.c. 1,4-HEXADIENE: flashpoint -25°C c.c. 1,5-HEXADIENE: flashpoint -27°C c.c. 2,4-HEXADIENE: flashpoint -7°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous me 1077 HEXAETHLY TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 2.3 1612 2 Toxic if swallowed, by skin contact or by dust inhalation. 1078 HEXAETHYL TETRAPHOSPHATE 6.1 1611 3 Yellow liquid. Miscible with water. Toxic if swallowed, by skin contact or by dust inhalation. 1079 HEXAFLUOROACETONE 2.3 2420 2 Non-flammable,toxic and corrosive,colouless,hygroscopic gas with an unpleasant odour.Reacts vigrously with water,evolving heat.Corrosive to glass and to most metals.Fumes in moist air.Much heavier than air (5.7).Highly irritating to skin,eyes and mucous me 1080 HEXAFLUOROACETONE HYDRATE,LIQUID 6.1 2552 2 Toxic if swallowed,by skin contact or by inhalation. 1081 HEXAFLUOROETHANE (REFRIGERANT GAS R 116) 2.2 2193 3 Non-flammable,colourless and odourless gas.Much heavier than air (4.8).Cannot remain in liquid state above 24.3'C. 1082 HEXAFLUOROPHOSPHORIC ACID 8 1782 3 Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. Harmful if swallowed. 1083 HEXAFLUOROPROPYLENE 2.2 1858 3 Non-flammable gas. Much heavier than air (5.2). 1084 HEXALDEHYDE 3 1207 3 Colourless liquid with a pungent odour. Immiscible with water. Flash point : 32oC c.c. 1085 HEXAMETHYLENE DIISOCYANATE 6.1 2281 3 Colourless to light yellow liquid with a pungent odour.Immiscible with water but reacts with it,evolving heat and carbon dioxide gas.When heated,evolves toxic nitrous fumes.Toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and muc 1086 HEXAMETHYLENEDIAMINE solution 8 1783 3 NULL 1087 HEXAMETHYLENEDIAMINE, SOLID 8 2280 3 White crystals or shiny flakes with a specific odour.Melting point:29'C.Soluble in water;solution in water is a strong alkali.Decomposes when heated,evolving flammable and toxic gases.Causes burns to skin,eyes and mucous membranes. 1088 HEXAMETHYLENEDIAMINE, MOLTEN 8 2280 3 White crystals or shiny flakes with a specific odour.Melting point:29'C.Soluble in water;solution in water is a strong alkali.Decomposes when heated,evolving flammable and toxic gases.Causes burns to skin,eyes and mucous membranes. 1089 HEXAMETHYLENEIMINE 3 2493 2 Yellowish liquid with an ammoniacal odour. Miscible with water. Harmful by inhalation. Absorbed through the skin. Causes burns to skin, eyes and mucous membranes. Sub risk is 8. Flash point : 18oC c.c. 1090 HEXAMETHYLENETETRAMINE 4.1 1328 3 White, crystaline powder. Soluble in water. 1091 HEXANES 3 1208 2 Colourless, volatile liquids with a faint odour. n-HEXANE: flashpoint-22°C c.c. boiling point 69°C. NEOHEXANE: flashpoint -48°C c.c. boiling point 50°C. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Explosive limits : 1 1092 HEXANITRODIPHENYLAMINE(DIPICRYLAMINE),(HEXYL) 1.1D 0079 1 Substance 1093 HEXANITROSTILBENE 1.1D 0392 1 Substance. Mass detonating explosive. 1094 HEXANOLS 3 2282 3 Colourless liquids. normal-HEXANOL: flashpoint 57°C c.c. Miscible with water. 1095 HEXOLITE(HEXOTOL) dry or wetted with less than 15% water, by mass 1.1D 0118 1 Substance. Mixtures of mass detonating explosives. 1096 HEXOTONAL 1.1D 0393 1 Substance. Mass detonating explosive. 1097 HEXYLTRICHLOROSILANE 8 1784 3 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1098 HYDRAZINE ANHYDROUS 8 2029 2 Colourless, flammable liquid with an ammoniacal odour. Reacts violently with acids. Flashpoint: 52'C c.c. Miscible with water. Highly reactive reducing agent. Ignites spontaneously when in contact with porous material such as earth, wood or cloth. Toxic if 1099 HYDRAZINE, AQUEOUS SOLUTION with not more 37% hydrazine, by mass 6.1 3293 3 Colourless liquid.React violently with acids.Toxic if swallowed,by skin contact or by inhalation. 1100 HYDRAZINE, HYDRATE or HYDRAZINE AQUEOUS SOLUTION with more than 37% hydrazine, by mass 8 2030 2 Colourless liquid.Powerful reducing agent, burns readily.Toxic if swallowed, by skin contact or by inhalation.Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1101 HYDRIODIC ACID 8 1787 3 Colourless liquid. An aqueous solution of the gas hydrogen iodode. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1102 HYDROBROMIC ACID 8 1788 3 Colourless liquid. An aqueous solution of the gas hydrogen iodode. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1103 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.OS. 2.1 1965 2 Liquefied flammable hydrocarbon gas obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butene, etc., in varying proportions. Heavier than air. 1104 HYDROCARBON GAS, MIXTURE, COMPRESSED, N.O.S. 2.1 1964 2 Flammable hydrocarbon gas mixture obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butene, butylene, etc., in varying proportions. Heavier than air. 1105 HYDROCARBONS, LIQUID N.O.S. 3 3295 2 Immiscible with water. 1106 HYDROCHLORIC ACID 8 1789 3 Colourless liquid. An aqueous solution of the gas hydrogen iodode. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1107 HYDROCYANIC ACID AQUEOUS SOLUTIONS 6.1 1613 2 Colourless liquid evolving extremely toxic vapour with a bitter almond odour. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Transport of HYDROCYANIC ACID, AQUEOUS SOLUCTION with more than 20% hydrogen cyanides and of HYD 1108 HYDROFLOURIC ACID solution 8 1790 2 Colourless liquid with an irritating odour. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Both the liquid and its fumes cause severe burns to skin, eyes and mucous membranes. 1109 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 8 1786 2 Colourless syrup liquid with a pungent odour. Mixture consists of between 70% and 80% by mass of acids and contains not less than 25% by mass of hydrofluoric acid. Reacts violently with water, developing heat. Highly corrosive to glass, other siliceous ma 1110 HYDROGEN and METHANE MIXTURE, COMPRESSED 2.1 2034 2 Flammable, odourless gas mixtures.Much lighter than air. 1111 HYDROGEN BROMIDE anhydrous 2.3 1048 2 Non-flammable, toxic and corrosive gas with a pungent odour. Highly corrosive in the presence of water. Much heavier than air (3.6). Highly irritating to the skin, eyes and mucous membranes. 1112 HYDROGEN CHLORIDE ANHYDROUS 2.3 1050 2 Non-flammable, toxic and corrosive colourless gas with a pungent odour. Highly corrosive in the presence of water. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes. 1113 HYDROGEN compressed 2.1 1049 2 Flammable, odourless gas. Explosive limits:4% to 75%. Much lighter than air (0.07). 1114 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more 45 % hydrogen cyanide 6.1 3294 2 Flammable solution,evolving extremely toxic flammable vapours.Miscible with water.Highly toxic if swallowed,by skin contact or by inhalation.Transport of HYDROGEN CYANIDE,SOLUTION IN ALCOHOL with more than 45% hydorgen cyanide is prohibited. 1115 HYDROGEN CYANIDE STABILIZED,containing less than 3 water% 6.1 1051 2 Very volatile, colourless flammable liquid, evolving extremely toxic flammable vapours. Boiling point:26'C. Flashpoint:-18'C c.c. Miscible with water. Highly yoxic if swallowed, by skin contact or by inhalation. 1116 HYDROGEN CYANIDE, STABILIZED 6.1 1614 2 Very volatile, colourless liquid, evolving extremely toxic flammable vapour, absorbed in a porous inert material. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1117 HYDROGEN FLUORIDE ANHYDROUS 8 1052 2 Colourless, fuming and highly volatile liquid with an irritating and pungent odour. Highly corrosive to metals and glass in the presence of moisture. Boiling point:20'C. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eye 1118 HYDROGEN IODIDE, ANHYDROUS 2.3 2197 2 Non-flammable, toxic and corrosive colourless gas with a pungent odour.Highly corrosive in the presence of..Much heavier than air (4.4).Highly irritating to skin, eyes and mucous membranes. 1119 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid (s) water and not more than 5% peroxyacetic acid, STABILIZED 5.1 3149 2 Colourless liquid.Carried as an aqueous solution.Slowly decomposes,evolving oxygen;the rate of decomposition increases on contact with most metals.In contact with combustible material,may cause fire.Causes burns to skin,eyes and mucous membranes.Even thoug 1120 HYDROGEN PEROXIDE AQUEOUS SOLUTION with not less than 8% but less than20% hydrogen peroxide 5.1 2984 3 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, expect aluminium. 1121 HYDROGEN PEROXIDE STABILIZED with more than 60% hydrogen peroxide (stabilized as necessary) 5.1 2015 2 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increase in contact with metals, except aluminium. Decomposes vigorously in contact with permanganates. When involved in fire, mixtures with combustible material may be explos 1122 HYDROGEN PEROXIDE with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 5.1 2014 2 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increase in contact with metals, except aluminium. In contact with combustible material, may cause fire or explosion. Causes burns to skin, eyes and mucous membranes. Even tho 1123 HYDROGEN REFRIGERATED LIQUID 2.1 1966 2 Liquefied, flammable, odourless gas. Explosive limits: 4% to 75%. Much lighter than air (0.07). 1124 HYDROGEN SELENIDE, ANHYDROUS 2.3 2202 2 Flammable, toxic, colourless gas with a disagreeble odour.Much heavier than air (2.8).Highly irritating to skin,eyes and mucous membranes. 1125 HYDROGEN SULPHIDE 2.3 1053 2 Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.2). 1126 HYDROGENDIFLUORIDES , SOLID N.O.S. 8 1740 2 Crystalline solids. Decomposed by heat or acid, evolving hydrogen fluoride, an extremely irritating and corrosive gas. In the presence of moisture, corrosive to glass, other siliceous materials and most metals. Cause burn to skin, eyes and mucous membranes 1129 HYDROXYLAMINE SULPHATE 8 2865 3 Colourless to white crystalline powder. Soluble in water. May decompose explosively when heated. Causes burns to skin, eyes and mucous membranes. 1130 HYPOCHLORITE SOLUTION 8 1791 3 Liquid with chlorine odour. In contact with acids, evolves very irritating and corrosive gases. Mildly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 1131 HYPOCHLORITES, INORGANIC, N.O.S. 5.1 3212 2 Solids.Critical ambient temperature of decomposition may be as low as 60oC.May cause fire in contact with organic material or ammonium compounds.React with acids,evolving chloride,an irritating,corrosive and toxic gas.In the presence of moisture,corrosive 1132 IGNITERS 1.1G 0121 1 NULL 1133 IGNITERS 1.2G 0314 1 NULL 1134 IGNITERS 1.3G 0315 1 NULL 1135 IGNITERS 1.4G 0325 2 NULL 1136 IGNITERS 1.4S 0454 2 NULL 1137 ISOPROPENYLBENZENE 3 2303 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 38-54oC c.c.Explosive limits:0.7% to 6.6%. 1138 INFECTIOUS SUBSTANCES, AFFECTING HUMANS 6.2 2814 2 Substances which are dangerous to humans or to humans and animals. 1139 INFECTIOUS SUBSTANCES, AFFECTING ANIMALS only 6.2 2900 2 Substances which are dangerous to animals only. For action to be taken in the event of damage to, or leaking from, a package containing infections substances, refer to 7.8.3. 1140 INSECTICIDE GAS TOXIC N.O.S. 2.3 1967 2 Toxic mixtures of insecticides with liquefied gases. These mixtures may be flammable. 1141 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2.1 3354 2 Flammable mixtures of insecticides with liquefied gases. 1142 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 3355 2 Toxic, flammable mixtures of insecticides with liquefied gases. 1143 INSECTICIDE GAS, N.O.S. 2.2 1968 3 Non-flammable and non-toxic mixtures of insecticides with liquefied gases. 1144 IODINE MONOCHLORIDE 8 1792 2 Red, brown or black crystals. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton and straw. In the presence of moisture, high 1145 IODINE PENTAFLUORIDE 5.1 2495 2 Colourless,furming liquid (density 3.75).Powerful oxidant;may cause fire in contact with organic material such as wood,cotton or straw.Reacts violently with water,evolving hydrogen fluoride,a toxic,extremely corrosive gas apparent as white fumes.In contact 1146 IODOMETHYLPROPANES 3 2391 2 Colourless liquids.Immiscible with water. 1147 IODOPROPANES 3 2392 2 Colourless liquids.1-IODOPROPANE: flashpoint 34°C c.c. 2-IODOPROPANE: flashpoint approx. 25°C c.c. Immiscible with water. 1148 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification 4.2 1376 3 Obtain from coal gas purification. Strong odour which may taint other cargo. Liable to heat and ignite spontaneously. May evolve hydrogen sulphide, sulphur dioxide and hydrogen cyanide, which are toxic gases. This substance should have been cooled and weat 1149 IRON PENTACARBONYL 6.1 1994 2 Yellow to dark red, volatile flammable liquid. Flashpoint: -15'C c.c. Explosive limit: 3.7% to 12.5%. May react with water or steam, evolving carbon monoxide, which is a toxic gas. Highly toxic if swallowed, by skin contact or by inhalation. 1150 ISOBUTANE 2.1 1969 2 Flammable hydrocarbon. Heavier than air. 1151 ISOBUTANOL (ISOBUTYL ALCOHOL) 3 1212 3 Colourless liquid with a sweet odour. Partially miscible with water. Flash point : 28oC c.c. Explosive limits : 1.2 to 10.9% 1152 ISOBUTYL ACETATE 3 1213 3 Colourless liquid with a pineapple-like odour. Immiscible with water. Flash point : 18oC c.c. Explosive limits : 1.3 to 10.5% 1153 ISOBUTYL ACRYLATE, STABILIZED 3 2527 3 Colourless liquid with a pungent odour. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 29oC c.c. 1154 ISOBUTYL FORMATE 3 2393 2 Colourless liquid. Irritating to skin, eyes and mucous membranes. Flash point : 5oC c.c. Explosive limits : 1.7% to 8% 1155 ISOBUTYL ISOBUTYRATE 3 2528 3 Colourless liquid with a fruity odour. Immiscible with water. Flash point : 37oC c.c. 1156 ISOBUTYL ISOCYANATE 3 2486 2 Liquid with a pungent odour.Immiscible with water but reacts violently with it,evolving gases.Highly toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 1157 ISOBUTYL METHACRYLATE STABILIZED 3 2283 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 49oC c.c. 1158 ISOBUTYL PROPIONATE 3 2394 3 Colourless liquid. Immiscible with water. Flash point : 31oC c.c. 1159 ISOBUTYLAMINE 3 1214 2 Colourless liquid. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : -9oC c.c. Explosive limits : 3.4 to 9% 1160 ISOBUTYLENE 2.1 1055 2 Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.8%. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air (1.94). 1161 ISOBUTYL ALDEHYDE (ISOBUTYRALDEHYDE) 3 2045 2 Colourless liquid with a characteristic pungent odour. Immiscible with water. Flash point : -24oC . Explosive limits : 1-12% 1162 ISOBUTYRIC ACID 3 2529 3 Colourless liquid with a pungent odour. Miscible with water. Causes burns to skin and eyes. Irritating to skin, eyes and mucous membranes. Flash point : 55oC c.c. Explosive limits : 2% to 2.9% 1163 ISOBUTYRONITRILE 3 2284 2 Colourless liquid. Immiscible with water. Toxic by skin contact or by inhalation. Flash point : 8oC c.c. 1164 ISOBUTYRYL CHLORIDE 3 2395 2 Colourless liquid with a pungent odour.Reacts with water,evolving hydrogen chloride,an irritating and corrosive gas apparent as white fumes.In the presence of moisture,highly corrosive to most metals.Causes burns to skin,eyes and mucous membranes. 1165 ISOCYANATES FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION,FLAMMABLE,TOXIC,N.O.S. 3 2478 2 Flammable toxic liquids with a pungent odour.Immiscible with water but react with it to form carbon dioxide.Toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 1166 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. 6.1 3080 2 Flammable liquids or solutions with a pungent odour. Immiscible with or insoluble in water, but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 1167 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. 6.1 2206 2 Liquids with a pungent odour.Immiscible with water but react with it to form carbon dioxide.Toxic if swallowed, by skin contact or by inhalation.If under deck, with mechanical ventilation, six air changes per hour, except when carried in closed containers, 1168 ISOCYANATOBENZO-TRIFLUORIDES 6.1 2285 2 Colourless or yellowish liquids with a pungent odour.Flashpoint of ortho-and meta-isompers:56'C.Immiscible with water,but reacts with it to form carbon dioxide gas.Toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membr 1169 ISOHEPTENES 3 2287 2 Colourless liquids.Immiscible with water. 1170 ISOHEXENES 3 2288 2 Colourless liquids.Boiling range:54'C to 69'C.Immiscible with water. 1171 ISOOCTENES 3 1216 3 Colourless liquids. Immiscible with water. 1172 ISOPENTENES 3 2371 2 Colourless, volatile liquid with a disagreeable odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point :<-18oC c.c. 1173 ISOPHORONE DIISOCYANATE 6.1 2290 2 Colourless or yellowish liquid.Immiscible with water.When involved in a fire,evolves nitrous fumes.Toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 1174 ISOPHORONEDIAMINE 8 2289 3 Colourless,slightly hygroscopic liquid with a slight amine odour.Combustible.Miscible with water.Harmful if swallowed.Irritating to skin,eyes and mucous membranes. 1175 ISOPRENE, STABILIZED 3 1218 2 Colourless, volatile liquid. Boiling point: 34°C. Immiscible with water. Flash point : -48oC c.c. Explosive limits : 1.5 to 9.7% 1176 ISOPROPANOL (ISOPROPYL ALCOHOL) 3 1219 3 Colourless, mobile liquid. Miscible with water. Flash point : 12oC c.c. Explosive limits : 2 to 12% 1177 ISOPROPENYL ACETATE 3 2403 3 Colourless liquid. Immiscible with water. Flash point : 10oC c.c. 1178 ISOPROPYL ISOBUTYRATE 3 2406 2 Colourless liquid. Immiscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. Flash point : 20oC c.c. 1179 ISOPROPYL ACETATE 3 1220 3 Colourless liquid with an aromatic odour. Immiscible with water. Flash point : 11oC c.c. Explosive limits : 1.8 - 7.8% 1180 ISOPROPYL ACID PHOSPHATE 8 1793 3 Oily liquid. Midly corrosive to most metals. 1181 ISOPROPYL BUTYRATE 3 2405 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 25oC c.c. 1182 ISOPROPYL CHLOROACETATE 3 2947 3 Colourless liquid with a pungent odour. Slightly soluble in water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. flash point : 56oC c.c. 1183 ISOPROPYL CHLOROFORMATE 6.1 2407 2 Colourless flammable liquid.Flashpoint:16oC c.c.Decomposed by water,evolving hydrogen chloride,an irritating and corrosive gas apparent as white fumes.In the presence of moisture,corrosive to most metals.Highly toxic if swallowed,by skin contact or by inha 1184 ISOPROPYL ISOCYANATE 3 2483 2 Liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases.Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : -10 to 0 oC c.c. 1185 ISOPROPYL NITRATE 3 1222 2 Colourless liquid. Immiscible with water. May explode on heating. Harmful by inhalation. Flash point : 12oC c.c. Explosive limits : up to 100% 1186 ISOPROPYL PROPIONATE 3 2409 2 Colourless liquid. Immiscible with water. Flash point : 21oC c.c. 1187 ISOPROPYL-2-CHLOROPROPIONATE 3 2934 3 Colourless liquid with a sweetish odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 50oC c.c. 1188 ISOPROPYLAMINE 3 1221 2 f/p: -37oC c.c. Colourless, volatile liquid with an ammonia-like odour. Boiling point: 32°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. 1189 ISOPROPYLBENZENE 3 1918 3 f/p : 31oC c.c. Colourless liquid with a chloroform-like odour. Immiscible with water. 1190 ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose mannose,starch or calcium hydrogen phosphate 4.1 2907 2 Desensitized explosive. Pure isosorbide dinitrate is explosive. May form extremely sensitive compounds with heavy metals or their salts. 1191 ISOSORBIDE-5-MONONITRATE 4.1 3251 2 May explode if involved in a fire under confined conditions.Sensitive to strong detonation shoch. 1192 JET PERFORATING GUN CHARGED oil well, without detonator 1.1D 0124 1 1193 JET PERFORATING GUNS, CHARGED, oil well, without detonator 1.4D 0494 2 NULL 1194 KEROSENE 3 1223 3 Immiscible with water 1195 KETONES LIQUID, N.O.S. 3 1224 3 NULL 1196 KRYPTON, COMPRESSED 2.2 1056 3 Inert gas. Much heavier than air (2.9) 1197 KRYPTON, REFRIGERATED LIQUID 2.2 1970 3 Liquefied, inert gas. Much heavier than air (2.9). 1198 LEAD ACETATE 6.1 1616 3 White crystals, or brown or grey lump. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1199 LEAD ARSENATES 6.1 1617 3 White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1200 LEAD ARSENITES 6.1 1618 3 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1201 LEAD AZIDE, WETTED with not less 20% water, or mixture of alcohol and water, by mass 1.1A 0129 1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost.This substance, when containing less alcohol, water or phlegmatizer than specified,shall not be transported,unless specifically authorized by the compe 1202 LEAD COMPOUNDS,SOLUBLE, N.O.S. 6.1 2291 3 Colourless crystals or powder.Soluble in water.Toxic if swallowed,by skin contact or by dust inhalation. 1203 LEAD CYANIDE 6.1 1620 2 White powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1204 LEAD DIOXIDE 5.1 1872 3 Brown powder or crystals. Insoluble in water. Harmful if swallowed. 1205 LEAD NITRATE 5.1 1469 3 White crystals. Soluble in water mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 1207 LEAD PERCHLORATE, SOLID 5.1 1470 2 White crystals or powder. Soluble in water. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to i 1208 LEAD PHOSPHITE DIBASIC 4.1 2989 2 Fine white crystals or powder. Insoluble in water. Combustion can be sustained, even in the absence of air. Harmful if swallowed. 1209 LEAD STYPHNATE (LEAD TRINITRORESORCINATE) WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1A 0130 1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost.This substance, when containing less alcohol, water or phlegmatizer than specified,shall not be transported,unless specifically authorized by the compe 1210 LEAD SULPHATE, with more than 3% free acid 8 1794 3 May be dry solid or slurry. Corrosive to most metals. Harmful if swallowed. 1211 LIFE-SAVING APPLIANCES NOT SELF- INFLATING 9 3072 3 These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fireboard inner packagings; .3 electric storage batteries; .4 first a 1212 LIFE-SAVING APPLIANCES, SELF-INFLATING 9 2990 3 These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fibreboard inner packaging; .3 electric storage batteries; .4 first a 1213 LIGHTER or LIGHTER REFILLS containing flammble gas 2.1 1057 2 Lighter or lighter refills containing butane or other flammable gas. 1214 LIGHTERS, FUSE 1.4S 0131 2 NULL 1215 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2.1 3161 2 NULL 1216 LIQUEFIED GAS, N.O.S. 2.2 3163 3 1217 LIQUEFIED GAS, OXIDIZING, N.O.S. 2.2 3157 2 1218 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 3308 2 NULL 1219 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2.3 3309 2 NULL 1220 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 3160 2 NULL 1221 LIQUEFIED GAS, TOXIC, N.O.S. 2.3 3162 2 NULL 1222 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2.3 3310 2 1223 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 3307 2 NULL 1224 LIQUEFIED GASES, non-flammable charged with nitrogen, carbon dioxide or air 2.2 1058 3 Non-flammable gases or mixture of such gases which are used for filling receptacles from which the contents are to be dispersed under pressure. Vapour may be heavier than air. 1226 LITHIUM ALUMINIUM HYDRIDE 4.3 1410 2 White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1227 LITHIUM ALUMINIUM HYDRIDE ethereal 4.3 1411 2 Clear, colourless solution of lithium aluminium hydride in ether. Reacts readily with water, evolving hydrogen, a flammable gas. Evaporates readily to leave a residue which is easily ignited by a spark or friction. 1228 LITHIUM METAL BATTERIES 9 3090 3 Electrical batteries containing lithium encased in a rigid metallic body. Lithium batteries may also be shipped in, or packed with, equipment. Electrical lithium batteries may cause fire due to an explosive rupture of the body caused by improper constructi 1229 LITHIUM METAL BATTERIES IN EQUIPMENT or LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT 9 3091 3 NULL 1230 LITHIUM BOROHYDRIDE 4.3 1413 2 Crystalline, hydroscopic solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1231 LITHIUM FERROSILICON 4.3 2830 2 Dark, crystalline, metal-like powder or brittle lumps. In contact with moisture, evolves flammable and toxic gases. 1232 LITHIUM HYDRIDE 4.3 1414 2 NULL 1233 LITHIUM HYDRIDE, FUSED SOLID 4.3 2805 2 White, crystalline mass. Reacts with water, moisture or acids, evolving hydrogen which may be ignited by the heat of the reaction. 1234 LITHIUM HYDROXIDE MONOHYDRATE 8 2680 3 Colourless crystals. Soluble in water. Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 1235 LITHIUM HYDROXIDE SOLUTION 8 2679 3 Colourless liquid. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1236 LITHIUM HYPOCHLORITE DRY OR LITHIUM HYPOCHLORITE MIXTURE,DRY 5.1 1471 2 White powder with pungent odour. Soluble in water. Critical ambient temperature of decomposition may be as low as 60'C. May cause fire in contact with organic material or ammonium compounds. Reacts with acids, evolving chlorine, an irritating, corrosive an 1237 LITHIUM NITRATE 5.1 2722 3 Colourless deliquescent crystals. Soluble in water. Mixtures with combustible materials are readily ignited and burn fiercely. Harmful if swallowed. 1238 LITHIUM NITRIDE 4.3 2806 2 Brownish-red crystals or fine, free-flowing powder. Reacts slowly with water to form lithium hydroxide and ammonia. 1239 LITHIUM PEROXIDE 5.1 1472 2 White powder. Soluble in water. Solution in water is an alkaline corrosive liquid. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact wi 1240 LITHIUM SILICON 4.3 1417 2 Shiny lumps, crystals or powder, with sharp irritating odour. Reacts readily with water, evolving hydrogen and silane, flammable gases. Enough heat may be generated to ignite the gas mixture in air. 1241 LITHIUM, non-pyrophoric 4.3 1415 2 White, ductile, soft metal. Floats on water. Readily decomposes in water and react violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. For fire-fighting purposes, dry lithium chloride powder, dry sodium chloride or gr 1242 LONDON PURPLE 6.1 1621 3 Mixture of arsenic trioxide, lime and ferric oxide, used as an insecticide. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1244 MAGNESIUM ALUMINIUM PHOSPHIDE 4.3 1419 2 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1245 MAGNESIUM and MAGNESIUM ALLOY with more than 50% magnesium in pellets, turning or ribbon 4.1 1869 3 Silvery white metal. Burns with an intense white light and heat. In contact with water, especially seawater, may evolve hydrogen, a flammable gas. Reacts readily with acids and caustic alkali, evolving hydrogen. Reacts readily with iron oxide, producing a 1246 MAGNESIUM ARSENATE 6.1 1622 3 White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1247 MAGNESIUM BROMATE 5.1 1473 2 White deliquescent crystals or crystalline powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with comboustible material, powdered metals or ammonium compound 1248 MAGNESIUM CHLORATE 5.1 2723 2 White deliquescent crystals or powder. Soluble in water. Melting point: 35'C. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible materials, powdered metals or ammoni 1249 MAGNESIUM DIAMIDE 4.2 2004 2 White powder. Ignites spontaneously in air. Reacts violently in contact with water. 1251 MAGNESIUM FLUOROSILICATE 6.1 2853 3 Solids which reacts with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 1252 MAGNESIUM GRANULES COATED 4.3 2950 2 Coated granules with particle size ranging from 149 to 2000 microns. In contact with water or acids, evolve hydrogen, a flammable gas. 1253 MAGNESIUM HYDRIDE 4.3 2010 2 White crystals. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1254 MAGNESIUM NITRATE 5.1 1474 3 White deliquescent crystals, soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1255 MAGNESIUM PERCHLORATE 5.1 1475 2 White deliquescent crystals or crystalline powder. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with comboustible material, powdered metals or ammonium compounds. These mixtures 1256 MAGNESIUM PEROXIDE 5.1 1476 2 White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Harmful if swallowed. 1257 MAGNESIUM PHOSPHIDE 4.3 2011 2 Solid. React with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1258 MAGNESIUM POWDER OR MAGNESIUM ALLOYS POWDER containing more than 50% magnesiumnnon-pyrophoric 4.3 1418 2 In contact with moisture, water or acids, evolves hydrogen, a flammable gas. Magnesium dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. For fire-fighting purposes, dry lithium chloride powder, dry sodium chl 1259 MAGNESIUM SILICIDE 4.3 2624 2 White powder or crystals. Reacts with water or steam, evolving hydrogen, a flammable gas. In contact with acids, evolves silane, a spontaneously flammable gas. 1260 MALEIC ANHYDRIDE, MOLTEN 8 2215 3 Melting point:about 53'C.The vapour of the molten substance has a flaspoint of 103'C c.c.and forms a flammable atmosphere with explosive limits of 1.4% to 7.1%.Fumes are irritating to skin,eyes and mucous membranes. 1261 MALEIC ANHYDRIDE 8 2215 3 White powder,needles,flakes,pellets,rods,briquettes,lumps or fused mass.Melting point:about 53%.Fumes and dust are irritating to skin,eyes and mucous membranes.Inhalation can cause respiratory trouble. 1262 MALONONITRILE 6.1 2647 3 Colourless crystals. Melting point: 32'C. Soluble in water. When heated, evolves highly toxic cyanogen fumes. Toxic if swallowed, by skin contact or by dust inhalation. 1263 MANEB, STABILIZED or MANEB PREPARATION stabilised against self-heating 4.3 2968 2 Yellow powder. May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids. Requires certification from the shipper that the substance is not class 4.2. 1264 MANEB or MANEB PREPARATION with not less than 60% maneb 4.2 2210 2 Yellow powder,liable to heat and to ignite spontaneously in air.May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids.Used as fungicide. 1265 MANGANESE NITRATE 5.1 2724 3 Pale pink deliquescent crystals. Soluble in water. Melting point between 26'C and 35'C. Mixtures with combustible material are readily ignited and may burn fiercely. Soluble in water are slightly corrosive. Harmful if swallowed. 1266 MANGANESE RESINATE 4.1 1330 3 Very dark brown solid. Insoluble in water.Liable to spontaneous heating.Irritating to skin,eyes and mucous membranes. 1267 MANNITOL HEXANITRATE (NITROMANNITE),WETTED with not less than 40% water,or mixture of alcohol and water, by mass 1.1D 0133 1 This substance, when containing less alcohol,water or phlegmatizer than specified,shall not be transported,unless specifically authorized by the competant authority. 1268 MATCHES, "STRIKE ANYWHERE" 4.1 1331 2 Ignite by friction;prepared surface is not required. 1269 MATCHES, FUSEE 4.1 2254 3 Matches,the heads of which are prepared with a friction-sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat, regardless of wind or other weather conditions. 1270 MATCHES SAFETY 4.1 1944 3 Intended to be ignited on a specially prepared surface. 1271 MATCHES WAX "VESTA" 4.1 1945 3 Ignite by friction; a prepared surface may be required. 1272 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 3248 2 Toxic if swallowed,by skin contact or by inhalation. 1273 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 3249 3 Toxic if swallowed,by skin contact or by inhalation. 1274 MEDICINES, LIQUID, TOXIC, N.O.S 6.1 1851 3 Toxic if swallowed, by skin contact or by inhalation. 1275 MERCAPTANS LIQUID , FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 1228 2 Colourless to yellow liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1276 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S.or MERCAPTAN MIXTURE, LIQUID FLAMMABLE, N.O.S. 3 3336 2 Colourless to yellow liquids with garlic odour. Immiscible with water. 1277 MERCAPTANS LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1 3071 2 Colourless to yellow flammable liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1278 MERCURIC ARSENATE 6.1 1623 3 Yellow crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1279 MERCURIC CHLORIDE 6.1 1624 3 White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1280 MERCURIC NITRATE 6.1 1625 3 White, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1281 MERCURIC POTASSIUM CYANIDE 6.1 1626 2 Colourless crystals. Soluble in water. Reacts with acids, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1282 MERCURY SULPHATE 6.1 1645 3 White crystals or powder. Decomposes in water, forming sulphuric acid. Toxic if swallowed, by skin contact or by dust inhalation. 1283 MERCUROUS NITRATE 6.1 1627 3 Crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1284 MERCURY ACETATE 6.1 1629 3 White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1285 MERCURY AMMONIUM CHLORIDE 6.1 1630 3 White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1286 MERCURY-BASED PESTICIDES, LIQUID, TOXIC, FLAMMABLE 6.1 3011 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 1287 MERCURY-BASED PESTICIDES, SOLID, TOXIC 6.1 2777 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1288 MERCURY-BASED PESTICIDES, LIQUID, TOXIC 6.1 3012 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1289 MERCURY BENZOATE 6.1 1631 3 White crystals. Toxic if swallowed, by skin contact or by dust inhalation. 1290 MERCURY BROMIDES 6.1 1634 3 White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1291 MERCURY COMPOUNDS, LIQUID, N.O.S. 6.1 2024 3 Toxic if swallowed, by skin contact or by inhalation. 1292 MERCURY COMPOUNDS, SOLID N.O.S. 6.1 2025 3 Toxic if swallowed, by skin contact or by dust inhalation. 1293 MERCURY CYANIDE 6.1 1636 2 White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1294 MERCURY FULMINATE, WETTED with not less 20% water, or mixture of alcohol and water, by mass 1.1A 0135 1 Sensitive substance used in detonators which will becomes extemely sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically a 1295 MERCURY GLUCONATE 6.1 1637 3 Solids. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1296 MERCURY IODIDE 6.1 1638 3 Red crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1297 MERCURY metal 8 2809 3 A silvery metallic element occuring in the liquid state at normal temperatures. Relative density: 13.546. Melting point: -39'C. Highly corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage o 1298 MERCURY NUCLEATE 6.1 1639 3 Brown powder containing about 20% mercury. Toxic if swallowed, by skin contact or by dust inhalation. 1299 MERCURY OLEATE 6.1 1640 3 Yellow oily paste. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 1300 MERCURY OXIDE 6.1 1641 3 Orange powder. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 1301 MERCURY OXYCYANIDE, DESENSITIZED 6.1 1642 2 White crystals or powder. React with acids and acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust inhalation. Should be sufficiently phlegmatized (merc 1302 MERCURY POTASSIUM IODIDE 6.1 1643 3 Yellow, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1303 MERCURY SALICYLATE 6.1 1644 3 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1304 MERCURY THIOCYANATE 6.1 1646 3 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1305 MERCURY-BASED PESTICIDES, LIQUID, FLAMMABLE, TOXIC 3 2778 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 1306 MESITY OXIDE 3 1229 3 Colourless, oily liquid with a sweet odour. Miscible with water. Flash point : 32oC c.c. 1307 METAL ALKYL HALIDES, WATER-REACTIVE, N.O.S. 4.2 3049 2 NULL 1308 METAL ALKYL HYDRIDES, WATER-REACTIVE, N.O.S. 4.2 3050 2 NULL 1311 METAL CARBONYL, N.O.S., LIQUID 6.1 3281 3 A range of metal carbonyls which,when heated,can give off carbon monoxide,a toxic gas.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1312 METAL CATALYST, DRY 4.2 2881 2 Liable to ignite spontaneously in air. 1313 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 3182 2 1314 METAL HYDRIDES, WATER REACTIVE, N.O.S. 4.3 1409 2 Solids. React with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1315 METAL POWDER, SELF-HEATING, N.O.S. 4.2 3189 2 Forms explosive mixtures with oxidizing substances. 1316 METAL POWDERS FLAMMABLE N.O.S. 4.1 3089 2 NULL 1317 METAL SALTS OF ORGANIC COMPOUNDS FLAMMABLE N.O.S. 4.1 3181 2 Decomposes in water.Liable to spontaneous heating.Irritating to skin and mucous membranes. 1318 METALDEHYDE 4.1 1332 3 White crystals, powder or tablets.Insoluble in water.Harmful if swallowed or by dust inhalation. 1319 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 3208 2 NULL 1320 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 4.3 3209 2 NULL 1321 METHACRYLALDEHYDE, STABILIZED 3 2396 3 Colourless liquid. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 2oC c.c. 1322 METHACRYLIC ACID, STABILIZED 8 2531 3 Colourless,combustible liquid with a specific odour.Miscible with water.Polymerizes readily above its melting point (15oC),thereby generating heat and possible risk of explosion;should therefore be properly stabilized.Coiling below melting point (15oC) fol 1323 METHACRYLONITRILE, STABILIZED 3 3079 2 Colourless, mobile liquid with a pungent odour. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals. Flash poi 1324 METHALLYL ALCOHOL 3 2614 3 Colourless liquid with a pungent odour. Miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 34oC c.c. 1325 METHANE COMPRESSED OR NATURAL GAS COMPRESSED with a high methane 2.1 1971 2 Flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). 1326 METHANE REFRIGERATED LIQUID or NATURAL GAS REFRIGERATED LIQUID 2.1 1972 2 Liquefied, flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). 1327 METHANESULPHONYL CHLORIDE 6.1 3246 2 Pale yellow liquid.Highly toxic if swallowed,by skin contact or by inhalation.Causes burns to skin,eyes and mucous membranes. 1328 METHANOL 3 1230 2 Colourless, volatile liquid. Miscible with water. Toxic if swallowed; may cause blindness. Avoid skin contact. Flash point : 11-25oC c.c. Explosive limits : 6-36.5% 1329 METHOXYMETHYL ISOCYANATE 3 2605 2 Colourless liquid with a pungent odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 13oC c.c. 1330 METHYL ACETATE 3 1231 3 Colourless, volatile liquid with a fragrant odour. Miscible with water. Flash point : -10oC c.c. Explosive limits : 3-16% 1331 METHYL ACRYLATE, STABILIZED 3 1919 3 Colorless, volatile liquid with a pungent odour. Flashpoint: -3'C c.c. Explosive limits: 1.2% to 25%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 1332 METHYL BROMIDE with not more than 2.0% chloropicrin 2.3 1062 2 Liquefied, toxic gas with a chloroform-like odour. Much heavier than air (3.3). Boiling point: 4.5C. Even though this substance has a flammable hazard, it only exhibits such hazard under extreme fire conditions in confined areas. 1333 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 6.1 1647 2 Solutions of methyl bromide gas, evolving toxic vapour. Methyl bromide has a boiling point of approximately 4'C. Highly toxic if swallowed, by skin contact or by inhalation. 1334 METHYL BROMOACETATE 6.1 2643 3 Colourless to straw-coloured liquid. Slightly miscible with water. Causes tears. Toxic if swallowed, by skin contact or by inhalation. 1335 METHYL BUTYRATE 3 1237 3 Colourless liquid. Immiscible with water. Flash point : 14oC c.c. 1336 METHYL CHLORIDE (REFRIGERANT GAS R 40) 2.1 1063 3 Liquefied, flammable gas. Explosive limits: 8% to 20%. Heavier than air (1.8). 1337 METHYL CHLORIDE and METHYLENE CHLORIDE mixture 2.1 1912 2 Solution of the flammable gas methyl chloride, UN No. 1063, in the liquid methylene chloride. 1338 METHYL CHLOROACETATE 6.1 2295 2 Colourless,flammable liquid with a pungent odour.Flashpoint:47'C c.c.Vapour much heavier than air (vapour density relative to air:3:8).Immiscible with water.Highly toxic if swallowed,by skin contact or by inhalation. 1339 METHYL CHLOROFORMATE 6.1 1238 2 Colourless liquid. Flashpoint: 5'C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1340 METHYL CHLOROMETHYL ETHER 6.1 1239 2 Colourless liquid. Flashpoint: below -18'C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1341 METHYL DICHLOROACETATE 6.1 2299 3 Liquid.Toxic if swallowed,by skin contact or by inhalation. 1342 METHYL FLUORIDE (REFRIGERANT GAS R 41) 2.1 2454 2 Flammable,colourless gas.Heavier than air (1.2). 1343 METHYL FORMATE 3 1243 2 Colourless liquid with an agreeable odour. Boiling point: 32°C. Miscible with water. Flash point : -32oC c.c. Explosive limits : 5-22.7% 1344 METHYL IODIDE 6.1 2644 3 Colourless liquid. Boiling point: 42'C to 43'C. Slightly miscible with water. When heated, evolves toxic fumes. Highly toxic if swallowed, by skin contact or by inhalation. Has strong narcotic effects. 1345 METHYL ISO BUTYL CARBINOL 3 2053 3 F/p : 41oC c.c. Colourless liquid. Miscible with water. Harmful by inhalation. 1346 METHYL ISOBUTYL KETONE 3 1245 3 Colourless liquid with a pleasant odour. Immiscible with water. Flash point : 14oC c.c. Explosive limits : 1.4 to 7.5% 1347 METHYL ISOCYANATE 6.1 2480 2 Flammable liquid with a pungent odour.Flashpoint:-7oC c.c.(pure product).Boiling point:38oC (pure product).Vapour heavier than air.Immiscible with water but reacts violently with it.In contact with water or acids,evolves highly toxic nitrous fumes.Highly t 1348 METHYL ISOPROPENYL KETONE, STABILIZED 3 1246 2 Colourless liquid with a pleasant odour. Explosive limits: 1.8% to 9%. Immiscible with water. 1349 METHYL ISOTHIOCYANATE 6.1 2477 2 White crystals.Usually shipped as an oily liquid with a flashpoint below 60oC c.c. (pure substance).Flashpoint:32oC c.c. (pure subtance).Insoluble in water.When involved in a fire,evolves toxic gases.Highly toxic if swallowed,by skin contact or by inhalati 1350 METHYL ISOVALERATE 3 2400 2 Colourless liquid.Immiscible with water. 1351 METHYL MERCAPTAN 2.3 1064 2 Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.7). Boiling point: 6'C. 1352 METHYL METHACRYLATE, MONOMER, STABILIZED 3 1247 2 Colourless, volatile liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 8 degree C c.c. Explosive limits : 1.5 to 11.6% 1354 METHYL NITRITE 2.2 2455 3 Transport is prohibited. 1355 METHYL ORTHOSILICATE 6.1 2606 2 Colourless, flammable liquid with an ethereal odour. Immiscible with water. Flashpoint: -18'C to 19'C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause blindness. 1356 METHYL PROPIONATE 3 1248 2 Colourless liquid. Immiscible with water. Flash point : -2oC c.c. Explosive limits : 2.4 to 13% 1357 METHYL PROPYL ETHER 3 2612 2 Colourless, volatile liquid with an ethereal odour. Boiling point: 39°C. Partially miscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. Flash point : <-18oC c.c. 1358 METHYL PROPYL KETONE 3 1249 3 Colourless liquid. Immiscible with water. Flash point : 7oC c.c. Explosive limits : 1.5 to 8.2% 1359 METHYL TRICHLOROACETATE 6.1 2533 3 Colourless liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1360 METHYL VINYL KETONE, STABILIZED 6.1 1251 3 Colourless liquid with an ammonia-like odour. Flashpoint: -7'C c.c. Explosive limits: 2.1% to 15.6%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1361 METHYL-2-CHLOROPROPIONATE 3 2933 3 Colourless liquid with an ether-like odour. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. Flash point : 32oC c.c. 1362 METHYLACETYLENE AND PROPADIENE mixture, stabilized 2.1 1060 2 Flammable gas. Explosive limit: 3% to 11%. Heavier than air (1.4). 1363 METHYLAL 3 1234 2 Colourless, volatile liquid with a chloroform-like odour. Boiling point: 42°C. Miscible with water. Irritating to skin, eyes and mucous membranes. flash point : -28oC c.c. Explosive limits : 3.6 t o 12.6% 1364 METHYL ALLYL CHLORIDE 3 2554 2 Colourless to yellowish, volatile liquid with a penetrating odour. Immiscible with water. When involved in a fire, may evolve highly toxic phosgene gas. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : -12oC c.c. Explosiv 1365 METHYLAMINE anhydrous 2.1 1061 2 Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.9). 1366 METHYLAMINE, AQUEOUS SOLUTION 3 1235 2 Aqueous solution of a flammable gas having an ammonia-like odour. Boiling point:-7°C (pure product). Commercial product is a 40% solution with: boiling point 48°C, flashpoint-13°C c.c. Miscible with water. May react explosively with mercury. Harmful by i 1367 METHYLAMYL ACETATE 3 1233 3 Colourless liquid. Immiscible with water. Flash point : 43oC c.c. 1368 METHYLCHLOROSILANE 2.3 2534 2 Liquefied,flammable,toxic and corrosive colourless gas with a pungent odour.Reacts with water,evolving hydrogen chloride,an irritating and corrosive gas.Heavier than air.Boiling point:9oC.Highly irritating to skin,eyes and mucous membranes. 1369 METHYLCYCLOHEXANE 3 2296 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : -4oC c.c. Explosive limits : 1.25 to 6.7% 1370 METHYLCYCLOHEXANOLS, flammable 3 2617 3 Colourless, viscous liquid with a menthol-like odour. Partially miscible with water. Flash point : 58oC c.c. 1371 METHYLCYCLOHEXANONE 3 2297 3 Colourless to pale yellow liquids with a sweet odour. 2-METHYLCYCLOHEXANONE: flashpoint 46°C c.c. 3-METHYLCYCLOHEXANONE: flashpoint 51°C c.c. 4-METHYLCYCLOHEXANONE: flashpoint 40°C c.c. Immiscible with water. 1372 METHYLCYCLOPENTANE 3 2298 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : <-10oC c.c.Explosive limits:1% to 8.4%. 1373 METHYLDICHLOROSILANE 4.3 1242 2 Colourless, very volatile liquid with a pungent odour. Flashpoint: -26'C c.c. Explosive limits: 4.5% to 70%. Boiling point: 41'C. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosiv 1374 METHYLHYDRAZINE 6.1 1244 2 Colourless liquid with an ammonia-like odour. Flashpoint: 20'C c.c. Explosive limits: 2.5% to 98%. Miscible with water. React violently with acid. May react dangerously with oxidizing substance. Highly toxic if swallowed, by skin contact or by inhalation. 1375 METHYLMAGNESIUM BROMIDE IN ETHYL ETHER 4.3 1928 2 Colourless, yellowish liquid. Decomposes violently in contact with water. Spillage will ignite spontaneously. 1376 METHYLPENTADIENES 3 2461 2 Flaspoint:< -18oC c.c. Colourless liquids. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1377 METHYLPHENYL-DICHLOROSILANE 8 2437 2 Colorless liquid.Reacts with water,evolving hydrogen chloride,an irritating and corrosive gas apparent as white fumes.When involved in a fire,evolves toxic gases.In the presence of moisture,highly corrosive to most metals.Causes burns to skin,eyes and muco 1378 METHYL tert-BUTYL ETHER 3 2398 2 Colourless liquid. Boiling point: 55°C. Immiscible with water. Flash point : <-18oC c.c. Explosive limits: 1.7% - 8.4% 1379 METHYLTETRAHYDROFURAN 3 2536 2 Colourless, volatile liquid with an ether-like odour. Immiscible with water. Flash point :-11oC c.c. 1380 METHYLTRICHLOROSILANE 3 1250 2 Colourless liquid with a pungent odour. Immiscible with water. Readily hydrolyzed by moisture evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin 1381 MINES with bursting charge 1.1F 0136 1 NULL 1382 MINES with bursting charge 1.1D 0137 1 NULL 1383 MINES with bursting charge 1.2D 0138 1 NULL 1384 MINES with bursting charge 1.2F 0294 1 NULL 1385 MOLYBDENUM PENTACHLORIDE 8 2508 3 Black or green-black.Hygroscopic.Reacts violently with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.Harmful if swallowed.Dust and vopour irritate skin,eyes and mucous membranes. 1386 MORPHOLINE 8 2054 2 Colourless liquid with a fishy odour.Flashpoint:38C o.c.Explosive limits:2% to 11.2%.Miscible with water.Harmful by skin contact or by inhalation.Corrosive to skin, eyes and mucous membranes. 1387 MOTOR FUEL ANTI-KNOCK mixture 6.1 1649 2 Volatile liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble in water. Highly toxic if swallowed, by skin contact or by inhalation. 1388 MOTOR SPIRIT or GASOLINE OR PETROL 3 1203 2 flash point : -40oC c.c. 1389 N,N-DIETHYLANILINE 6.1 2432 3 Colourless to yellow-brownoily liquid.Combustible.Toxic if swallowed,by skin contact or by inhalation. 1390 N,N-DIETHYLENEDIAMINE 8 2685 2 Colourless, flammable liquid with a fishy odour. Flashpoint: 46'C c.c. Miscible with water. Harmful by skin contact. Irritating to eyes and mucous membranes. 1391 N,N-DIMETHYLANILINE 6.1 2253 3 Yellowish to brownish oily liquid.Combustile.Toxic if swallowed,by skin contact or by inhalation 1392 DIMETHYLCARBAMOYL CHLORIDE 8 2262 3 Colourless to yellow liquid with a pungent odour.Immiscible with water.Reacts with water,evolving toxic and corrosive fumes.Causes tears.Causes burns to skin,eyes and mucous membranes. 1393 N,N-DIMETHYL-CYCLOHEXYLAMINE 8 2264 2 Colourless,flammable liquid.Flaspoint:43'C c.c.Partially miscible with water.Causes burns to skin,eyes and mucous membranes. 1394 N N-DI-n-BUTYLAMINOETHANOL 6.1 2873 3 Colourless liquid with a perceptible odour. Immiscible with water. Toxic if swallowed, by skin contactor by inhalation. 1395 N,N-DIMETHYLFORMAMIDE 3 2265 3 Colourless liquid. Miscible with water. May react violently with oxidizing materials. Flash point : 58oC c.c. Explosive limits : 2.2% to 16% 1396 DIMETHYL-N-PROPYLAMINE 3 2266 2 Colourless liquid with a fishy odour. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Flash point : -11oC c.c. 1397 N-AMINOETHYLPIPERAZINE 8 2815 3 Yellow liquid. Miscible with water. Corrosive to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 1398 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 4.1 1334 3 Crystalline flakes or powder with a persistent odour.Evolves flammable vapours at, or below, its melting point. 1399 NAPHTHYLTHIOUREA 6.1 1651 3 White crystals or powder. Toxic if swallowed, by skin contact or by inhalation. 1400 NAPHTHYLUREA 6.1 1652 3 Crystals or powder. Toxic if swallowed, by skin contact or by inhalation. 1401 NAPTHALENE, MOLTEN 4.1 2304 2 Molten liquid with a persistent odour.Melting point:80oC.Evolves flammable vapours.As the melting point of naphthalene approximates very closely its flaspoint,care should be taken to avoid all possible causes of ignition.Contact between water and molten na 1402 NEON compressed 2.2 1065 3 Inert gas. Lighter than air (0.7). 1403 NEON refrigerated liquid 2.2 1913 3 NULL 1404 N-ETHYLANILINE 6.1 2272 3 Colourless to yellowish oily liquid.Reacts with acids,evolving highly toxic fumes of aniline and oxides of nitrogen .Reacts violently with oxidizing substances.Toxic if swallowed,by skin contact or by inhalation. 1405 N-ETHYL-N-BENZYLANILINE 6.1 2274 3 Light yellow,oily liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1406 N-ETHYLBENZYLTOLUIDINES, LIQUID 6.1 2753 3 Liquids with a strong odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1408 N-ETHYLTOLUIDINES 6.1 2754 2 Colourless to light amber flammable liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1409 NICKEL CARBONYL 6.1 1259 2 Colourless or yellow volutile, flammable liquid. Flashpoint: below -20'C c.c. Oxidizes in air and explodes at a temperature of 60'C. Lower explosive limit: 2.0%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1410 NICKEL CATALYST WETTED with a visible excess of liquid. 4.2 1378 2 Liable to ignite spontaneously if dry. 1411 NICKEL CYANIDE 6.1 1653 2 Green crystals or powder. Insoluble in water. React with acids and acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 1412 NICKEL NITRATE 5.1 2725 3 Green deliquescent crystals. Soluble in water. Melting point: 55'C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 1413 NICKEL NITRITE 5.1 2726 2 Reddish-yellow crystals. Decomposes if heated, giving off toxic nitrous fumes. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. 1414 NICOTINE 6.1 1654 3 Thick colourless oil, turning brown on exposure to air. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1415 NICOTINE COMPOUND, LIQUID, N.O.S.or NICOTINE PREPARATIONS, LIQUID, N.O.S. 6.1 3144 2 A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 1416 NICOTINE COMPOUNDS, SOLID, N.O.S. 6.1 1655 3 A wide variety of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 1417 NICOTINE HYDROCHLORIDE, LIQUID 6.1 1656 3 Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1419 NICOTINE SALICYLATE 6.1 1657 3 White crystals. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1420 NICOTINE SULPHATE SOLUTION 6.1 1658 3 Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1422 NICOTINE TARTRATE 6.1 1659 3 White crystals. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1423 NITRATES, INORGANIC, AQUEOUS SOLUTION N.O.S. 5.1 3218 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 1424 NITRATES INORGANIC N.O.S. 5.1 1477 2 Solids. Solid mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1425 NITRATING ACID, MIXTURE 8 1796 2 Mixture of concentrated nitric and sulphuric acids. Oxidant; may cause fire in contact with organic materials such as wood, cotton and straw, developing highly toxic gas (brown fumes). Highly corrosive to most metals. Cuases severe burns to skin, eyes and 1426 NITRATING ACID, MIXTURE, SPENT 8 1826 2 Usually a mixture of acids which has been used for nitration processes. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. Prohibited for shipment unless the mixture is (1) chemically stable; and (2) certified as conta 1427 NITRIC ACID other than red fuming, with more than 70% nitric acid 8 2031 2 Colourless liquid.Powerful oxidant;may cause fire in contact with organic materials such as wood,cotton or straw.evolving highly toxic gases(brown fumes).Highly corrosive to most metals.Causes severe burns to skin,eyes and mucous membranes. 1428 NITRIC ACID, RED FUMING 8 2032 2 Brown liquid.Powerful oxidant;may cause fire in contact with organic materials such as wood,cotton or straw.Highly corrosive to most metals.Toxic if swallowed,by skin contact or by vapour inhalation.Causes severe burns to skin,eyes and mucous membranes. 1429 NITRIC OXIDE AND DINITROGEN TETROXIDE mixture (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 2.3 1975 2 Non flammable, toxic and corrosive, brown gas mixtures of varying composition with a pungent odour. Strong oxidizing agent. Heavier than air. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect similar to phosgene 1430 NITRIC OXIDE COMPRESSED 2.3 1660 2 Non-flammable, toxic and corrosive gas. Strong oxidizing agent. On contact with air, gives off brown fumes which are toxic by inhalation, with delayed effect similar to phosgene. Heavier than air (1.04). Highly irritating to skin, eyes and mucous membranes 1431 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 3273 2 Liquids evolving toxic vapour.React with acids or acid fumes,evolving hydrogen cyanide,a highly toxic and flammable gas.Toxic if swallowed,by skin contact or by inhalation. 1432 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 3275 2 Flammable liquids,evolving toxic vapour.React with acids or acid fumes,evolving hydrogen cyanide,a highly toxic and flammable gas.Miscible with water.Toxic if swallowed,by skin contact or by inhalation. 1433 NITRILES,LIQUID,TOXIC, N.O.S. 6.1 3276 3 Liquids,evolving toxic vapour.React with acids or acid fumes,evolving hydrogen cyanide,a highly toxic and flammable gas.Miscible with water.Toxic if swallowed,by skin contact or by inhalation. 1434 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 3219 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 1435 NITRITES, INORGANIC, N.O.S. 5.1 2627 2 Solid. Solid mixtures with combustible material are readily ignited and may burn fiercely. Solid mixtures with ammonium compounds or cyanides may explode. If heated, may decompose, giving off toxic nitrous fumes. Harmful if swallowed. Transport of AMMONIUM 1436 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 4.1 1336 2 Desensitized explosive.White solid.When involved in a fire, evolves toxic fumes;in closed compartments,these fumes may form an explosive mixture with air.May form extremely sensitive compounds with heavy metals or their salts. 1437 NITRO UREA 1.1D 0147 1 Substance. 1438 NITROANILINES 6.1 1661 3 Yellow crystals. Toxic if swallowed, by skin contact or by inhalation. ortho-NITROANILINES may be carried in the molten state. 1439 NITROANISOLES, LIQUID 6.1 2730 3 Light reddish or amber liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1441 NITROBENZENE 6.1 1662 3 Oily liquid, evolving toxic and corrosive gas. Melting point: approximately 6'C. Toxic if swallowed, by skin contact or by inhalation. 1442 NITROBENZENESULPHONIC ACIDS 8 2305 3 Crystals.Solble in water.Causes burns to skin,eyes and mucous membranes. 1443 NITROBENZOTRIFLUORIDES, LIQUID 6.1 2306 3 Pale straw-coloured,oily liquids with an aromatic odour.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1445 NITROBROMOBENZENES, LIQUID 6.1 2732 3 Colourless to pale yellow liquids. Melting point of 1-BROMO-3-NITROBENZENE: 17'C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1447 NITROCELLULOSE dry or wetted with less than 25% water (or alcohol) by mass 1.1D 0340 1 Substance. 1448 NITROCELLULOSE MEMBRANE FILTERS with not more than 12.6% nitrogen,by dry mass 4.1 3270 2 Filters may be small round pieces or large sheets.When involved in a fire.evolve toxic fumes;in closed compartments,these fumes may form an explosive mixture with air.Burn rapidly with intense heat radiation. 1449 NITROCELLULOSE PLASTICIZED with not less than 18% plasticizing substances, by mass 1.3C 0343 1 Substance. 1450 NITROCELLULOSE SOLUTION, FLAMMABLE with not than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 2059 2 When involved in a fire, evolves toxic nitrous fumes. 1451 NITROCELLULOSE unmodified or plasticized with less than 18% plasticizing substance, by mass 1.1D 0341 1 Substance. 1452 NITROCELLULOSE WETTED with not less than 25% alcohol by mass 1.3C 0342 1 Substance. 1453 NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol,by mass,and not more than 12.6% nitrogen,by dry mass) 4.1 2556 2 Nitrocellulose may be granular or in flakes,blocks or fibrous form.In case of leakage flammable vapours are evolved which,in closed compartment,may form explosive mixtures with air.When involved in a fire,evolves toxic fumes;in closed compartments,these fu 1454 NITROCELLULOSE WITH WATER (not less than 25% water,by mass) 4.1 2555 2 Desensitized explosive.Nitrocellulose may be granular or in flakes,blocks or fibrous form.When involved in a fire,evolves toxic fumes;in closed compartments,these fumes may form an explosive mixture with air.May form extremely sensitive compounds with heav 1455 NITROCELLULOSE with not more than 12.6 nitrogen, by dry mass MIXTURE WITH or WITHOUT PLASTICIZER WITH OR WITHOUT PIGMENT 4.1 2557 2 Nitrocellulose may be in granular form or in flakes.This product may also contain added pigments.When involved in a fire,evolves toxic fumes;in closed compartments,these fumes may form an explosive mixture with air.Burns extremely repidly with intense heat 1456 NITROCRESOLS SOLID 6.1 2446 3 Yellow cystals.Melting point:32oC or above.Slightly soluble in water.Toxic if swallowed,by skin contact or by inhalation. 1457 NITROETHANE 3 2842 3 F/p : 28oC c.c. Colourless, oily liquid. When involved in a fire, evolves nitrous toxic fumes. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. 1458 NITROGEN compressed 2.2 1066 3 Non-flammable, odourless gas. Lighter than air (0.97) 1459 NITROGEN, REFRIGERATED LIQUID 2.2 1977 3 Liquefied, non-flammable, odourless gas. Lighter than air (0.97). Arrangement for the containment of the liquid nitrogen and fittings in use should be appropriate to the potential danger to the structure of the freight container or ship from the effect of 1460 NITROGEN TRIFLUORIDE 2.2 2451 2 Non-flammable,non-toxic,colourless,odourless gas.Strong oxidizing agen;reacts violently with many substances,e.g.grease,oil,etc.Much heavier than air (2.4).May cause slight eye irritation. 1461 NITROGEN TRIOXIDE 2.3 2421 2 Liquefied,non-flammable,toxic and corrosive gas.At lower temperatures,present as a blue liquid.Strong oxidizing agent.Much heavier than air (2.6).Boiling point:3.5oC.Highly irritating to skin,eyes and mucous membranes. 1462 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass 1.1D 0143 1 Substance. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competant authority. 1463 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 4.1 3319 2 Desensitized explosive with lactose ,glucose or cellulose. White solid. Soluble in water. When involved in a fire, the nitroglycerin may accumulate and may produce an explosion. Contact with water may dissolve the desensitizer (lactose or glukose), causing 1464 NITROGLYCERIN MIXTURE, DESENTISED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass 3 3343 2 NULL 1465 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1.1D 0144 1 Substance. 1466 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin 3 3064 2 Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. 1467 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 3 1204 2 Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. 1468 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass 3 3357 2 NULL 1469 NITROGUANIDINE (PICRITE) dry or wetted with less than 20% water, by mass 1.1D 0282 1 Substance. 1470 NITROHYDROCHLORIC ACID 8 1798 2 Yellow liquid; a mixture of nitric acid and hydrochloric acid, usually in the proportion of 1:3. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton and straw, evolving suffocating and highly toxic gases. Highly corrosiv 1471 NITROMETHANE 3 1261 2 Colourless liquid. Miscible with water. Fire and explosion hazard if package is ruptured. flash point : 35oC c.c. Explosive limits : 7.1 to 63% 1472 NITRONAPHTHALENE 4.1 2538 3 Yellow crystals.Insoluble in water.Harmful if swallowed. 1473 NITROPHENOLS ortho-meta-para- 6.1 1663 3 Yellow crystals. Some isomers may have a melting point as low as 44'C. Toxic if swallowed, by skin contact or by inhalation. May be carried in the molten state. 1474 NITROPROPANES 3 2608 3 Colourless liquids. 1-NITROPROPANE: flashpoint approx. 33°C c.c. 2-NITROPROPANE: flashpoint approx. 28°C c.c. Partially miscible with water. Harmful by inhalation. Flash point : 2.2% to 11% 1475 NITROSTARCH dry or wetted, with less than 20% water, by mass 1.1D 0146 1 Substance. 1476 NITROSTARCH, WETTED with not less than 20% water, by mass 4.1 1337 2 Desensitized explosive.Orange powder.Explosive and sensitive to friction in the dry state.When involved in a fire, evolves toxic fumes;in closed compartments these fumes may form an explosive mixture with air.May form extremely sensitive compounds with hea 1477 NITROSYLSULPHURIC ACID, LIQUID 8 2308 2 Clear,straw coloured,oily liquid.Oxidant which may cause fire with organic materials (such as wood,straw,etc.)When involved in a fire,evolves toxic gases.In the presence of moisture,highly corrosive to most metals.Causes burns to skin,eyes and mucous membr 1479 NITROSYL CHLORIDE 2.3 1069 2 Non-flammable, toxic yellow gas with an irritating odour. Corrosive to steel. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. 1480 NITROTOLUENES, LIQUID 6.1 1664 3 Yellow liquids. Melting point: ortho-NITROTOLUENE: -4'C, meta-NITROTOLUENE: 15'C. Toxic if swallowed, by skin contact or by inhalation. 1482 NITROTOLUIDINES (MONO) 6.1 2660 3 Yellow to orange-red crystalline solids. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1483 NITROTRIAZOLONE (NTO) 1.1D 0490 1 Substance. 1484 NITROUS OXIDE 2.2 1070 2 Non-flammable gas. Strong oxidizing agent. Heavier than air (1.5). 1485 NITROUS OXIDE, REFRIGERATED LIQUID 2.2 2201 2 Liquefied, non-flammable,colourless gas with a slighly sweet odour.Strong oxidizing agent.Heavier than air (1.5).Cannot remain in liquid state above 36.5'C. 1486 NITROXYLENES, LIQUID 6.1 1665 3 Yellow liquids. Melting point: 2-NITROTOLUENE: -4'C, meta-NITRO-2-XYLENE: 7'C to 9'C, 4-NITRO-3-XYLENE: 2'C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1488 N-METHYLANINILE 6.1 2294 3 Colourless to brown combustible liquid.Toxic if swallowed,by skin contact or by inhalation. 1489 N-METHYLBUTHYLAMINE 3 2945 2 Colourless liquid. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : 0oC c.c. 1490 N-normal-BUTYLIMIDAZOLE 6.1 2690 3 Colourless to amber mobile liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1491 N-BUTYLANILINE 6.1 2738 3 Amber liquid with a perceptible odour. Immiscible with water. May react vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1492 NONANES 3 1920 3 Colourless liquids. normal-NONANE: flashpoint 31°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. Explosive limits : 08.% - 2.9% 1493 NONYLTRICHLOROSILANE 8 1799 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1494 n- PROPYL ISOCYANATE 6.1 2482 2 Flammable liquid with a pungent odour.Immiscible with water but reacts violently with it.evolving gases.Flashpoint:-18oC to 23oC c.c.Highly toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 1495 n-BUTYL ISOCYANATE 6.1 2485 2 Colourless liquid with a pungent odour.Immsicible with water but reacts violently with it,evolving gase.Flashpoint:11oC c.c.Highly toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 1496 normal BUTYRIC ACID 8 2820 3 Colourless liquid with a penetrating and unpleasant odour. Freezing point: -5'C to -8'C. Miscible with water. Corrosive to most metals. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 1497 AMYL METHYL KETONE 3 1110 3 Colourless liquid. Immiscible with water. Flash point : 49oC c.c. 1498 normal-BUTYL CHLOROFORMATE 6.1 2743 2 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 32'C c.c. to 39'C c.c. Toxic if swallowed, by skin contact o 1499 BUTYL FORMATE 3 1128 3 Colourless liquid. Immiscible with water. Flash point : 18oC c.c. Explosive limits : 1.6 to 8.3% 1500 n-BUTYL METHACRYLATE, STABILIZED 3 2227 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. flash point : 41oC c.c. Explosive limits : 2% to 8% 1501 BUTYL METHYL ETHER 3 2350 2 Colourless liquid.Immiscible with water. 1502 BUTYLAMINE 3 1125 2 Flashpoint: -9'C c.c. Explosive limits: 1.7% to 10%. Colourless, volatile liquid with an ammonia-like odour. Miscible with water. Causes burns to skin, eyes and mucous membranes. Flash point : -9oC c.c. Explosive limits : 1.7 to 10% 1503 n-DECANE 3 2247 3 Flaspoint :47oC c.c.Colourless liquid. Immiscible with water.Explosive limits:0.6% to 5.5%. 1504 HEPTANALDEHYDE 3 3056 3 Colourless or pale yellow, oily liquid with a pungent odour. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. Flash point : 35-45oC c.c. Explosive limits : 1.1 to 5.2% 1505 n-HEPTENE 3 2278 2 f/p : -3oC c.c. Colourless liquid. Immiscible with water. 1506 PROPAN0L (PROPYL ALCOHOL, NORMAL) 3 1274 3 Colourless liquid. Miscible with water. Flash point : 15 to 23oC c.c. Explosive limits : 2% to 12% 1507 PROPYL ACETATE 3 1276 3 Colourless, clear liquid with a pleasant odour. Immiscible with water. Flash point : 10oC c.c. Explosive limits : 1.8 to 8% 1508 PROPYL CHLOROFORMATE 6.1 2740 2 Colourless flammable liquid. Flashpoint: 28'C c.c. Decomposes by water, generating propyl alcohol. Highly toxic if swallowed, by skin contact or by inhalation. Causes burn to skin, eyes and mucous membranes. 1509 PROPYL NITRATE 3 1865 2 F/p : 20oC c.c. White to straw-coloured liquid with an ether-like odour. Immiscible with water. Oxidizing material. May explode on heating. Harmful if swallowed or by inhalation. 1510 n-PROPYLBENZENE 3 2364 3 F/p : 39oC c.c. Colourless liquid. Immiscible with water.Explosive limits:0.8% to 6%. 1511 UNDECANE 3 2330 3 Colourless liquid. Immiscible with water. Flash point : 60oC c.c. 1512 VALERYL CHLORIDES 8 2502 3 Liquid with a penetrating odour.Flashpoint:23oC c.c.or above.Reacts with water,evolving hydrogenchloride,a corrosive gas apparent as white fumes.Corrosive to most metals.Causes burns to skin eyes and mucous membranes. 1513 OCTADECYLTRICHLOROSILANE 8 1800 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1514 OCTADIENE 3 2309 2 Colourless liquid. Immiscible with water. Flash point : 9-15oC c.c. 1515 OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318) 2.2 2422 3 Liquefied,non-flammable,colourless gas.Much heavier than air (6.9).Boiling point:1.2oC 1516 OCTAFLUOROCYCLOBUTANE 2.2 1976 3 Liquefied, non-flammable gas. Much heavier than air (5.7). 1517 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) 2.2 2424 3 Liquefied,non flammable,colourless gas.Much heavier than air (6.6).Boiling point:-36oC. 1518 OCTANES 3 1262 3 Colourless liquids. ISOOCTANE: flashpoint-12°C c.c. n-OCTANE: flashpoint 13°C c.c. Immiscible with water. Explosive limits : 1 to 6.5% 1519 OCTOLITE(OCTOL)dry or wetted with less than15% water by mass 1.1D 0266 1 Substance. Mixture of mass detonating explosives. 1520 OCTONAL 1.1D 0496 1 Substance. Mixtures of mass detonating explosives. 1521 OCTYLTRICHLOROSILANE 8 1801 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1522 OIL GAS, COMPRESSED 2.3 1071 2 Flammable, toxic gas. A mixture of hydrocarbons and carbon monoxide. 1523 ORGANIC PEROXIDE TYPE B, LIQUID 5.2 3101 2 May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1524 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED 5.2 3111 2 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. 1525 ORGANIC PEROXIDE TYPE B, SOLID 5.2 3102 2 May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Additional of water to disuccinic acid peroxide will decrease its thermal stability. May evolve irritant or toxic 1526 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED 5.2 3112 2 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. 1527 ORGANIC PEROXIDE TYPE C, LIQUID 5.2 3103 2 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-butyl hydroperoxide. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1528 ORGANIC PEROXIDE TYPE C,LIQUID,TEMPERATURE CONTROLLED 5.2 3113 2 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. 1529 ORGANIC PEROXIDE TYPE C,SOLID 5.2 3104 2 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1530 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED 5.2 3114 2 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. Th 1531 ORGANIC PEROXIDE TYPE D, LIQUID 5.2 3105 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for acetylacetone peroxide, tert-butyl hydroperoxide and peroxyacetic acid, type D, stabilized. Contact with the eyes and skin should be avoided. May evolve ir 1532 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 5.2 3115 2 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. 1533 ORGANIC PEROXIDE TYPE D, SOLID 5.2 3106 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water except for 3-chloroperoxybenzoic acid. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1534 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED 5.2 3116 2 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The 1535 ORGANIC PEROXIDE TYPE E, LIQUID 5.2 3107 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-amyl hydroperoxide, and tert-butyl hydroperoxide and peroxyacetic acid, type E, stabilized. Contact with the eyes and skin should be avoided. May evol 1536 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 5.2 3117 2 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. 1537 ORGANIC PEROXIDE TYPE E, SOLID 5.2 3108 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1538 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED 5.2 3118 2 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except for di-(2-ethylhexyl) peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency temperatures for eac 1539 ORGANIC PEROXIDE TYPE F, LIQUID 5.2 3109 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-butyl hydroperoxide; dibenzoyl peroxide; dilauroyl peroxide and peroxyacetic acid, type F, stabilized. Contact with the eyes and skin should be avoide 1540 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED 5.2 3119 2 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water except for di-(4-tert-butylcyclohexyl) peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency tempera 1541 ORGANIC PEROXIDE TYPE F, SOLID 5.2 3110 2 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 1542 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED 5.2 3120 2 NULL 1543 ORGANIC PIGMENTS, SELF-HEATING 4.2 3313 2 Self-heating coloured powder or granules.Odourless.Liable to self-heating or spontaneous combustion. 1544 ORGANOARSENIC COMPOUND, N.O.S. LIQUID 6.1 3280 2 Toxic if swallowed,by skin contact or by inhalation. 1545 ORGANOCHLORINE PESTICIDES, LIQUID, FLAMMABLE TOXIC 3 2762 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 1546 ORGANOCHLORINE PESTICIDES, LIQUID, TOXIC 6.1 2996 3 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1547 ORGANOCHLORINE PESTICIDES LIQUID, TOXIC, FLAMMABLE 6.1 2995 2 It frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1548 ORGANOCHLORINE PESTICIDES, SOLID, TOXIC 6.1 2761 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1549 ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION,WATER-REACTIVE N.O.S. 4.3 3207 2 NULL 1550 ORGANOMETALLIC COMPOUND, TOXIC, N.O.S. LIQUID 6.1 3282 3 Toxic if swallowed,by skin contact or by inhalation. 1552 ORGANOPHOSPHOROUS COMPOUND, TOXIC, N.O.S. LIQUID 6.1 3278 3 Toxic if swallowed,by skin contact or by inhalation. 1553 ORGANOPHOSPHOROUS COMPOUND TOXIC, FLAMMABLE, N.O.S. 6.1 3279 2 A wide variety of toxic flammable liquids.Toxic if swallowed,by skin contact or by inhalation. 1554 ORGANOPHOSPHORUS PESTICIDES, LIQUID, TOXIC 6.1 3018 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1555 ORGANOPHOSPHORUS PESTICIDES, LIQUID TOXIC, FLAMMABLE 6.1 3017 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 1556 ORGANOPHOSPHORUS PESTICIDES LIQUID, FLAMMABLE, TOXIC 3 2784 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 1557 ORGANOPHOSPHORUS PESTICIDES, SOLID, TOXIC 6.1 2783 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1558 ORGANOTIN COMPOUNDS LIQUID SOLID, N.O.S. 6.1 3146 3 A wide variety of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 1559 ORGANOTIN COMPOUNDS, LIQUID, N.O.S. 6.1 2788 3 A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 1560 ORGANOTIN PESTICIDES, LIQUID, TOXIC 6.1 3020 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1561 ORGANOTIN PESTICIDES, LIQUID, TOXIC, FLAMMABLE 6.1 3019 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 1562 ORGANOTIN PESTICIDES LIQUID, FLAMMABLE, TOXIC 3 2787 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 1563 ORGANOTIN PESTICIDES, SOLID, TOXIC 6.1 2786 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1564 ANISIDINES 6.1 2431 3 Reddish or yellowish oily liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhlation. 1565 ortho-DICHLOROBENZENE 6.1 1591 3 NULL 1566 OSMIUM TETROXIDE 6.1 2471 2 Pale yellow,crystalline,volatile solid with an irritating odour.Highly toxic if swallowed,by skin contact or by inhalation. 1567 OXIDIZING LIQUID N.O.S. 5.1 3139 2 NULL 1568 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 3098 2 Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. 1569 OXIDIZING LIQUID, POISONOUS, N.O.S. 5.1 3099 2 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 1570 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 3085 2 Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. 1571 OXIDIZING SOLID, POISONOUS, N.O.S. 5.1 3087 2 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 1572 OXIDIZING SOLID, N.O.S. 5.1 1479 2 NULL 1573 OXIDIZING SOLID, FLAMMABLE, N.O.S. 5.1 3137 2 NULL 1574 OXIDIZING SOLID, WATER-REACTIVE, N.O.S. 5.1 3121 2 NULL 1575 OXYGEN compressed 2.2 1072 3 Non-flammable, odourless gas. Strong oxidizing agent. Heavier than air (1.1). 1576 OXYGEN DIFLUORIDE, COMPRESSED 2.3 2190 2 Non-flammable, toxic and corrosive, colourless gas with a foul odour.Strong oxidizing agent.Reacts slowly with water or moist air to produce poisonous and corrosive fumes.Corrosive to glass and to most metals.Heavier than air (1.9).Highly irritating to ski 1577 OXYGEN GENERATOR, CHEMICAL 5.1 3356 3 Oxygen generators, chemical are devices containing chemicals which, upon activation, release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support, e.g.in aircraft, submarines, sp 1578 OXYGEN REFRIGERATED LIQUID 2.2 1073 2 Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid oxygen with acetylene or oils may explode. 1579 PAINT or PAINT RELATED MATERIAL 3 1263 3 Miscibility with water depends upon the composition. 1580 PAPER UNSATURATED OILS TREATED incompletely dried 4.2 1379 3 Liable to ignite spontaneously. The provision of this Code should not apply to manufactured articles properly aged. 1581 CHLOROBENZYL CHLORIDES, LIQUID 6.1 2235 3 Colourless liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1583 PARAFORMALDEHYDE 4.1 2213 3 White powder with a pungent odour.Evolves formaldehyde,particularly when heated, which is irritating to eyes and mucous membranes. 1584 PARALDEHYDE 3 1264 3 Colourless liquid. Miscible with water. flash point : 27oC c.c. Explosive limits : 1.3 % to .... 1585 p-NITROSODIMETHYLANILINE 4.2 1369 2 Dark green, crystalline solid, insoluble in water. Ignites spontaneously in air when dry. Harmful if swallowed. 1586 PENTABORANE 4.2 1380 2 Colourless liquid. Boiling point range: 48'C to 63'C. Ignites spontaneously in air. Decomposes in contact with water, evolving hydrogen, a flammable gas. Toxic if swallowed, by skin contact or by inhalation. 1587 PENTACHLOROETHANE 6.1 1669 3 Clourless liquid. Toxic if swallowed, by skin contact or by inhalation. 1588 PENTACHLOROPHENOL 6.1 3155 3 Toxic if swallowed,by skin contact or by dust inhalation. 1589 PENTAERYTHRITE TETRANITRATE(PETN) (PENTAERYTHRITOL TETRANITRATE) WETTED with not less than 25% water, by mass or PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), DESENSITIZED with not less than 15% phlegmatizer, by mass 1.1D 0150 1 Substance, Mass detonating explosive which will become more sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authoriz 1590 PENTAERYTHRITE TENTRANITRATE MIXTURE, DESENSITIZED, SOLID n.o.s., with more than 10% but not more than 20% PETN by mass 4.1 3344 3 1591 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE) (PETN) with not less than 7% wax, by mass 1.1D 0411 1 Substance. 1592 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) 2.2 3220 3 Liquefied, non-flammable gas with a mild ether-like odour.Much heavier than air (4.2). 1593 PENTAMETHYLHEPTANE 3 2286 3 Colourless liquid. Immiscible with water. Flash point : 43oC c.c. 1594 PENTANE-2,4-DIONE 3 2310 3 Colourless liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Sub risk is 6.1. Flash point : 34oC c.c. Explosive limits : 1.7% to ... 1595 PENTANES, LIQUID 3 1265 2 Colourless liquid. Flashpoint: 27'C c.c. Explosive limits: 1.3% to... Miscible with water. 1596 PENTANOLS 3 1105 3 Colourless liquids with a strong odour. Immiscible with water. tertiary - AMYL ALCOHOL: flashpoint 19°C to 21°C c.c. 1597 PENTOLITE dry or wetted with less than 15% water by, mass 1.1D 0151 1 Substance. Mixture of mass detonating explosive substances. 1598 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 3211 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 1599 PERCHLORATES INORGANIC N.O.S. 5.1 1481 2 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with comboustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to 1600 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 5.1 1873 2 Colourless liquid. Mixtures with combustible material may ignite spontaneously and, when involved in a fire, by shock or by friction, may cause an explosion. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Transport of PER 1601 PERCHLORIC ACID with not more than 50% acid, by mass 8 1802 2 Colourless liquid. Oxidant. Highly corrosive to most metals. 1602 PERCHLOROMETHYL MERCAPTAN 6.1 1670 2 Yellow, oily, volatile liquid evolving irritating vapour ("Tear Gas"). Slowly decomposes in contact with water, producing hydrochloric acid. React with iron or steel, evolving carbon tetrachloride. Corrosive to most metals. Highly toxic if swallowed, by sk 1603 PERCHLORYL FLUORIDE 2.3 3083 2 Non-flammable, toxic, colorless gas with a characteristic sweet odour. Strong oxidizing agent; may cause fire in contact with organic materials. React with water or moist air to produce toxic and corrosive fumes. Mixtures with oils or combustible materials 1604 PERFLUORO(ETHYL VINYL ETHER) 2.1 3154 2 Explosive limits:7% to 73%.Much heavier than air (6.4).Boiling point:12oC 1605 PERFLUORO(METHYL VINYL ETHER) 2.1 3153 2 Explosive limits:7% to 73%.Much heavier than air (4.8).Boiling point:-27oC. 1606 PERFUMERY PRODUCTS, with flammable liquid 3 1266 3 Miscibility with water depends upon the composition. 1607 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 3214 2 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 1608 PERMANGANATES, INORGANIC, N.O.S. 5.1 1482 2 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with comboustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to 1609 PEROXIDES, INORGANIC, N.O.S. 5.1 1483 2 Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1610 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 3216 3 When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute,cotton or sis 1611 PERSULPHATES, INORGANIC, N.O.S. 5.1 3215 3 Solids.Solid mixtures with combustible material are sensitive to friction and are liable to ignite.React fiercely with cyanides when heated or by friction.May form explosive mixture with powdered metals or ammonium compounds. 1612 PESTICIDES LIQUID, FLAMMABLE, TOXIC, N.O.S. Flashpont not less than 23°C 3 3021 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1613 PESTICIDES LIQUID, TOXIC, N.O.S. 6.1 2902 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1614 PESTICIDES LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1 2903 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend up 1615 PESTICIDES SOLID, TOXIC, N.O.S. 6.1 2588 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1616 PETROLEUM CRUDE OIL 3 1267 2 NULL 1617 PETROLEUM DISTILLATES N.O.S. or PETROLEUM PRODUCTS, N.O.S. 3 1268 2 Immiscible with water 1618 PETROLEUM GASES liquefied 2.1 1075 2 Flammable hydrocarbon gases or mixture obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc. In varying proportions. Heavier than air. 1619 PHENACYL BROMIDE 6.1 2645 3 White crystals changing to a greenish colour under the influence of light. Melting point: 50'C. Insoluble in water. Causes tears. Highly toxic if swallowed, by skin contact or by inhalation. 1620 PHENETIDINES 6.1 2311 3 Colourless to yellowish liquids.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1621 PHENOL MOLTEN 6.1 2312 3 Molten liquid with a distinctive strong odour.Melting point:10oC to 43oC (pure product).Toxic if swallowed,by skin contact or by inhalation.Rapidly absorbed through the skin. 1622 PHENOL SOLUTIONS 6.1 2821 2 Yellowish solutions with a perceptible odour. Toxic if swallowed, by skin contact or by inhalation. Rapidly absorbed through the skin. 1623 PHENOL, SOLID 6.1 1671 2 Colourless or white crystals or crystallized mass. Melting point: 43'C (pure product). Soluble in water. Toxic if swallowed, by skin contact or by vapour inhalation. Rapidly absorbed through the skin. 1624 PHENOLSULPHONIC ACID, LIQUID 8 1803 2 Yellow, oily liquid. Corrosive to most metals. 1625 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23oC 3 3346 2 Pesticides frequently containing petroleum or coal tar distilates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1626 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 3348 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1627 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 3345 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1628 PHENOXYACETIC ACID DERIVATIVE PESTICIDE LIQUID TOXIC, FLAMMABLE flashpoint not less than 23oC 6.1 3347 2 They frequently contain petroleum or coal tar distilates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1629 PHENYL CHLOROFORMATE 6.1 2746 2 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to ski 1630 PHENYL ISOCYANATE 6.1 2487 2 Colourless to yellowish liquid with a pungent odour.Flashpoint:51oC c.c.Immiscible with water.Reacts with water,evolving carbon dioxide.Highly toxic if swallowed,by skin contact or by inhaltion.Irritating to skin,eyes and mucous membranes. 1631 PHENYL MERCAPTAN 6.1 2337 2 Colourless flammable liquid with a foul odour.Flaspoint:50oC c.c.Immiscible with water.In contact with acids or when involved in a fire,evolves highly toxic sulphurous fumes.Highly toxic if swallowed,by skin contact or by inhalation. 1632 PHENYL MERCURIC ACETATE 6.1 1674 3 Toxic if swallowed, by skin contact or by dust inhalation. 1633 PHENYLTRICHLOROSILANE 8 1804 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most meta 1634 PHENYLACETONITRILE,LIQUID 6.1 2470 3 Colourless to light brown liquid.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 1635 PHENYLACETYL CHLORIDE 8 2577 3 Colourless liquid with a pungent odour.Reacts with water,evolving hydrogen chloride,an irritating and corrosive gas apparent as white fumes.When involved in a fire,evolves highly toxic fumes.Corrosive to most metals.Vapour irritates eyes and mucous membran 1636 PHENYLCARBYLAMINE CHLORIDE 6.1 1672 3 Pale yellow, oily liquid with an irritating unpleasant odour. Highly toxic if swallowed, by skin contact or by inhalation . 1637 PHENYLENEDIAMINES 6.1 1673 3 White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. 1638 PHENYLHYDRAZINE 6.1 2572 3 Pale yellow oily liquid.Melting point:20oC.Slightly soluble in water.Toxic if swallowed,by skin contact or by inhalation. 1639 PHENYLMERCURIC COMPOUNDS, N.O.S. 6.1 2026 2 Usually white crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1640 PHENYLMERCURIC HYDROXIDE 6.1 1894 3 White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1641 PHENYLMERCURIC NITRATE 6.1 1895 3 White crystals or powder. Toxic if swallowed, by skin contact or by inhalation. 1642 PHENYLPHOSPHORUS DICHLORIDE 8 2798 3 Colourless liquid. Causes burns to skin, eyes and mucous membranes. 1643 PHENYLPHOSPHORUS THIODICHLORIDE 8 2799 3 NULL 1644 PHOSGENE 2.3 1076 2 Liquefied, non-flammable, toxic and corrosive gas with a foul odour. Corrosive in the presence of water. Much heavier than air (3.5). Boiling point: 8'C. Highly irritating to skin, eyes and mucous membranes. This gas is particurlarly dangerous in that it m 1645 PHOSPHINE 2.3 2199 2 Flammable, toxic, colourless gas with a garlic odour.Ignites spontaneoulsy in air.Heavier tham air (1.2).Irritating to skin, eyes and mucous membranes. 1647 PHOSPHORIC ACID, LIQUID 8 1805 3 Miscible in water. Mildly corrosive to most metals. 1648 PHOSPHOROUS ACID 8 2834 3 Colourless to yellow deliquescent crystals. Soluble in water. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1649 PHOSPHOROUS PENTACHLORIDE 8 1806 3 Colorless, crystalline powder. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vap 1650 PHOSPHORUS, AMORPHOUS 4.1 1338 2 Reddish-brown powder.Insoluble with water.Ingnites readily by friction.When involved in a fire,evolves irritating fumes.Forms explosive mixtures with oxidizing sunstances.Harmful if swallowed or by dust inhalation. 1651 PHOSPHORUS HEPTASULPHIDE free from yellow or white phosphorus 4.1 1339 2 Yellow solid.Ignites readily by friction.Develops heat in contact with moist air, evolving toxic and flammable gases.Forms explosive mixtures with oxidizing substances.Harmful if swallowed or by dust inhalation. 1652 PHOSPHORUS OXYBROMIDE MOLTEN 8 2576 2 Colourless liquid with a pungent odour.Melting point:56oC.Reacts violently with water,evolving hydrogen bromide,a toxic and corrosive gas apparent as white fumes.Reacts violently with organic materials (such as wood,cotton,straw),causing fire.When involved 1653 PHOSPHORUS OXYBROMIDE solid 8 1939 2 Colourless crystals. Melting point: 56'C. Reacts violently with water, evolving hydrogen bromide, a toxic and corrosive gas apparent as white fumes. Reacts violently with organic materials (such as wood, cotton, straw), causing fire. Decomposes when heated 1654 PHOSPHORUS OXYCHLORIDE 8 1810 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous memb 1655 PHOSPHORUS PENTABROMIDE 8 2691 2 Yellow hygroscopic crystals, evolving fumes in the air which are corrosive and heavier air. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. Reacts violently with ammonia, bases and many other 1656 PHOSPHORUS PENTAFLUORIDE 2.3 2198 2 Non-flammable, toxic and corrosive colourless gas with an irritating odour.Reacts with water or moist air to produce toxic and corrosive fumes.Corrosive to glass and to most metals.Much heavier than air (4.3).Highly irritating to skin, eyes and mucous memb 1657 PHOSPHORUS PENTASULPHIDE free from yellow or white phosphorus 4.3 1340 2 Yellow solid.Ignites readily by friction.Develops heat in contact with moist air, evolving toxic and flammable gases.Forms explosive mixtures with oxidizing substances.Harmful if swallowed or by dust inhalation. 1658 PHOSPHORUS PENTOXIDE 8 1807 2 Crystalline powder, very deliquescent. Reacts violently with water and organic materials such as wood, cotton or straw, generating heat. In the presence of moisture, mildly corrosive to most metals. 1659 PHOSPHORUS SESQUISULPHIDE free from yellow or white phosphorus 4.1 1341 2 Yellow solid.Ignites readily by friction.Develops heat in contact with moist air, evolving toxic and flammable gases.Forms explosive mixtures with oxidizing substances.Harmful if swallowed or by dust inhalation. 1660 PHOSPHORUS TRIBROMIDE 8 1808 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membr 1661 PHOSPHORUS TRICHLORIDE 6.1 1809 2 Colourless liquid with pungent odour. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact 1662 PHOSPHORUS TRIOXIDE 8 2578 2 Colourless crystals or white deliquescent powder.Melting point:23oC.Reacts with water,evolving heat and at normal temperatures phosphoric acid,but at higher temperatures phosphine,a highly toxic gas.In the presence of moisture,corrosive to most metals.Caus 1663 PHOSPHORUS TRISULPHIDE free from yellow or white phosphorus 4.1 1343 2 Yellow solid.Ignites readily by friction.Develops heat in contact with moist air, evolving toxic and flammable gases.Forms explosive mixtures with oxidizing substances.Harmful if swallowed or by dust inhalation. 1664 PHOSPHORUS,WHITE,MOLTEN 4.2 2447 2 Molten liquid.Melting point:44oC.Ignites spontaneously in air.Toxic if swallowed,by skin contact or by inhalation.Shipped molten above its melting point. 1665 PHOSPHORUS, WHITE or YELLOW, DRY or UNDER WATER or IN SOLUTION 4.2 1381 2 Ignites spontaneously in air. Melting point: 44'C. Toxic if swallowed, by skin contact or by inhalation. Receptacles are usually filled with substance in the liquid state which subsequently solidifies. A sufficient ullage should be allowed. 1666 PHTHALIC ANHYDRIDE with more than 0.005% of maleic anhydride 8 2214 3 White powder or flakes and lumps containing a high proportion of dust.Melting point:131'C.The vapour of the molten substance has a flaspoint of 152'C c.c.and forms a flammable atmosphere with explosive limits of 1.7% to 10.4%.Causes burns to skin,eyes and 1667 PICOLINES 3 2313 3 Colourless to yellow liquids with a pungent or sweet odour. Miscible with water. Harmful by inhalation. Alpha-Picoline flashpoint: 28°C c.c. Beta-Picoline flashpoint: 40°C c.c. gamma-Picoline flashpoint 40°C c.c. irritating to skin, eyes and mucous membran 1668 PINE OIL 3 1272 3 Volatile oils with characteristic odours. Immiscible with water. flash point : 57-60oC c.c. 1669 PIPERAZINE 8 2579 2 Colourless,deliquescent crystals,turning dark on exposure to light.Soluble in water.Decomposes when heated and when involved in a fire,evolving highly toxic nitrous fumes.The solution in water is a strong base and is highly corrosive.Reacts violently with 1670 PIPERIDENE 8 2401 2 Colourless liquid with a fish-like odour.Miscible with water.Reacts violently with acids.Solution in water is a strong alkali and is corrosive.When involved in fire,evolves toxic nitrous fumes. 1671 PLASTICS,NITROCELLULOSE-BASED SELF-HEATING, N.O.S. 4.2 2006 2 NULL 1672 PLASTING MOULDING COMPOUND in dough, sheet or extruded rope form, evolving flammable vapour 9 3314 2 A moulding material consisting predominantly of polystyrene,poly (methyl methacrylate)or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentene.During storage,a small proportion of this pentene is released 1673 TOXIC LIQUIDS, ORGANIC, N.O.S. 6.1 2810 2 Toxic if swallowed, by skin contact or by inhalation. 1674 TOXIC SOLID, ORGANIC, N.O.S. 6.1 2811 3 Toxic if swallowed, by skin contact or by inhalation. 1675 POLYCHLORINATED BIPHENYLS, LIQUID 9 2315 2 Colourless liquid (pure product) with perceptible odours.Immiscible with water.Harmful by ingestion or by skin contact.If spilled,can be a persistent hazard to the environment.This entry also covers articles,such as tranformers and condensers,containing fr 1677 POLYHALOGENATED BIPHENYLS, LIQUID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES,LIQUID or POLYHALOGENATED TERPHENYLS,LIQUID 9 3151 3 Viscous liquids with a perceptible odour.Harmful by ingestion or by skin contact.This entry also covers articles,such as transformers and condensers,containing free liquid polyhalogenated biphenyls or polyhalogenated terphenyls 1678 POLYHALOGENATED BIPHENYLS, SOLID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES,LIQUID or POLYHALOGENATED TERPHENYLS SOLID 9 3152 3 Solid with a perceptible odour.Melting point of solids varies from 2oC to 164oC.Harmful by ingestion or by skin contact.This entry also covers articles,such as rags,cotton waste,clothing or sawdust,containing polyhalogenated biphenyls or polyhalogenated te 1679 POLYMERIC BEADS, EXPANDABLE evolving flammable vapours 9 2211 2 A moulding material in bead or granular from consisting predominantly of polystyrene,poly(methyl methacrylate)or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is pridominantly pentene.During storage,a small proportion of 1680 POLYSTER RESIN KIT,liquid base material 3 3269 3 Polyester resin kits consist of two components:a base material (flammable liquid)and an activator (organic peroxide),each separately packed in an inner packaging. 1681 POTASIUM BOROHYDRIDE 4.3 1870 2 White, crystalline powder. In the contact with water, acids or moisture evolves hydrogen, which may be ignited by the heat of the reaction. 1682 POTASSIUM 4.3 2257 2 Soft,silvery metal,solid or liquid.Floats on water.Reacts violently with moisture,water or acids,evolving hydrogen,which may be ignited by the heat of the reaction.Highly reactive,sometimes with explosive effect. 1683 POTASSIUM ARSENATE 6.1 1677 3 Colourless crystals or white powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1684 POTASSIUM ARSENITE 6.1 1678 3 White powder. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1685 POTASSIUM BROMATE 5.1 1484 2 White crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sens 1686 POTASSIUM CHLORATE 5.1 1485 2 White crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sens 1687 POTASSIUM CHLORATE,AQUEOUS SOLUTION 5.1 2427 2 Colourless liquid.When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material or sulphur,danger of spontaneous combustion; .2 in contact wi 1688 POTASSIUM CUPROCYANIDE 6.1 1679 2 White crystals or powder. Soluble in water. Reacts with acids and acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1690 POTASSIUM CYANIDE, SOLID 6.1 1680 2 White, deliquescent crystals or lumps. Soluble in water. Reacts with acids and acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1691 POTASSIUM DITHIONITE 4.2 1929 2 Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. 1693 POTASSIUM FLUORIDE, SOLID 6.1 1812 3 White, deliquescent crystals or powder. Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. 1694 POTASSIUM FLUOROACETATE 6.1 2628 2 Solid. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1695 POTASSIUM FLUOROSILICATE 6.1 2655 3 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 1696 POTASSIUM HYDROGEN SULPHATE 8 2509 2 Colourless crystals.Soluble in water.When involved in a fire,evolves extremely irritating and corrosive fumes.In the presence of moisture,corrosive to most metals.Irritating to skin,eyes and mucous membranes. 1697 POTASSIUM HYDROGENDIFLUORIDE, SOLID 8 1811 2 White crystalline solid. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. To 1699 POTASSIUM HYDROXIDE, SOLID 8 1813 3 White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1700 POTASSIUM HYDROXIDE, SOLUTION 8 1814 3 Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1701 POTASSIUM METAL ALLOY 4.3 1420 2 Soft, silvery metal liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1702 POTASSIUM METAVANADATE 6.1 2864 3 White crystalline powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1703 POTASSIUM MONOXIDE 8 2033 3 Deliquescent crystalline solid.Reacts violently with water,generating heat.Reacts with ammonium salts,evolving ammonia gas.Reacts violently with acids.In the presence of moisture,corrosive to aluminium,zinc and tin.Causes burns to skin, eyes and mucous mem 1704 POTASSIUM NITRATE 5.1 1486 3 White crystals or powder. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1705 POTASSIUM NITRATE and SODIUM NITRITE mixture 5.1 1487 2 Deliquescent solid. Soluble in water. May cause fire in contact with organic material such as wood, cotton or straw. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. May be shipped in the form of fused solid block or lumps. 1706 POTASSIUM NITRITE 5.1 1488 3 White or slightly yellowish deliquescent crystals or sticks. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. 1707 POTASSIUM PERCHLORATE 5.1 1489 2 White crystals or powder, soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sens 1708 POTASSIUM PERMANGANATE 5.1 1490 2 Dark purple crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures ar 1709 POTASSIUM PEROXIDE 5.1 1491 2 Yellow powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating t 1710 POTASSIUM PERSULPHATE 5.1 1492 3 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered meta 1711 POTASSIUM PHOSPHIDE 4.3 2012 2 Solid. React with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1712 POTASSIUM SODIUM alloy 4.3 1422 2 Soft, silvery metal liquid. Floats on water. React violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1713 POTASSIUM SULPHIDE ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 4.2 1382 3 Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Reacts violently with avids. 1714 POTASSIUM SULPHIDE HYDRATED with not less than 30% water of crystallization 8 1847 3 Crystalline solid. Melting point: 60'C. Reacts violently with acids, evolving hydrogen sulphine, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1715 POTASSIUM SUPEROXIDE 5.1 2466 2 Yellow flakes.Particularly if wetted with small quantities of wate,a mixture with combustible material may ignite,following impact or friction.When involved in a fire,or in contact with water or acids,decomposes,evolving oxygen.Highly irritating to skin,ey 1716 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass 1.3C 0159 1 Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerin or other liquid organic nitrates or a mixture of these. This substance, when containing less alcohol water of phlegmatizer than specified, shall not be transported, 1717 POWDER CAKE (POWDER PASTE) WETTED with not less than 17% alcohol, by mass 1.1C 0433 1 1718 POWDER, SMOKELESS 1.1C 0160 1 Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. 1719 POWDER SMOKELESS 1.3C 0161 1 Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. 1720 PRIMERS Cap Type 1.1B 0377 1 NULL 1721 PRIMERS TUBULAR 1.3G 0319 1 NULL 1722 PRIMERS, CAP TYPE 1.4S 0044 2 NULL 1723 PRIMERS, CAP TYPE 1.4B 0378 2 NULL 1724 PRIMERS, TUBULAR 1.4S 0376 2 NULL 1725 PRIMERS, TUBULAR 1.4G 0320 2 NULL 1726 PRINTING INK flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 1210 3 Fluid or viscous liquid containing colouring matter in solution or suspension. Miscibility with water depends upon the solvent. 1727 PROJECTILES inert with tracer 1.3G 0424 1 NULL 1728 PROJECTILES inert with tracer 1.4G 0425 2 NULL 1729 PROJECTILES with burster or expelling charge 1.2D 0346 1 NULL 1730 PROJECTILES with burster or expelling charge 1.2F 0426 1 NULL 1731 PROJECTILES with burster or expelling charge 1.2G 0434 1 NULL 1732 PROJECTILES with burster or expelling charge 1.4G 0435 2 NULL 1733 PROJECTILES with burster or expelling charge 1.4F 0427 2 NULL 1734 PROJECTILES with bursting charge 1.1F 0167 1 NULL 1735 PROJECTILES with bursting charge 1.1D 0168 1 NULL 1736 PROJECTILES with bursting charge 1.2D 0169 1 NULL 1737 PROJECTILES with bursting charge 1.2F 0324 1 NULL 1738 PROJECTILES with bursting charge 1.4D 0344 2 NULL 1739 PROJECTILES, inert, with tracer 1.4S 0345 2 NULL 1740 PROJECTILES, with burster or expelling charge 1.4D 0347 1 1741 PROPADIANE, STABILIZED 2.1 2200 2 Liquefied, flammable, colourless gas.Explosive limits:1.7% to 12%.Heavier than air (1.4).Boiling point:-34'C.Irritating to skin, eyes and mucous membranes. 1742 PROPANE 2.1 1978 2 Flammable hydrocarbon gas. Explosive limit: 2.3% to 9.5%. Heavier than air (1.56). 1743 PROPANETHOILS 3 2402 2 Colourless or yellowish liquids with a strong unpleasant odour. Boiling range: 53°C to 67°C. Immiscible with water. flash point : <-18oC c.c. 1744 PROPELLANT, LIQUID 1.1C 0497 1 NULL 1745 PROPELLANT, LIQUID 1.3C 0495 1 NULL 1746 PROPELLANT, SOLID 1.1C 0498 1 NULL 1747 PROPELLANT, SOLID 1.3C 0499 1 NULL 1748 PROPELLANT, SOLID 1.4C 0500 2 NULL 1749 PROPIONALDEHYDE 3 1275 2 Colourless liquid with a pungent odour. Boiling point: 49°C. Miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : <-18oC c.c. Explosive limits : 2.3 to 21% 1750 PROPIONIC ACID with ot less than 10% and less than 90% acid by mass 8 1848 3 Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Causes burns to skin, eyes and mucous membranes. 1751 PROPIONIC ANHYDRIDE 8 2496 3 Colourless,combustible liquid with a pungent odour.Reacts with water,forming propionic acid.Corrosive to skin,eyes and mucous membranes. 1752 PROPIONITRILE 3 2404 2 Colourless, volatile liquid with an ether-like odour. Miscible with water. When involved in a fire, evolves highly toxic cyanide fumes. Toxic if swallowed, by skin contact or by inhalation. Flash point : 2oC c.c. Explosive limits: 3.1% to .... 1753 PROPIONYL CHLORIDE 3 1815 2 Colourless liquid. F/point : 12oC c.c. Colourless liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, 1754 PROPYL FORMATES 3 1281 3 Colouless liquids with a pleasant odour. Explosive limits:2.4% to 7.8%.Miscibility with water depends upon the composition.Irritating to skin,eyes and mucous membranes. 1755 PROPYL TRICHLOROSILANE 8 1816 2 Colourless, flammable liquid, with a pungent odour. Flashpoint: 38'C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moi 1756 PROPYLAMINE 3 1277 2 Colourless liquid. Boiling point: 48°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. flash point : < -18oC c.c. Explosive limits : 2 - 10.4% 1757 PROPYLENE 2.1 1077 2 Flammable hydrocarbon gas. Explosive limit: 2% to 11.1%. Heavier than air (1.5). 1758 PROPYLENE CHLOROHYDRIN 6.1 2611 3 Colourless flammable liquid with a mild odour. Flashpoint: 51'C c.c. Miscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 1759 PROPYLENE OXIDE 3 1280 2 Colourless, volatile liquid with an ether-like odour. Boiling point: 34°C. Partially miscible with water. Flash point : <-18oC c.c. Explosive limits : 2 - 22% 1760 PROPYLENE TETRAMER 3 2850 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1-dodecene is not marine pollutant. 1761 1,2-PROPYLENEDIAMINE 8 2258 3 Colourless,flammable liquid with an ammoniacal odour.Flaspoint range:33'C to 48'C c.c.Miscible with water.When involved in a fire,evolves toxic gases.Harmful by inhalation.Causes burns to skin and eyes.Irritating to mucous membranes. 1762 PROPYLENEIMINE, STABILIZED 3 1921 2 f/p : -4oC c.c. Colourless liquid with an ammoniacal odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin and eyes. 1763 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23oC 3 3350 2 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1764 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 3352 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1765 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23oC 6.1 3351 2 They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1766 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 3349 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 1767 PYRIDINE 3 1282 3 Colourless or slightly yellow liquid with a pungent odour. Miscible with water. Harmful by inhalation. Flash point : 17oC c.c. Explosive limits : 1.8 to 12.4% 1768 PYROPHORIC LIQUID, INORGANIC, N.O.S. 4.2 3194 2 Highly flammable liquids,may ignite spontaneously in moist air.In contact with air,evolve irritating and slightly toxic fumes. 1769 PYROPHORIC LIQUIDS, ORGANIC, N.O.S. 4.2 2845 2 Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. 1770 PYROPHORIC METAL N.O.S. or PYROPHORIC ALLOY N.O.S. 4.2 1383 2 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolves hydrogen, a flammable gas. 1771 PYROPHORIC ORGANOMETALLIC COMPOUND LIQUID, WATER-REACTIVE, N.O.S. 4.2 3203 2 NULL 1773 PYROPHORIC SOLID, INORGANIC, N.O.S. 4.2 3200 2 Liable to ignite spontaneously in air.If shaken,may produce sparks.In contact with water,evolve hydrogen,a flammable gas. 1774 PYROPHORIC SOLIDS N.O.S. 4.2 2846 2 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 1775 PYROSULPHURYL CHLORIDE 8 1817 2 Collourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most m 1776 PYRROLIDINE 3 1922 3 f/p : 3oC c.c. Colourless to pale yellow liquid with an ammoniacal odour. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1777 QUINOLINE 6.1 2656 2 Colourless liquid with a pungent odour. Immiscible with water. When heated, evolves highly toxic fumes (of oxides of nitrogen). Toxic if swallowed, by skin contact or by inhalation. 1778 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY(LSA-II), non-fissile or fissile excepted 7 3321 2 NULL 1779 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY(LSA-III), non-fissile or fissile excepted 7 3322 2 NULL 1780 RADIOACTIVE MATERIAL, TYPE C PACKAGE non-fissile or fissile excepted 7 3323 2 NULL 1781 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY(LSA-II), FISSILE 7 3324 2 1782 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY(LSA-III), FISSILE 7 3325 2 1783 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE 7 3326 2 1784 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE non-special form 7 3327 2 NULL 1785 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE 7 3328 2 NULL 1786 RADIOACTIVE MATERIAL, TYPE B(M)PACKAGE, FISSILE 7 3329 2 NULL 1787 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE 7 3330 2 NULL 1788 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE 7 3331 2 NULL 1789 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM non fissile or fissile excepted 7 3332 2 NULL 1790 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE 7 3333 2 NULL 1791 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE-EMPTY PACKAGING 7 2908 2 NULL 1792 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE-ARTICLES ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM 7 2909 2 NULL 1793 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE-LIMITED QUANTITY OF MATERIAL 7 2910 2 NULL 1794 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE-INSTRUMENTS or ARTICLES 7 2911 2 NULL 1795 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY(LSA-1) non-fissile or fissile excepted 7 2912 2 NULL 1796 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECT (SCO-1 or SCO-II), non-fisile or fissile excepted 7 2913 2 NULL 1797 RADIOACTIVE MATERIAL, TYPE A PCKAGE, non-special form, non-fissile or fissile excepted 7 2915 2 NULL 1798 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non-fissile or fissile excepted 7 2916 2 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 1799 RADIOACTIVE MATERIAL, TYPE B(M)PACKAGE, non-fissile or fissile excepted 7 2917 2 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 1800 RADIOACTIVE MATERIAL TRANSPORTED UNDER SPECIAL ARRANGEMENT non-fissile or fissile excepted 7 2919 2 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 1801 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE 7 2977 2 NULL 1802 RADIOACTIVE MATERIAL,URANIUM HEXAFLUORIDE non-fissile or fissile excepted 7 2978 2 NULL 1803 RAGS OILY 4.2 1856 3 Liable to ignite spontaneously in air according to oil content. 1807 RECEPTACLES SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non refillable 2 2037 2 Normally contain mixtures of liquefied butane and propane in various proportions for use in camping stoves, etc. 1808 REFRIGERANT GAS R 404A 2.2 3337 3 Liquefied, non-flammable,colourless gas with a faint ether-like odour. Heavier than air (1.06). Very high exposures may cause anaesthetic effects and asphyxiation. 1809 REFRIGERANT GAS R 407A 2.2 3338 3 Liquefied, non-flammable,colourless gas with a faint ether-like odour. Heavier than air (1.17). Very high exposures may cause anaesthetic effects and asphyxiation. 1810 REFRIGERANT GAS R 407B 2.2 3339 3 Liquefied, non-flammable,colourless gas with a faint ether-like odour. Heavier than air (1.19). Very high exposures may cause anaesthetic effects and asphyxiation. 1811 REFRIGERANT GAS R 407C 2.2 3340 3 Liquefied, non-flammable,colourless gas with a faint ether-like odour. Heavier than air (1.16). Very high exposures may cause anaesthetic effects and asphyxiation. 1812 REFRIGERANT GASES N.O.S. 2.2 1078 2 Different chlorofluorohydrocarbon or other non-flammable, non-toxic gases considered as refrigerant agent. 1813 REFRIGERATING MACHINES containing non-flammable non-toxic liquefied gases or ammonia solution (UN 2672) 2.2 2857 3 NULL 1814 REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas 2.1 3358 2 NULL 1815 RELEASE DEVICES, EXPLOSIVE 1.4S 0173 2 NULL 1816 RESIN SOLUTION flammable 3 1866 3 Miscibility with water depends upon the composition. 1817 RESORCINOL 6.1 2876 3 White to pink crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1818 RIVETS, EXPLOSIVE 1.4S 0174 2 NULL 1819 ROCKET LINE THROWING 1.4G 0453 2 NULL 1820 ROCKET MOTOR 1.2C 0281 1 NULL 1821 ROCKET MOTOR WITH HYPERGOLIC LIQUID with or without expelling charge 1.2L 0322 1 NULL 1822 ROCKET MOTORS 1.1C 0280 1 NULL 1823 ROCKET MOTORS 1.3C 0186 1 NULL 1824 ROCKET MOTORS LIQUID FUELLED 1.2J 0395 1 NULL 1825 ROCKET MOTORS LIQUID FUELLED 1.3J 0396 1 NULL 1826 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without an expelling charge 1.3L 0250 1 NULL 1827 ROCKETS with expelling charge. 1.2C 0436 1 1828 ROCKET with expelling charge. 1.3C 0437 1 1829 ROCKETS Line Throwing 1.2G 0238 1 NULL 1830 ROCKETS LINE-THROWING 1.3G 0240 1 NULL 1831 ROCKETS LIQUID FUELLED with bursting charge 1.1J 0397 1 NULL 1832 ROCKETS LIQUID FUELLED with bursting charge 1.2J 0398 1 NULL 1833 ROCKETS with bursting charge 1.1F 0180 1 NULL 1834 ROCKETS with bursting charge 1.1E 0181 1 NULL 1835 ROCKETS with bursting charge 1.2E 0182 1 NULL 1836 ROCKETS with bursting charge 1.2F 0295 1 NULL 1837 ROCKETS with expelling charge 1.4C 0438 2 NULL 1838 ROCKETS with inert head 1.3C 0183 1 NULL 1839 ROCKETS with inert head 1.2C 0502 1 NULL 1840 ROSIN OIL 3 1286 3 Colourless to brown viscous liquid.Immicible with water. 1841 RUBBER SCRAP powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% or RUBBER SHODDY powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% 4.1 1345 3 Liable to spontaneous heating. 1842 RUBBER SOLUTION 3 1287 3 Miscibility with water depends upon the composition. 1843 RUBIDIUM 4.3 1423 2 Silvery-white, ductile, soft metal. Melting point: 39'C. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1844 RUBIDIUM HYDROXIDE solid 8 2678 2 Greyish-white solid, very hydroscopic. Reacts violenty with acids. React with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1845 RUBIDIUM HYDROXIDE solution 8 2677 2 Liquid. React violently with acids. React with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1846 SAMPLES EXPLOSIVE other than initiating explosive 1 0190 1 Substance or article. Division and compatibility group as classified by the competent authority. 1847 SEED CAKE containing vegetable oil (a) mechanically expelled seeds, containing more than 10% oil or more than 20% oil and moisture combined 4.2 1386 3 Residue remaining after oil has been expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop) 1848 SEED CAKE with not more than 1.5% oil and not more than 11% moisture 4.2 2217 3 Residue remaining after oil has been extracted by a solvent process from oil-bearing seeds.Used mainly as an animal feed or fertilizer.The most common seed cakes include those derived from coconut (copra),cottonseed, groundnut (peanut),inseed,maize (hominy 1849 SEED CAKE containing vegetable oil (b) 4.2 1386 3 Residue remaining after oil has been extracted by a solvwnt process or expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (pea 1850 SELENATES or SELENITES 6.1 2630 2 A wide range of toxic solids. Generally soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1851 SELENIC ACID 8 1905 2 White, very deliquescent crystalline solid. Melting point: 50'C. Soluble in water. Reacts violently with organic materials such as wood, cotton or straw. In the presence of moisture, corrosive to most metals. Causes severe burns to skin, eyes and mucous me 1852 SELENIUM COMPOUND,SOLID,N.O.S. 6.1 3283 3 Toxic if swallowed,by skin contact or by inhalation. 1853 SELENIUM DISULPHIDE 6.1 2657 2 Bright red-yellow crystals with a faint odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 1854 SELENIUM HEXAFLUORIDE 2.3 2194 2 Colourless,toxic and corrosive gas.Corrosive to glass and to most metals.Heavier than air.Highly irritating to skin, eyes and mucous membranes. 1855 SELENIUM OXYCHLORIDE 8 2879 2 Colourless, yellowish liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalati 1856 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 3188 2 1857 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 4.2 3185 2 NULL 1858 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 3186 2 NULL 1859 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 3183 2 NULL 1860 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 3187 2 NULL 1861 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 3184 2 NULL 1862 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 3192 2 NULL 1863 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 3190 2 Liable to self-heating or spontaneous combustion. 1864 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 3191 2 NULL 1865 SELF-HEATING SOLID, ORGANIC, .N.O.S. 4.2 3088 2 Liable to self-heating or spontaneous combustion. 1866 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 3128 2 NULL 1867 SELF-HEATING, SOLID, CORROSIVE, ORGANIC, N.O.S. 4.2 3126 2 Liquefied, non-flammable gas. Much heavier than air (2.4). 1868 SELF-HEATING, SOLID, OXIDIZING, N.O.S. 4.2 3127 2 NULL 1869 SELF-REACTIVE LIQUID TYPE B 4.1 3221 2 May explode at elevated temperatures or in a fire.Burns vigorously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1870 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 4.1 3231 2 May explode at temperatures higher than the emergency temperature or in a fire.Burns vigorously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition may be toxic by inhalation.Control and emergency temperatures for each for 1871 SELF-REACTIVE LIQUID TYPE C 4.1 3223 2 May decompose violently at elevated temperatures or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1872 SELF-REACTIVE LIQUID TYPE C TEMPERATURE CONTROLLED 4.1 3233 2 May explode at temperatures higher than the emergency temperature or in a fire.Burns vigorously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition may be toxic by inhalation.Control and emergency temperatures for each for 1873 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED 4.1 3234 2 May explode at temperatures higher than the emergency temperature or in a fire.Burns vigorously.Insoluble in water except: 3-METHYL-4(PYRROLIDIN-1-YL)BENZENEDIAZONIUM TETRAFLUOROBORATE TETRAMINEPALLADIUM (2)NITRATE Contact with alkalis or acids may cause 1874 SELF-REACTIVE LIQUID TYPE D 4.1 3225 2 Decomposes at elevated temperatures or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1875 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 4.1 3235 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic b 1876 SELF-REACTIVE LIQUID TYPE E 4.1 3227 2 Decomposes at elevated temperatures or in a fire.Burns vigorously.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1877 SELF-REACTIVE LIQUID TYPE E TEMPERATURE CONTROLLED 4.1 3237 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic b 1878 SELF-REACTIVE LIQUID TYPE F 4.1 3229 2 Decomposes at elevated temperatures or in a fire.Burns vigorously.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1879 SELF-REACTIVE LIQUID TYPE F TEMPERATURE CONTROLLED 4.1 3239 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic b 1880 SELF-REACTIVE SOLID TYPE B 4.1 3222 2 May explode at elevated temperatures or in a fire.Burns vigorously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1881 SELF-REACTIVE SOLID TYPE B TEMPERATURE CONTROLLED 4.1 3232 2 May explode at temperatures higher than the emergency temperature or in a fire.Burns vigorously.Insoluble in water.Contact with alkalis or acids may cause dangerous decomposition may be toxic by inhalation.Control and emergency temperatures for each formul 1882 SELF-REACTIVE SOLID TYPE C 4.1 3224 2 May decompose violently at elevated temperatures or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1883 SELF-REACTIVE SOLID TYPE D 4.1 3226 2 Decomposes at elevated temperatures or in a fire.Burns vigorously.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation.Insoluble in water except 4-(BENZYL(E 1884 SELF-REACTIVE SOLID TYPE D TEMPERATURE CONTROLLED 4.1 3236 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Soluble in water except: AZODICARBONAMIDE FORMULATION TYPE D 2,2'-AZODI(2,4-DIMETHYL-4-METHOXYVALERONITRILE) 2,2'-AZODI(2,4-DIMETHYLVALERONITRILE) 2,2;AZODI(2-MET 1885 SELF-REACTIVE SOLID TYPE E 4.1 3228 2 Decomposes at elevated temperatures or in a fire.Burns vigorously.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1886 SELF-REACTIVE SOLID TYPE E TEMPERATURE CONTROLLED 4.1 3238 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic b 1887 SELF-REACTIVE SOLID TYPE F 4.1 3230 2 Decomposes at elevated temperatures or in a fire.Burns vigorously.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic by inhalation. 1888 SELF-REACTIVE SOLID TYPE F TEMPERATURE CONTROLLED 4.1 3240 2 Decomposes at temperatures higher than the emergency temperature or in a fire.Burns vigrously.Immiscible with water.Contact with alkalis or acids may cause dangerous decomposition.The products of combustion or self-accelerating decomposition may be toxic b 1889 SHALE OIL 3 1288 2 Immiscible with water. 1890 SIGNAL DEVICES, HAND 1.4G 0191 2 NULL 1891 SIGNAL DEVICES, HAND 1.4S 0373 2 NULL 1892 SIGNAL RAILWAY TRACT, EXPLOSIVE 1.4G 0493 2 NULL 1893 SIGNAL, RAILWAY TRACT, EXPLOSIVE 1.3G 0492 1 NULL 1894 SIGNAL, SMOKE 1.3G 0487 1 NULL 1895 SIGNALS DISTRESS ship 1.1G 0194 1 NULL 1896 SIGNALS DISTRESS ship 1.3G 0195 1 NULL 1897 SIGNALS RAILWAY TRACK EXPLOSIVE 1.1G 0192 1 NULL 1898 SIGNALS SMOKE 1.1G 0196 1 NULL 1899 SIGNALS,SMOKE 1.2G 0313 1 1900 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.4S 0193 2 NULL 1901 SIGNALS, SMOKE 1.4G 0197 2 NULL 1902 SILANE 2.1 2203 2 Flammable,colourless gas with a foul odour.Explosive limits 1% to 100%.Ignites spontaneously in air.Strong reducing agent which reacts violently with oxidizing substances.Heavier than air (1.1). 1903 SILICON POWDER amorphous 4.1 1346 2 Dark brown, non-metallic powder. Burns in air, when ignited; readily flammable when mixed with oxidizing substances. 1904 SILICON TETRACHLORIDE 8 1818 2 Colourless, extremely mobile liquid with a suffocating odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highl 1905 SILICON TETRAFLUORIDE 2.3 1859 2 Non- flammable, toxic and corrosive gas with a pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. 1906 SILVER ARSENITE 6.1 1683 3 Yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1907 SILVER CYANIDE 6.1 1684 2 White powder. Insoluble in water. React with acids and acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1908 SILVER NITRATE 5.1 1493 3 Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Irritating to skin and mucous membranes. 1909 SILVER PICRATE WETTED with not less than 30% water, by mass 4.1 1347 2 Desensitized explosive. Yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. May form extremely sensitive compounds with heavy metals or their salts. Transport of SILVER PICRATE, 1910 SLUDGE ACID 8 1906 2 Waste or spent sulphuric acid, usually a by-product of refining petroleum oils or crude benzenes. Highly corrosive to most metals. 1911 SODA LIME with more than 4% sodium hydroxide 8 1907 3 Deliquescent, granulated mixture of sodium hydroxide and calcium hydroxide. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and muc 1912 SODIUM 4.3 1428 2 White, ductile, soft metal. Floats on water. React violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1913 SODIUM ALUMINATE solution 8 1819 2 Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1914 SODIUM ALUMINIUM HYDRIDE 4.3 2835 2 White, crystalline solid. Reacts with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1915 SODIUM AMMONIUM VANADATE 6.1 2863 3 Orange wet cake (with 10% to 15% water). Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1916 SODIUM ARSANILATE 6.1 2473 3 White,crystalline powder.Soluble in water.Toxic if swallowed,by skin contact or by dust inhalation. 1917 SODIUM ARSENATE 6.1 1685 3 Colourless crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1918 SODIUM ARSENITE AQUEOUS SOLUTIONS 6.1 1686 3 Colourless. Toxic if swallowed, by skin contact or by inhalation. 1919 SODIUM ARSENITE SOLID 6.1 2027 3 Greyish-white powder. Soluble in water. Reacts with oxidizing substances, evolving heat. Toxic if swallowed, by skin contact or by dust inhalation. 1920 SODIUM AZIDE 6.1 1687 2 Colourless crystals. May react vigorously with acids to form hydrazoic acid, which is an explosive. May form extremely sensitive compounds with heavy metals or their salts. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust i 1921 SODIUM BOROHYDRIDE 4.3 1426 2 Crystalline powder. In contact with water, acids or moisture, evolving hydrogen, which may be ignited by the heat of the reaction. 1922 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass 8 3320 3 Off-white clear liquid with a slight hydrocarbon odour. React violently with acids. In contact with acids or diluted with large amount of water, evolves hydrogen gas and heat. Causes burns to skin, eyes and mucous membranes. 1923 SODIUM BROMATE 5.1 1494 2 White deliquescent crystals. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are s 1924 SODIUM CACODYLATE 6.1 1688 3 White, deliquescent crystals or lumps. Soluble in water. React with acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1925 SODIUM CHLORATE 5.1 1495 2 Colourless deliquescent crystals. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures 1926 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 2428 2 Colourless liquid.When involved in a fire,may cause an explosion.Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material or sulphur,danger of spontaneous combustion; .2 in contact wi 1927 SODIUM CHLORITE 5.1 1496 2 Colourless deliquescent solid. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are 1928 SODIUM CHLOROACETATE 6.1 2659 3 White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1929 SODIUM CUPROCYANIDE,SOLID 6.1 2316 2 White powder.Soluble in water.Reacts with acids or acid fumes,evolving hydrogen cyanide,a highly toxic and flammable gas.Highly toxic if swallowed,by skin contact or by dust inhalation. 1930 SODIUM CUPROCYANIDE SOLUTION 6.1 2317 2 Colourless liquid.Miscible with water.Decomposed by acids,evolving hydrogen cyanide,a highly toxic and flammable gas.Highly toxic if swallowed,by skin contact or by inhalation. 1932 SODIUM CYANIDE,SOLID 6.1 1689 2 White, deliquescent crystals or lumps. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1933 SODIUM DINITRO-o-CRESOLATE dry or wetted with less than 15% water, by mass 1.3C 0234 1 Substance. 1934 SODIUM DINITRO-ortho-CRESOLATE WETTED with not less than 15% water by mass 4.1 1348 2 Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compound with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed 1935 SODIUM DITHIONITE (SODIUM HYDROSULPHITE) 4.2 1384 2 White or grey crystalline powder. Liable to heat and ignite spontaneously in air and evolve sulphur dioxide, an irritating gas. 1936 SODIUM FLOURIDE solid 6.1 1690 3 White crystals or powder. React with acids, evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 1938 SODIUM FLUOROACETATE 6.1 2629 2 White powder. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1939 SODIUM FLUOROSILICATE 6.1 2674 3 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by inhalation. 1940 SODIUM HYDRIDE 4.3 1427 2 White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1941 SODIUM HYDROGENDIFLUORIDE 8 2439 2 White,crystalline powder.Soluble in water.Decomposed by heat or acids,evolving hydrogen fluoride,a toxic extremely irritating and corrosive gas.In the presence of moisture,highly corrosive to glass,other siliceous materials and most metals.Causes burns to 1942 SODIUM HYDROSULPHIDE with less than 25% water of crystallazition 4.2 2318 3 Colourless needles to lemon-coloured flakes.Soluble in water.Reacts violently with acids. 1943 SODIUM HYDROSULPHIDE HYDRATED with not less than 25% water of crystallization 8 2949 2 Colourless needles or yellow flakes. Soluble in water with a foul odour. Melting point: 52'C. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Causes burns to skin, eyes and mucous membranes. 1944 SODIUM HYDROXIDE SOLID 8 1823 3 White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aliminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1945 SODIUM HYDROXIDE SOLUTION 8 1824 3 Colourless liquid. Corrosive to aluminium, zinc and tin. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1946 SODIUM METHYLATE 4.2 1431 2 White, amorphous, free-flowing, hygroscopic powder. Decomposed by water to form methanol, a flammable liquid, which may be ignited by the heat of the reaction. Causes burns to skin, eyes and mucous membranes. 1947 SODIUM METHYLATE SOLUTION in alcohol 3 1289 2 Reacts violently with water.Causes burns to skin,eyes and mucous membranes. 1948 SODIUM MONOXIDE 8 1825 2 Deliquescent crystalline solid. Reacts violently with water and acids, generating heat. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1949 SODIUM NITRATE 5.1 1498 3 Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. This substance in the impure form is known as Chile Saltpetre. 1950 SODIUM NITRATE and POTASSIUM NITRATE mixture 5.1 1499 3 Colourless, hygroscopic solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Mixture prepared as a fertilizer. 1951 SODIUM NITRITE 5.1 1500 3 Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Decomposes if heated, giving off toxic nitrous fumes and gases supporti 1952 SODIUM PENTACHLOROPHENATE 6.1 2567 3 White or light brown powder with a pungent odour.Soluble in water.Toxic if swallowed,by skin contact or by inhalation. 1953 SODIUM PERCHLORATE 5.1 1502 2 Colourless crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are 1954 SODIUM PERMANGANATE 5.1 1503 2 Red crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensit 1955 SODIUM PEROXIDE 5.1 1504 2 Pale yellow coarse powder or granules. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxy 1956 SODIUM PEROXOBORATE ANHYDROUS 5.1 3247 2 Yellowish,odourless crystals.Soluble in water.Mixtures with combustible material are readily ignited and may burn fiercely.Harmful if swallowed. 1957 SODIUM PERSULPHATE 5.1 1505 3 Colourless deliquescent solid. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. 1958 SODIUM PHOSPHIDE 4.3 1432 2 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1959 SODIUM PICRAMATE dry or wetted with less than 15% water by mass 1.3C 0235 1 Substance. 1960 SODIUM PICRAMATE WETTED with not less than 20% water by mass 4.1 1349 2 Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compound with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed 1961 SODIUM SULPHIDE anhydrous or SODIUM SULPHIDE with less than 30% water of crytallization 4.2 1385 2 Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. React violently with acids. 1962 SODIUM SULPHIDE HYDRATED 8 1849 3 Yellow-pink or white deliquescent crystals, flakes or lumps. Melting point: 50'C. Soluble in water. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous m 1963 SODIUM SUPEROXIDE 5.1 2547 2 Pale yellow coarse powder or granules.Particularly if wetted with small quantities of water,a mixture with combustible material may ignite,following impact or friction.When involved in a fire,or in contact with water or acids,decomposes,evolving oxygen.Hig 1964 SOLID CONTAINING FLAMMABLE LIQUID, N.O.S. 4.1 3175 2 Mixtures of non-dangerous solids (such as soil,sand,production materials,etc.)and flammable liquids. 1965 SOLID CONTAINING TOXIC, LIQUID, N.O.S. 6.1 3243 2 Mixtures of non-dangerous solids(such as soil,sand,production materials,etc.)and toxic liquids.Toxic if swallowed,by skin contact or by inhaltion. 1966 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 8 3244 2 Mixtures of non-dangerous solids(such as soil,sand,production materials,etc.)and corrosive liquids.Cause burns to skin,eyes and mucous membranes. 1967 SOUNDING DEVICES EXPLOSIVE 1.1F 0296 1 NULL 1968 SOUNDING DEVICES EXPLOSIVE 1.1D 0374 1 NULL 1969 SOUNDING DEVICES EXPLOSIVE 1.2F 0204 1 NULL 1970 SOUNDING DEVICES EXPLOSIVES 1.2D 0375 1 NULL 1971 STANNIC CHLORIDE anhydrous 8 1827 3 Colourless liquid. In the presence of water, corrosive to most metals. Vapour irritates mucous membranes. 1972 STANNIC CHLORIDE PENTAHYDRATE 8 2440 3 White,deliquescent solid.Melting point:about 60oC.Soluble in water.In the presence of water,corrosive to most metals.Irritating to skin,eyes and mucous membranes. 1973 STANNIC PHOSPHIDES 4.3 1433 2 Silver-white solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalati 1974 STIBINE 2.3 2676 2 Flammable, toxic, colourless gas with a foul odour. Decomposes violently in the presence of water. Much heavier than air (4.3). 1975 STRONTIUM ARSENITE 6.1 1691 3 White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1976 STRONTIUM CHLORATE 5.1 1506 2 Colourless deliquescent solid. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are 1977 STRONTIUM NITRATE 5.1 1507 3 Colourless solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1978 STRONTIUM PERCHLORATE 5.1 1508 2 Colourless crystals or powder, soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are 1979 STRONTIUM PEROXIDE 5.1 1509 2 Colorless powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1980 STRONTIUM PHOSPHIDE 4.3 2013 2 Solid. React with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1981 STRYCHNINE or STRYCHNINE SALTS 6.1 1692 2 White crystals or powder. Strychnice is slightly soluble; the salts are soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1982 STYRENE MONOMER, STABILIZED 3 2055 3 f/p : 32oC c.c. Colourless, oily liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1983 SUBSTANCE, EXPLOSIVE, VERY INSENSITIVES, (SUBSTANCE, EVI) N.O.S. 1.5D 0482 1 NULL 1984 SUBSTANCES EXPLOSIVE N.O.S. 1.1L 0357 1 NULL 1985 SUBSTANCES EXPLOSIVE N.O.S. 1.2L 0358 1 NULL 1986 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3L 0359 1 NULL 1987 SUBSTANCES, EXPLOSIVE, N.O.S 1.1A 0473 1 NULL 1988 SUBSTANCES, EXPLOSIVE, N.O.S 1.1C 0474 1 NULL 1989 SUBSTANCES, EXPLOSIVE, N.O.S 1.3C 0477 1 NULL 1990 SUBSTANCES, EXPLOSIVE, N.O.S 1.4C 0479 2 NULL 1991 SUBSTANCES, EXPLOSIVE, N.O.S 1.1D 0475 1 NULL 1992 SUBSTANCES, EXPLOSIVE, N.O.S 1.4D 0480 1 1993 SUBSTANCES, EXPLOSIVE, N.O.S 1.1G 0476 1 NULL 1994 SUBSTANCES, EXPLOSIVE, N.O.S 1.3G 0478 1 NULL 1995 SUBSTANCES, EXPLOSIVE, N.O.S 1.4G 0485 2 NULL 1996 SUBSTANCES, EXPLOSIVE, N.O.S 1.4S 0481 2 NULL 1997 SUBSTITITED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 3014 3 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 1998 SUBSTITUTED NITROPHENOL PESTICIDES LIQUID, FLAMMABLE, TOXIC 3 2780 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 1999 SUBSTITUTED NITROPHENOL PESTICIDES, SOLID, TOXIC 6.1 2779 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2000 SUBSTITUTED NITROPHENOL PESTTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1 3013 2 Liquid flammable pesticides having a flashpoint between 23'C and 60'C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depends u 2001 SULPHAMIC ACID 8 2967 3 White crystalline powder. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. 2002 SULPHURIC ACID with more than 51% acid 8 1830 3 Colourless, oily liquid, mixture over 1.41 up to 1.84relative density. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2003 SULPHURIC ACID fuming 8 1831 2 Colourless, oily liquid, may be partly crystallized. Solution of varying quantities of sulphur acid. Reacts violently with water and organic material, generating heat. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by ski 2004 SULPHUR CHLORIDES 8 1828 2 Red liquids with a suffocating odour. Reacts violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Cuases burns to skin, eyes and mucous membranes 2005 SULPHUR DIOXIDE 2.3 1079 2 Non-flammable, toxic and corrosive gas with a pungent odour. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. 2006 SULPHUR 4.1 1350 3 When involved in a fire, evolves toxic, very irritating and suffocating gas. The dust forms an explosive mixture with air which may be ignited by static electricity. Forms explosive mixture with oxidizing substances. Corrosive to steel, in particular in th 2007 SULPHUR HEXAFLUORIDE 2.2 1080 3 Liquefied, non-flammable, odourless gas. Much heavier than air (5.1) 2008 SULPHUR,MOLTEN 4.1 2448 3 Melting point:119oC.Molten sulphur may contain hydrogen sulphide,Which is highly poisonous in low concentrations.When involved in a fire,evolvestoxic,very irritating and suffocating gas.Forms explosive and extremely sensiitive mixtures with oxidizing subst 2009 SULPHUR TETRAFLUORIDE 2.3 2418 2 Non-flammable,toxic and corrosive, colourless gas with a pungent odour.Reacts with water,moist air or acids to produce toxic and corrosive fumes.Corrosive to glass and to most metals.Much heavier than air (3.7).Highly irritating to skin,eyes and mucous me 2010 SULPHUR TRIOXDE,STABILIZED 8 1829 2 Very deliquescent solid. Melting point may be as low as 17'C. Reacts violently with water, generating heat. May cause fire in contact with organic materials such as wood, cotton and straw. In the presence of moisture, highly corrosive to most metals. Cause 2011 SULPHURIC ACID spent 8 1832 2 Sulphuric acid, usually of high concentration, which has been used for chemical processes. Highly corrosive to most metals. 2012 SULPHURIC ACID, with not more than 51 acid or BATTERY FLUID, ACID 8 2796 3 Colourless liquid, mixture not exceeding 1.405 relative density. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2013 SULPHUROUS ACID 8 1833 3 Solution of sulphur dioxide in water, with a suffocating odour. Corrosive to most metals. Vapour irritates mucous membranes. 2014 SULPHURYL CHLORIDE 8 1834 2 Colourless liquid with pungent odour. Boiling point 69'C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes severe burns to 2015 SULPHURYL FLUORIDE 2.3 2191 2 Non-flammable, toxic,colourless,odourless gas.Reacts with water or moist air (3.5).Irritating to skin, eyes and mucous membranes. 2016 TARS, LIQUID 3 1999 3 Mobile liquids prepared by mixing asphalt with petroleum distillate. Pungent odour. Immiscible with water. 2017 TEAR GAS CANDLES 6.1 1700 2 Devices containing tear-producing substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. 2018 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 1693 2 "Tear gas substance" is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic if swallowed, by skin contact or by inhalation. 2020 TELLURIUM COMPOUND, N.O.S. 6.1 3284 3 Toxic if swallowed,by skin contact or by inhalation. 2021 TELLURIUM HEXAFLOUORIDE 2.3 2195 2 Non-flammable, toxic and corrosive colourless gas with an unpleasant odour.Decomposes in water, evolving highly toxic and corrosive fumes.Corrosive to glass and to most metals.Much heavier than air (7.2).Highly irritating to skin, eyes and mucous membranes 2022 tert-BUTYL HYPOCHLORITE 4.2 3255 2 Volatile flammable slightly yellow liquid with a pungent odour.Immiscible with water.Boiling point:77oC to 79oC.Flashpoint between -15oC and -10oC.Exposure to light causes immediate dangerous decomposition.Causes burns to skin,eyes and mucous membranes. 2023 TERPENE HYDROCARBONS, N.O.S. 3 2319 3 Colourless or yellowish liquids.Flaspoint:32oC to 49oC c.c.Immiscible with water. 2024 TERPINOLENE 3 2541 3 Colourless to pale amber liquid with a lemon odour. Immiscible with water. Flash point : 37oC c.c. 2025 tert-BUTYL CYCLOHEXYLCHLOROFORMATE 6.1 2747 3 Colourless to yellowish liquid. Reacts with water or decomposes if heated, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 2026 tert-BUTYL ISOCYANATE 6.1 2484 2 Colourless liquid with a pungent odour.Immsicible with water but reacts violently with it,evolving gase.Flashpoint:11oC c.c.Highly toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 2027 TETRABROMOETHANE 6.1 2504 3 Colourless to yellowish liquid with a camphor-like odour.Toxic if swallowed,by skin contact or by inhalation. 2028 TETRACHLOROETHYLENE 6.1 1897 2 Colourless liquid with an ethereal odour. When involved in a fire, evolves extremely fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 2029 TETRAETHYLENEPENTAMINE 8 2320 2 Viscous liquid.Miscible with water.When involved in a fire,evolves toxic gases.Causes burns to skin,eyes and mucous membranes.Reacts violently with acids. 2030 TETRAETHYL DITHIOPHROPHOSPHATE 6.1 1704 2 Colourless liquid. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. 2031 TETRAETHYL SILICATE 3 1292 3 Colourless liquid. Immiscible with water. Flash point : 37oC c.c. Explosive limits : 1.3 to 23% 2032 TETRAFLOUROMETHANE COMPRESSED 2.2 1982 3 Non-flammable gas. Much heavier than air (3.1). 2033 TETRAFLUOROETHYLENE, STABILIZED 2.1 1081 2 Liquefied, flammable gas. Explosive limits: 11% to 60%. Much heavier than air (3.5). Irritating to skin,eyes and mucous membranes. 2034 TETRAHDROFURFURYLAMINE 3 2943 3 f/p : 45oC c.c. Colourless to yellowish liquid with an ammoniacal odour. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2035 TETRAHYDROFURAN 3 2056 2 f/p : < -18oC c.c. Colourless liquid with an ethereal odour. Miscible with water. 2036 TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride 8 2698 3 White crystalline powders. Reacts with water, evolving heat and forming tetrahydrophthalic acid. Cause burns to skin, eyes and mucous membranes. When heated, evolve acrid fumes which are irritating to skin, eyes and mucous membranes. 2037 TETRAHYDROTHIOPHENE 3 2412 3 f/p : 13oC c.c. Colourless liquid with a pleasant odour. Immiscible with water. 2038 TETRAMETHYLAMMONIUM HYDROXIDE, SOLUTION 8 1835 2 Miscible with water. Reacts violently with acids. 2039 TETRAMETHYLSILANE 3 2749 2 f/p : <-18oC c.c. Colourless, volatile liquid. Boiling point: 27°C. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 2040 TETRANITROANILINE 1.1D 0207 1 NULL 2041 TETRANITROMETHANE 5.1 1510 2 Colourless liquid with a pungent odour. Freezing point: 12.5'C. Insoluble in water. Mixtures with combustible material are readily ignited, burn fiercely and may also explode by friction or shock. Highly toxic if swallowed, by skin contact or by inhalation 2042 TETRAPROPYL ORTHOTITANATE 3 2413 3 f/p : 38oC c.c. Colourless liquid. 2043 TETRAZOL-1-ACETIC ACID 1.4C 0407 2 Substance. 2044 TEXTILE WASTE, WET 4.2 1857 3 Liable to ignite spontaneously in air according to moisture content. 2045 THALLIUM CHLORATE 5.1 2573 2 Colourless crystals.Slightly soluble in water.Reacts vigrously with sulphuric acid.Reacts fiercely with cyanides when heater or friction.May form explosive mixtures with combustible material,powdered metals or ammonium compounds.These mixtures are sensitiv 2046 THALLIUM COMPOUNDS N.O.S. 6.1 1707 2 White crystals or powder. Toxic if swallowed, by skin contact or by inhalation. 2047 THALLIUM NITRATE 6.1 2727 3 Colourless crystals. Soluble in water. Mixtures with combustible material are readily and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 2048 THIOACETIC ACID 3 2436 2 NULL 2049 THIOGLYCOL 6.1 2966 3 Colourless liquid with a foul odour. Miscible with water. Decomposes when heated, evolving sulphur dioxide. Toxic if swallowed, by skin contact or by inhalation. 2050 THIOGLYCOLIC ACID 8 1940 2 Colourless liquid with a strong, very unpleasant odour. Corrosive to most metals. Harmful if swallowed. 2051 THIOLACTIC ACID 6.1 2936 3 Oily liquid with a foul odour. Melting point: 10'C. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2052 THIONYL CHLORIDE 8 1836 2 Yellow or red liquid. Boiling point: 79'C. Reacts violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Cuases severe burns to skin, eyes and muco 2053 THIOPHENE 3 2414 3 f/p : -9oC c.c. Colourless liquid with an unpleasant odour. Immiscible with water. Irritating to skin, eyes and mucous membranes.Explosive limits:1.5% to 12.5%. 2054 THIOPHOSGENE 6.1 2474 3 Red fuming luquid with a foul phosgene-like odour.Decomposes slowly in water.Reacts with acids,evolving toxic and corrosive fumes.Highly toxic if swallowed,by skin contact or by inhalation. 2055 THIOPHOSPHORYL CHLORIDE 8 1837 3 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 2056 THIOUREA DIOXIDE 4.2 3341 2 White to yellow-white crystaline powder.Virtually odourless. Strong reducing agent. Violent exothermic decomposition above 100oC with emission of large amounts of sulphur oxides, ammonia, carbon monoxide, carbon dioxide, nitrogen oxides and hydrogen sulphi 2057 TINCTURES MEDICINAL 3 1293 3 Miscibility with water depends upon the composition. 2058 TITANIUM DISULPHIDE 4.2 3174 2 Yellow or grey powder with an unpleasant odour.In contact with water slowly evolves hydrogen sulphide gas. 2059 TITANIUM HYDRIDE 4.1 1871 2 Dark grey powder or crystals. 2060 TITANIUM POWDER, DRY 4.2 2546 2 Grey powder.Liable to ignite spontaneously in air.Forms explosive mixtures with oxidizing substances. 2061 TITANIUM POWDER WETTED 4.1 1352 3 Grey powder. Forms explosive mixture with oxidizing substances. 2062 TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS 4.1 2878 3 Silvery grey granules or dark grey, amorphous powder. May react with carbon dioxide, evolving oxygen. Forms explosive mixtures with oxidizing substances. 2063 TITANIUM TETRACHLORIDE 6.1 1838 2 Colourless liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. 2064 TITANIUM TRICHLORIDE MIXTURES 8 2869 2 Violet crystalline solid. Reacts in moist air or in water, evolving heat and hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2065 TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 4.2 2441 2 Finely divided,violet,crystalline solid.May ignite on exposure to air or mositure.In the presence of moisture,corrosive to most metals.Causes burns to skin,eyes and mucous membranes. 2066 TOLUENE 3 1294 2 f/p : 7oC c.c. Colourless liquid with a benzene-like odour. Immiscible with water. 2067 TOLUENE DIISOCYANATE 6.1 2078 2 Colourless to pale yellow liquid with a pungent odour.Immiscible with water but reacts with it to form carbon dioxide.Melting point:20'C (pure contact).Toxic if swallowed, by skin contact or by inhalation.Irritating to skin, eyes and mucous membranes. 2068 TOLUIDINES, LIQUID 6.1 1708 3 Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. 2070 TORPEDOES with bursting charge 1.1E 0329 1 NULL 2071 TORPEDOES with bursting charge 1.1F 0330 1 NULL 2072 TORPEDOES, LIQUID-FULLED with or without bursting charge 1.1J 0449 1 2073 TORPEDOES, LIQUID-FULLED, with inert head 1.3J 0450 1 2074 TORPEDOES, with bursting charge 1.1G 0451 1 NULL 2075 TOXIC LIQUID, CORROSIVE, INORGANIC N.O.S. 6.1 3289 2 Toxic if swallowed,by skin contact or by inhalation.Causes burns to skin,eyes and mucous membranes. 2076 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 3287 3 Toxic if swallowed,by skin contact or by inhalation. 2077 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 2927 2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2078 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 2929 2 Toxic if swallowed, by skin contact or by inhalation. 2079 TOXIC LIQUIDS, OXIDIZING, N.O.S. 6.1 3122 2 Toxic if swallowed, by skin contact or by inhalation. 2080 TOXIC LIQUIDS, WATER REACTIVES, N.O.S. 6.1 3123 2 Toxic if swallowed, by skin contact or by inhalation. 2081 TOXIC SOLID, INORGANIC, N.O.S. 6.1 3288 3 Toxic if swallowed,by skin contact or by inhalation. 2082 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 3290 2 Toxic if swallowed,by skin contact or by inhalation.Causes burns to skin,eyes and mucous membranes. 2083 TOXIC SOLID, WATER REACTIVE, N.O.S. 6.1 3125 2 Toxic if swallowed, by skin contact or by inhalation. 2084 TOXIC SOLIDS, SELF-HEATING, N.O.S. 6.1 3124 2 Toxic if swallowed, by skin contact or by inhalation. 2085 TOXIC, SOLID, OXIDIZING, N.O.S. 6.1 3086 2 Toxic if swallowed, by skin contact or by inhalation. 2086 TOXIC, SOLIDS, FLAMMABLE, ORGANIC, N.O.S. 6.1 2930 2 Toxic if swallowed, by skin contact or by inhalation. 2087 TOXICSOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 2928 2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2088 TOXINS EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 3172 2 Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in inflectious substances should be classified in class 6.2.Toxic if swallowed,by skin contact or by inhalation. 2090 TRACERS FOR AMMUNITION 1.3G 0212 1 NULL 2091 TRACERS FOR AMMUNITION 1.4G 0306 3 NULL 2092 TRIALLYL BORATE 6.1 2609 3 Liquid. Hydrolyses in contact with water, forming allyl alcohol.Toxic if swallowed, by skin contact or by inhalation. 2093 TRIALLYLAMINE 3 2610 3 f/p : 39oC c.c. Colourless liquid with a fishy odour. Corrosive when in contact with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2094 TRIAZINE PESTICIDES LIQUID, TOXIC 6.1 2998 3 See alphabetical index to identify those pesticides which are marine pollutants. Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2095 TRIAZINE PESTICIDES LIQUID, FLAMMABLE, TOXIC 3 2764 2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation 2096 TRIAZINE PESTICIDES LIQUID, TOXIC, FLAMMABLE 6.1 2997 2 NULL 2097 TRIAZINE PESTICIDES, SOLID, TOXIC 6.1 2763 3 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2098 TRIBUTHYLAMINE 6.1 2542 3 Colourless,combustible liquid with an amine odour.Immiscible with water.When involved in a fire,evolves toxic gases.Toxic if swallowed,by skin contact or by inhalation. 2099 TRIBUTYLPHOSPHANE 4.2 3254 2 Colourless yellowish liquid.Insoluble in water.Strong garlic odour (phosphine).Liable to heat and ignite spontaneously in air.If involved in a fire,evolves phosphine, a flammable and highly toxic gas.Reacts violently with oxidizing substances (peroxides,ha 2100 TRICHLOROACETIC ACID SOLID 8 1839 3 Colourless, deliquescent crystals. Melting point of the pure substance: 58'C. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2101 TRICHLOROACETIC ACIDS SOLUTION 8 2564 3 Colourless,clear solution with a pungent odour.Corrosive to most metals.Causes burns to skin,eyes and mucous membranes. 2102 TRICHLOROACETYL CHLORIDE 8 2442 3 Liquid with a pungent odour,which fumes in moist air,Reacts violently with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.When involved in a fire,evolves toxic gases.In the presence of moisture,corrosive to most metals.Liquid and 2103 TRICHLOROBENZENES, LIQUID 6.1 2321 3 Colourless liquids.Immiscible with water.Toxic if swallowed,by skin contact or by inhalation. 2104 TRICHLOROBUTENE 6.1 2322 2 Colourless liquid.Immiscible with water.When heated,develops toxic and irritant gases such as phosgene and hydrogen chloride and may also explode.Toxic if swallowed,by skin contact or by inhalation. 2105 TRICHLOROETHYLENE 6.1 1710 3 Colourless liquid with a chloroform-like odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 2106 TRICHLOROISOCYANURIC ACID, DRY 5.1 2468 2 Colourless powder granules.Mixtures with combustible material are sensitive to friction and are liable to ignite.On contact with nitrogen compounds,fumes of nitrogen trichloride can be formed,which are very explosive.Harmful by inhalation.Irritating to ski 2107 TRICHLOROSILANE 4.3 1295 2 Colourless,very volatile, flammable and corrosive liquid.Flaspoint:below -50c.Explosive limits:1.2% to 90.5%.Boiling point:32c.Reacts with water or steam to produce heat, which may lead to self-ignition; toxic and corrosive fumes will be evolved.May react 2108 TRICRESYL PHOSPHATE with more than 3% ortho isomer 6.1 2574 3 Colourless liquid.A mixture of isomers.Immiscible with water.Toxic if swallowed,by skin contact or by dust inhalation. 2109 TRIETHYL PHOSPHITE 3 2323 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 44oC c.c. 2110 TRIETHYLAMINE 3 1296 2 Colourless liquid with a strong ammonia-like odour. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : -11oC c.c. Explosive limits : 1.2 to 8% 2111 TRIETHYLENETETRAMINE 8 2259 3 Moderately viscous,yellow combustible liquid with an ammoniacal odour.Miscible with water.Strongly alkaline.Can form explosive mixtures with nitric acid.When involved in a fire,evolves toxic gases.Corrosive to copper and copper alloys.Reacts violently with 2112 TRIFLUOROACETIC ACID 8 2699 3 Colourless, fuming, hygroscopic liquid with a pungent odour. Miscible with water. When heated to decomposition or in contact with acids, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour are highly irritating to skin 2113 TRIFLUOROACETYL CHLORIDE 2.3 3057 2 Liquefied, non-flammable, toxic and corrosive gas. Reacts with water. Corrosive to glass and to most metals, including steel. Heavier than air (1.4 at 20'C). Highly irritating to skin, eyes and mucous membranes. 2114 TRIFLUOROCHLOROETHYLENE, STABILIZED 2.3 1082 2 Flammable, toxic, odourless gas. Explosive limits: 8.4% to 38.7%. Much heavier than air (4.0) 2115 TRIFLUOROMETHANE 2.2 1984 3 Liquefied, non-flammable gas. Much heavier than air (2.4). 2116 TRIFLUOROMETHANE REFRIGERATED LIQUID 2.2 3136 2 NULL 2117 TRIISOBUTYLENE 3 2324 3 Colourless liquid.Immiscible with water. 2118 TRIISOPROPYL BORATE 3 2616 3 Colourless liquid. Reacts with water, evolving flammable vapours. flash point : 17oC to 60oC c.c. 2119 TRIMETHYL BORATE 3 2416 2 Colourless liquid.Reacts with water,evolving flammable vapours. 2120 TRIMETHYL PHOSPHITE 3 2329 3 Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 23oC c.c. 2121 TRIMETHYLACETYL CHLORIDE 6.1 2438 2 Flammable liquid.Flashpoint:10oC c.c.Boiling point:108oC.Reacts with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.In the presence of moisture,corrosive to most metals.Highly toxic if swallowed,by skin contact or by inhalation.Ca 2122 TRIMETHYLAMINE ANHYDROUS 2.1 1083 2 Liquefied, flammable gas with a fishy odour. Explosive limits: 2% to 12%. Much heavier than air (2.1). Boiling point:3'C. 2123 TRIMETHYLAMINE AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 1297 3 Aqueous solution of a flammable gas with an ammonia-like odour.Flaspoint depending on percentage of dissolved gas.May react explosively with mercury.Miscible with water .An Aqueous solution of 45% TRIMETHYLAMINE,by mass,has a flashpoint of -45c c.c. and a 2124 TRIMETHYLCHLOROSILANE 3 1298 2 Colourless liquid. Boiling point: 57°C. Immiscible with water. Readily hydrolysed by moisture, evolving hydrogen chloride, a toxic and corrosive gas. Causes burns to skin, eyes and mucous membranes. flash point : <-18oC c.c. Explosive limits : 1.8 to 6% 2125 TRIMETHYLCYCLO HEXYLAMINE 8 2326 3 Colourless,slightly hygroscopic,combustible liquid with a slight amine odour.Immiscible with water.Causes burns to skin,eyes and mucous membranes. 2126 TRIMETHYLHEXAMETHYLENE DIISOCYANATE 6.1 2328 3 Colourless or yellowish liquid.Reacts with water,evolving carbon dioxide.Toxic if swallowed,by skin contact or by inhalation.Irritating to skin,eyes and mucous membranes. 2127 TRIMETHYLHEXAMETHYLENEDIAMINES 8 2327 3 Colourless,slightly hygroscopic,combustible liquids.Miscible with water.Irritating to skin,eyes and mucous membranes. 2128 TRINITROANILINE (PICRAMIDE) 1.1D 0153 1 Substance. 2129 TRINITROANISOLE 1.1D 0213 1 Substance. 2130 TRINITROBENZENE dry or wetted with less than 30% water, by mass 1.1D 0214 1 Substance. 2131 TRINITROBENZENE WETTED with not less than 30% water by mass 4.1 1354 2 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive compounds with heavy metals or thei 2132 TRINITROBENZENESULPHONIC ACID 1.1D 0386 1 Substance. 2133 TRINITROBENZOIC ACID dry or wetted with less than 30% water, by mass 1.1D 0215 1 Substance. 2134 TRINITROCHLOROBENZENE (PICRYL CHLORIDE) 1.1D 0155 1 Substance. 2135 TRINITROFLUORENONE 1.1D 0387 1 Substance. 2136 TRINITROLUENE WETED with not less than 30% water,by mass 4.1 1356 2 Desensitized explosive. Substance in pure form consists of white crystals. When involved in a fire, evolves toxic fumes; in closed compartment these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May for 2137 TRINITRO-meta-CRESOL 1.1D 0216 1 Substance. 2138 TRINITRONAPTHALENE 1.1D 0217 1 Substance. 2139 TRINITROPHENETOLE 1.1D 0218 1 Substance. 2140 TRINITROPHENOL (PICRIC ACID) 1.1D 0154 1 Substance. 2141 TRINITROPHENOL WETTED with not less than 30% water by mass 4.1 1344 2 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin con 2142 TRINITROPHENYLMETHYLNITRAMINE(TETRYL) 1.1D 0208 1 NULL 2143 TRINITRORESORCINOL(STYPHNIC ACID) dry or wetted with less than 20% water, or mixture alcohol and water, by mass 1.1D 0219 1 Substance. 2144 TRINITRORESORCINOL(STYPHNIC ACID)WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1D 0394 1 Substance. Mass detonating explosive. 2145 TRINITROTOLUENE (TNT) AND TRINITROBENBENZENE MIXTURE OR TRINOTROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE 1.1D 0388 1 Substance. 2146 TRINITROTOLUENE(TNT) 1.1D 0209 1 NULL 2147 TRINITROTOLUNE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE 1.1D 0389 1 Substance. 2148 TRINITTROBENZOIC ACID WETTED with not less than 30% water by mass 4.1 1355 2 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in th 2149 TRIPROPYLAMINE 3 2260 2 Colourless liquid. Partially miscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. Flash point : 35oC c.c. 2150 TRIPROPYLENE 3 2057 3 Colouless liquid.Immiscible with water. 2151 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 6.1 2501 3 Aqueous solution.Miscible with water.Toxic if swallowed,by skin contact or by inhalation. 2152 TRITONAL 1.1D 0390 1 Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium. 2153 TUNGSTEN HEXAFLUORIDE 2.3 2196 2 Non-flammable, toxic and corrosive colourless or yellow liquid.Decomposes in water or moist air, evolving highly toxic and corrosive fumes.Corrosive to glass and to most metals.Much heavier than air (10.3).Boiling point:19.5’C.Highly irritating to skin, ey 2154 TURPENTINE 3 1299 3 Colourless liquid. Mixture of resin and volatile oils. Immiscible with water. Flash point : 35oC c.c. 2155 TURPENTINE SUBSTITUTE 3 1300 3 Immiscible with water. 2156 UREA HYDROGEN PEROXIDE 5.1 1511 2 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitivee to friction and are liable to ignite. Irritating to skin, eyes and mucous membranes. 2157 UREA NITRATE dry or wetted with less than 20% water, by mass 1.1D 0220 1 Substance. 2158 UREA NITRATE WETTED with not less than 20% water by mass 4.1 1357 2 Desensitized explosive. Substance in pure form consists of white crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartment these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the 2159 VALERALDEHYDE 3 2058 3 Colourless liquid. Partially miscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 12oC c.c. 2160 VANADIUM OXYTRICHLORIDE 8 2443 3 Yellow liquid.Decomposition occurs on exposure to most air,forming red fumes of vanadic acid and hydrogen chloride, a corrosive gas apparent as white fumes.Reacts with or dissolves,many organic compounds.In the presence of moisture,corrosive to most metals 2161 VANADIUM COMPOUND, N.O.S. 6.1 3285 3 Toxic if swallowed,by skin contact or by inhalation. 2162 VANADIUM PENTOXIDE non-fused form 6.1 2862 2 Brownish powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2163 VANADIUM TETRACHLORIDE 8 2444 2 Reddish-brown liquid.Decomposes under the influence of light,evolving chloride,a highly toxic and irritating gas.Reacts violently with water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.In the presence of moisture,corrosive gas appare 2164 VANADIUM TRICHLORIDE 8 2475 3 Pink,deliquescent crystals.Decomposes in water,evolving hydrogen chloride,a corrosive gas apparent as white fumes.In the presence of moisture,highly corrosive to most metals.Irritating to skin,eyes and mucous membranes. 2165 VANADYL SULPHATE 6.1 2931 2 Blue, crystalline powder. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2166 VINYL ACETATE STABILIZED 3 1301 3 Colourless to light yellow liquid. Immiscible with water. Flash point : -8oC . Explosive limits : 2.6 to 14% 2167 VINYL BROMIDE, STABILIZED 2.1 1085 2 Liquefied, flammable gas. Much heavier than air (3.7). Boiling point: 16'C. 2168 VINYL BUTYRATE STABILIZED 3 2838 2 Colourless liquid with a pungent odour. Immiscible with water. Irritating to skin, eyes and mucous membranes. Flash point : 12oC c.c. Explosive limits : 1.4% to 8.8% 2169 VINYL CHLORIDE, STABILIZED 2.1 1086 2 Liquefied, flammable gas. Explosive limits: 4% to 31%. Much heavier than air (2.2). 2170 VINYL CHLOROACETATE 6.1 2589 2 Flammable liquid. Flashpoint: 50'C c.c. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2171 VINYL ETHYL ETHER STABILIZED 3 1302 2 Colourless liquid. Boiling point: 33°C. Immiscible with water. Extremely reactive; may polymerize. Flash point : <-18oC c.c. Explosive limits : 1.7 to 28% 2172 VINYL FLUORIDE STABILIZED 2.1 1860 2 Flammable gas. Explosive limits: 2.9% to 29%. Heavier than air (1.6). 2173 VINYL METHYL ETHER STABILIZED 2.1 1087 2 Liquefied, flammable gas. Explosive limits: 2.6% to 39%. Heavier than air (2.0). Boiling point: 6'C. 2174 VINYL TOLUENES, STABILIZED 3 2618 3 Colourless liquids. Partially miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Flash point : 54oC to 60oC 2175 VINYLIDENE CHLORIDE, STABILIZED 3 1303 2 Colourless to straw-coloured, volatile liquid with a sweet odour. Boiling point: 32°C. Immiscible with water. Flash point : -28oC c.c. Explosive limits : 6.5 to 15.5% 2176 VINYL ISOBUTYL ETHER, STABILIZED 3 1304 2 Colourless liquid. Immiscible with water. Flash point : -9oC c.c. 2177 VINYLPYRIDINES, STABILIZED 6.1 3073 2 Colourless to straw-coloured flammable liquids. Flashpoint: 42'C to 51'C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. React violently with acids. 2178 VINYLTRICHLOROSILANE STABILIZED 3 1305 3 Colourless, pale yellow or pink liquid with a pungent odour. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Immiscible with water. In the presence of moisture, corrosive to most metals. 2179 WARHEAD ROCKET with burster or expelling charge 1.4F 0371 2 NULL 2180 WARHEAD ROCKETS with bursting charge 1.1F 0369 1 NULL 2181 WARHEAD TORDEDO with bursting charge 1.1D 0221 1 NULL 2182 WARHEADS ROCKET with burster or expelling charge 1.4D 0370 2 NULL 2183 WARHEADS ROCKET with bursting charge 1.2D 0287 1 NULL 2184 WARHEADS ROCKETS with bursting charge 1.1D 0286 1 NULL 2185 WATER REACTIVE LIQUID, N.O.S. 4.3 3148 2 NULL 2186 WATER REACTIVE SOLID, N.O.S. 4.3 2813 2 NULL 2187 WATER-REACTIVE LIQUID, CORROSIVE N.O.S. 4.3 3129 2 NULL 2188 WATER-REACTIVE LIQUID, TOXIC N.O.S. 4.3 3130 2 NULL 2189 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 3132 2 NULL 2190 WATER-REACTIVE SOLID,CORROSIVE N.O.S. 4.3 3131 2 NULL 2191 WATER-REACTIVE SOLID, TOXIC, N.O.S 4.3 3134 2 NULL 2192 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 4.3 3133 2 NULL 2193 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 3135 2 NULL 2194 WOOD PRESERVATIVES LIQUID 3 1306 3 Miscibility with water depends upon the composition.Harmful by inhalation. 2195 WOOL WASTE, WET 4.2 1387 3 Liable to ignite spontaneously in air according to moisture content. 2196 XANTHATES 4.2 3342 2 Hygroscopic yellow powder with an unpleasant odour. On contact with moisture, evolves highly flammable vapours such as carbon disulphide (UN 1131, which has a flashpoint of -30oC c.c. and a very low ignition temperature of 100oC). When confine, can cause a 2197 XENON 2.2 2036 3 Liquefied,inert gas.Much heavier than air (4.5). 2198 XENON REFRIGERATED LIQUID 2.2 2591 3 Liqusfied, inert, colourless and odourless gas. Much heavier than air (4.5). 2199 XYLENES 3 1307 3 Colourless liquids. Immiscible with water. Flash point : 17 to 23oC c.c. m-xylene , flash point : 25-29.4oC c.c. o-xylene , flash point : 17-46.1oc c.c. p-xylene, flash point : 25-27oC c.c. 2201 XYLENOLS, SOLID 6.1 2261 3 Crystals or needles.Toxic if swallowed,by skin contact or by inhalation. 2202 XYLIDINES, LIQUID 6.1 1711 3 Toxic if swallowed, by skin contact or by inhalation. 2204 XYLYL BROMIDE LIQUID 6.1 1701 3 Colourless liquid, evolving irritating vapour ("Teas Gas"). Toxic if swallowed, by skin contact or by inhalation. 2205 ZINC ARSENATE or ZINC ARSENITE or ZINC ARSENATE, ZINC ARSENITE MIXTURE 6.1 1712 2 Crystalline solid. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2206 ZINC AMMONIUM NITRITE 5.1 1512 2 Transport od prohibited. 2207 ZINC ASHES 4.3 1435 2 In contact with moisture or water, liable to evolve dangerous gases, including hydrogen, a flammable gas. 2208 ZINC BROMATE 5.1 2469 3 Colourless powder.Soluble in water.Reacts vigorously with sulphuric acid.Reacts fiercely with cyanides when heated or by friction.May form explosive mixtures are sensitive to friction and are liable to ignite.When involved in a fire,may cause and explosion 2209 ZINC CHLORATE 5.1 1513 2 Colourless or yellowish crystals. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures 2210 ZINC CHLORIDE, ANHYDROUS 8 2331 2 White,deliquescent crystals.Soluble in waterDust causes burns to skin,eyes and mucous membranes. 2211 ZINC CHLORIDE, SOLUTION 8 1840 2 Colourless liquid. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2212 ZINC CYANIDE 6.1 1713 2 White crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanides, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 2213 ZINC DITHIONITE 9 1931 3 White, amorphous solid material. Soluble in water. Liable to heat on contact with moisture and heating results in evolution of sulphur dioxide, an intensely irritating gas. Also evolves sulphur dioxide on contact with acids. 2214 ZINC FLUOROSILICATE 6.1 2855 3 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2215 ZINC NITRATE 5.1 1514 2 Colourless solid. Soluble in water. Melting point: 36'C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 2216 ZINC PERMANGANATE 5.1 1515 2 Violet-brown or black crystals or powder. Soluble in water. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These m 2217 ZINC PEROXIDE 5.1 1516 2 White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction.When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 2218 ZINC PHOSPHIDE 4.3 1714 2 Grey crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. 2219 ZINC POWDER or ZINC DUST 4.3 1436 2 In contact with water, alkalis or acids, evolves hydrogen, a flammable gas. Zinc dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. 2220 ZINC RESINATE 4.1 2714 3 Powder or clear amber lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 2221 ZIRCONIUM, DRY 4.1 2858 3 Hard silvery metal. 2222 ZIRCONIUM HYDRIDE 4.1 1437 2 Black coloured powder. 2223 ZIRCONIUM NITRATE 5.1 2728 3 White crystals, flakes or powder. Soluble in water. Solutions in water are slightly corrosive. Harmful if swallowed. 2224 ZIRCONIUM PICRAMATE WETTED with not less than 20% water by mas 4.1 1517 2 Desensitized explosive. Highly explosive in the dry state or if insufficiently wetted. May react violently in contact with heavy metals or their salts. 2225 ZIRCONIUM PICRAMATE dry or wetted with less than 20% water by mass 1.3C 0236 1 Substance. 2226 ZIRCONIUM POWDER DRY 4.2 2008 2 Amorphous powder. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. 2227 ZIRCONIUM POWDER, WETTED 4.1 1358 2 Grey powder. Insoluble in water. Liable to spontaneous combustion when dry. Form explosive mixture with oxidizing substances. 2228 ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID 3 1308 2 Finely divided zirconium metal in a flammable liquid.Immiscible with water.Spillage is liable to self-ignition. 2229 ZIRCONIUM TETRACHLORIDE 8 2503 3 White,lustrous crystals.Reacts with water,evolving hydorgen chloride,a corrosive gas apparent as white fumes.In the presence of moisture,corrosive to most metals.Irritating to mucous membranes. 2230 ZIRCONIUM, dry finished sheet strip or coiled wire 4.2 2009 2 Hard, silvery metal, liable to ignite spontaneously in air. 2231 ZIRCONIUM, SCRAP 4.2 1932 2 Particle size larger than 840 microns. Readily flammable; may ignite spontaneously in air. In contact with water, may evolve hydrogen, a flammable gas. 2238 SODIUM PERBORATE MONOHYRATE 5.1 3377 2 White crystals or powder. Partially soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Risk of decomposition when exposed to continous heat (exothermic decomposition 60oC ). When involved in a fire or exposed to 2239 SODIUM CARBONATE PEROXYHYRATE 5.1 3378 2 White crystals or powder. Partially soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Risk of decomposition when exposed to continous heat (exothermic decomposition 60oC ). When involved in a fire or exposed to 2240 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S 6.1 3379 2 Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. 2241 DESENSITIZED EXPLOSIVE, SOLID, N.O.S 4.1 3380 2 Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. 2242 TOXIC BY INHALATION LIQUID, N.O.S with an inhalation toxicity lower than or equal to 200 ml/m3 saturated vapour consentration vapour greater than or equal to 500 LC50 6.1 3381 2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 2243 TOXIC BY INHALATION LIQUID, N.O.S with an inhalation toxicity lower than or equal to 1000 ml/m3 saturated vapour consentration vapour greater than or equal to 10 LC50 6.1 3382 2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 2244 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S with an inhalation toxicity lower than or equal to 200 ml/m3 saturated vapour consentration greater than or equal to 500 LC50 6.1 3383 2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 2245 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal 10 LC50 6.1 3384 2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 2246 TOXIC BY INHALATION LIQUID,WATER REACTIVE, N.O.S with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 3385 2 A variety of toxic liquids which present a significant toxic inhalation hazard as well as being water-reactive.Highly toxic by inhalation, if swallowed or by skin contact 2247 TOXIC BY INHALATION LIQUID, WATER REACTIVE, N.O.S with an inhalation toxicity lower than or equal to 1000 ml/m3 saturated vapour consentration greater than or equal to 10 LC50 6.1 3386 2 A variety of toxic liquids which present a significant toxic inhalation hazard as well as being water-reactive.Highly toxic by inhalation, if swallowed or by skin contact 2248 TOXIC BY INHALATION LIQUID, OXIDING, N.O.S with an inhalation toxicity lower than or equal to 200 ml/m3 saturated vapour consentration greater than or equal to 500 LC50 6.1 3387 2 A variety of toxic liquids which present a significant toxic inhalataion hazard as well as being an oxidizer .Highly Toxic by inhalation, if swallowed or by skin contact or by inhalation. 2249 TOXIC BY INHALATION LIQUID,OXIDING, N.O.S with an inhalation toxicity lower than or equal to 1000 ml/m3 saturated vapour consentration greater than or equal to 10 LC50 6.1 3388 2 A variety of toxic liquids which present a significant toxic inhalataion hazard as well as being an oxidizer .Highly Toxic by inhalation, if swallowed or by skin contact or by inhalation. 2250 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S with an inhalation toxicity lower than or equal to 200 ml/m3 satured vapour consentration greater than or equal to 500 LC50 6.1 3389 2 A variety of toxic liquids which present a significant toxic inhalation hazard as well as being corrosive. Highly toxic by inhalation. Toxic if swallowed or by skin contact 2251 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S with an inhalation toxicity lower than or equal to 1000 ml/m3 saturated vapour consentration greater than or equal to 10 LC50 6.1 3390 2 A variety of toxic liquids which present a significant toxic inhalataion hazard as well as being an corrosive. Highly Toxic by inhalation, if swallowed or by skin contact or by inhalation. 2252 ORGANOMETALLIC SUBSTANCE, SOLID PYROPHORIC 4.2 3391 2 Liable to ignite spontaneously in air. If shaken, may produce sparks. 2253 ORGANOMETALLIC SUBSTANCE, LIQUID PYROPHORIC 4.2 3392 2 Highly flammable liquid. Liable to ignite spontaneously contact with air, evolve irritating and slightly toxic fumes. 2254 ORGANOMETALLIC SUBSTANCE, SOLID PYROPHORIC, WATER, REACTIVE 4.2 3393 2 Liable to ignite spontaneously in air. If shaken, may produce sparks.React violently with moisture, water and acids, evolving flammable gas. 2255 ORGANOMETALLIC SUBSTANCE, LIQUID PYROPHORIC, WATER, REACTIVE 4.2 3394 2 Highly flammable liquid. Liable to ignite spontaneously contact with air, evolve irritating and slightly toxic fumes. React violently with moisture, water and acids, evolving flammable gas 2256 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE 4.3 3395 2 React violently with moisture, water and acids, evolving flammable gas 2257 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE, FLAMMABLE 4.3 3396 2 Flammable solid. Reacts violently with moisture, water and acids, evolving flammable gas. 2258 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE, SELF HEATING 4.3 3397 2 Liable to self-heating or spontaneous combustion. Reacts violently with moisture, water and acids evolving flammable gas 2259 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER REACTIVE 4.3 3398 2 React violently with moisture, water and acids, evolving flammable gas 2260 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER REACTIVE, FLAMMABLE 4.3 3399 2 Flammable solid. Reacts violently with moisture, water and acids, evolving flammable gas. 2261 ORGANOMETALLIC SUBSTANCE, SOLID, SELF HEATING 4.2 3400 2 Liable to self-heating or spontaneous combustion. 2262 ALKALI METAL AMALGAM, SOLID 4.3 3401 2 Silvery solid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. 2263 ALKALINE EARTH METAL AMALGAM, SOLID 4.3 3402 2 Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals & may contain up to 98% mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapors 2264 POTASSIUM METAL ALLOYS, SOLID 4.3 3403 2 Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes withexplosive effect. 2265 POTASSIUM SODIUM ALLOYS, SOLID 4.3 3404 2 Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes withexplosive effect. 2266 BARIUM CHLORATE SOLUTION 5.1 3405 2 Colourless aqueous solution. Reats vigrously with sulphuric acid. Reacts fircely with cyanides when heated. May form explosive mixtures with combustible material, material, powdered matals or ammonium compounds. These mixtures are liable to ignite. When in 2267 BARIUM PERCHLORATE SOLUTION 5.1 3406 2 Reats vigrously with sulphuric acid. Reacts fircely with cyanides when heated. May form explosive mixtures with combustible material, material, powdered matals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause a 2268 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 5.1 3407 2 Reats vigrously with sulphuric acid. Reacts fircely with cyanides when heated. May form explosive mixtures with combustible material, material, powdered matals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause 2269 LEAD PERCHLORATE SOLUTION 5.1 3408 3 Reats vigrously with sulphuric acid. Reacts fircely with cyanides when heated. May form explosive mixtures with combustible material, material, powdered matals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause a 2270 CHLORONITROBENZENES, LIQUID 6.1 3409 2 Yellow liquid. Toxic if swallowed, by skin contact or by inhalation. 2271 4-CHLORO-o-TOLUIDDINE HYROCHLORIDE SOLUTION 6.1 3410 3 Toxic if swallowed, by skin contact or by inhalation. 2272 beta-NAPHTHYLAMINE SOLUTION 6.1 3411 3 Toxic if swallowed, by skin contact or by inhalation. 2273 POTASSIUM CYANIDE SOLUTION 6.1 3413 3 Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. 2274 SODIUM CYNIDE SOLUTION 6.1 3413 3 NULL 2275 SODIUM FLOURIDE SOLUTION 6.1 3415 3 Colourless liquid. Reacts with acids , evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 2276 CHLOROACETOPHENONE, LIQUID 6.1 3416 2 Liquid evolving irritating vapour ('Tear Gas'). Toxic if swallowed, by skin contact or by inhalation. 2277 XYLYL BROMIDE, SOLID 6.1 3417 3 Crystals or powder, evolving irritating vapour ('Tear Gas'). Toxic if swallowed, by skin contact or by inhalation. 2278 2,4-TOLUYLENEDIAMINE SOLUTION 6.1 3418 3 Toxic if swallowed, by skin contact or by inalation. 2279 BORON TRIFLOURIDE ACETIC ACID COMPLEX, SOLID 8 3419 2 White crystaline solid. Melting point: 23oC. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2280 BORON TRIFLOURIDE PROPIONIC ACID COMPLEX, SOLID 8 3420 2 White crystaline solid. Melting point: 28oC. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2281 POTASSIUM HYROGEN DIFLOURIDE SOLUTION 8 3421 3 Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin 2282 POTASSIUM FLOURIDE SOLUTION 6.1 3422 3 Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. 2283 TETRAMETHYLAMMONIUM HYROXIDE, SOLID 8 3423 2 Very soluble in water. Reacts violently with acids. 2284 AMMONIUM DINITRO-o-CRESOLATE SOLUTION 6.1 3424 2 The commercial product is a 50% suspension in water. May support combustion and burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals and their componds. Tox 2285 BROMOACETIC ACID, SOLUTION 6.1 3425 3 Colourless, deliquescent crystals. Melting point: 51oC. Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. 2286 ACRYLAMIDE SOLUTION 6.1 3426 3 Toxic if swallowed, by skin contact or by inhalation. 2287 CHLOROBENZYL CHLORIDES, SOLID 6.1 3427 3 Colourless crystaline solid. Melting point:29oC. Immisible with insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2288 3-CHLORO-4-METHYLPHENYLISOCYANATE, SOLID 6.1 3427 3 NULL 2289 CHLOROTOLUIDNIDES, LIQUID 6.1 3429 3 Brown liquid. Toxic if swallowed, by skin contact or by inhalation. 2290 XYLENOLS, LIQUID 6.1 3430 2 The commercial products are liquids with a pungent tar odour. Toxic if swallowed, by skin contact or by inhalation. 2291 NITROBENZOTRIFLOURIDES, SOLID 6.1 3431 2 Low melting point (31oC TO 32oC) Solids with an aromatic odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2292 POLYCHLORINATED BIPHENYLS, SOLID 9 3432 3 Solids with perceptible odour. Insoluble in water. Harmful by ingestion or by skin contact. If spilled, can be a persistent hazard to the environment. This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polychlorina 2294 NITROCRESOLS, LIQUID 6.1 3434 3 Slighty miscible in water. Toxic if swallowed, by skin contact or by inhalation. 2296 HEXAFLOUROACETONE HYRATE, SOLID 6.1 3436 2 This entry covers solid hydrate and hexafluoroacetone. Melting point of the pure substance:23oC. Toxic if swallowed, by skin contact or by inhalation. 2297 CHLOROCRESOLS, SOLID 6.1 3437 2 White or pink crystals with a phenol-like odour. Melting point:45oC TO 68oC. Slightly soluble in water. Decomposes when heated. evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 2298 alpha-METHYLBENZYL ALCOHOL, SOLID 6.1 3438 3 Slightly soluble in water. Melting point:21oC (pure substance). Toxic if swallowed, by skin contact or by inhalation. 2299 NITRILES, TOXIC, SOLID, N.O.S 6.1 3439 3 NULL 2300 SELENIUM COMPOUND, LIQUID, N.O.S 6.1 3440 3 Toxic if swallowed, by skin contact or by inhalation. 2301 CHLORODINITROBENZENES, SOLID 6.1 3441 2 Crystals. Melting point:27oC to 53oC. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 2302 DICHLOROANILINES, SOLID 6.1 3442 2 Solid with a penetrating odour. Liquid mixtures of varios isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24oC TO 72oC. Toxic if swallowed, by skin contact or by inhalation. 2303 DINITROBENZENES, SOLID 6.1 3443 2 May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 2304 NICOTINE HYDROCHLORIDE, SOLID 6.1 3444 3 Deliquescent crystals or solids or pastes. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2305 NICOTINE SULPHATE, SOLID 6.1 3445 3 Solid or paste. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2306 NITROTOLUENES, SOLID 6.1 3446 3 Yellow solid. Melting point: para-NITROLUENE:52oC TO 54oC. Toxic if swallowed, by skin contact or by inhalation. 2307 NITROXYLENES, SOLID 6.1 3447 3 Yellow solid. Melting points: 4-NITRO-2_XYLENE:29oC TO 31oC, 5-NITRO-3-XYLENE:72oC to 74oC. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2308 TEAR GAS SUBSTANCE, SOLID, N.O.S 6.1 3448 2 'Tear gas substance' is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic of swallowed, by skin contact or by inhalation. 2309 BROMOBENZYL CYANIDES, SOLID 6.1 3449 2 Volatile, yellow crystals evolving irritating vapours ('Tear Gas'). Melting point:meta-BROMOBENZYL CYANIDE 25oC . Highly toxic if swallowed, by skin contact or by inhalation. 2310 DIPHENYLCHLOROARSINE, SOLID 6.1 3450 2 When pure, volatile, colourless crystals evolving an irritating vapour ('Tear Gas'). Melting point: 41oC. Highly toxic if swallowed, by skin contact or by inhalation. 2311 TOLUIDINES, SOLID 6.1 3451 3 para-TOLUIDINE is solid in pure form, with a melting point of approximately 45oC. Toxic if swallowed, by skin contact or by inhalation. 2312 XYLIDINES, SOLID 6.1 3452 3 3,4- Dimethylaniline is a solid, which has a melting point of 47oC. Toxic if swallowed, by skin contact or by dust inhalation. 2313 PHOSPHORIC ACID, SOLID 8 3453 3 Very deliquescent, crystalline solid. Melting point: 42oC. Soluble in water. Midly corrosive to most metals. 2314 DINITROTOLUENES, SOLID 6.1 3454 2 Yellow crystals or flakes, insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2315 CRESOLS, SOLID 6.1 3455 3 Light yellow solid. Soluble in water. Melting points of CRESOLS: ortho-CRESOL:30oC, para-CRESOL:35oC. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2316 NITROSYLSULPHURIC ACID, SOLID 8 3456 3 Crystalline solid. Oxidant which may cause fire with organic materials (such as wood, straw ,etc.). When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2317 CHLORONITROTOLUENES, SOLID 6.1 3457 3 Melting range 20oC to 40oC. Insoluble in water. Oxidizing substance which may explode or burn fiercely when in contact with organic materials. Toxic if swallowed, by skin contact or by inhalation. 2318 NITROANISOLES, SOLID 6.1 3458 3 Light reddish or amber crystals. Melting points:38oC to 54oC. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2319 NITROBROMOBENZENES, SOLID 6.1 3459 3 Colourless to pale yellow crystals which may liquefy under transport conditions. Melting points: 1-BROMO-2-NITROBENZENE:43oC. 1-BROMO-4-NITROBENZENE:127oC. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2320 N-ETHYLBENZYLTOLUIDINES, SOLID 6.1 3460 3 Solid which may liquefy under transport conditions. Strong odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhaltion. 2322 TOXINS EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S 6.1 3462 2 Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in infectious substances should be classified in class 6.2. Toxic if swallowed, by skin contact or by inhalation. 2323 ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S 6.1 3464 3 Toxic if swallowed, by skin contact or by inhalation. 2324 ORGANOARSENIC COMPOUND, SOLID, N.O.S 6.1 3465 2 Toxic if swallowed, by skin contact or by inhalation. 2325 METAL CARBONYLS, SOLID, N.O.S 6.1 3466 3 Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2326 ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S 6.1 3467 2 Toxic if swallowed, by skin contact or by inhalation. 2327 HYDROGEN IN A METAL HYRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT 2.1 3468 2 Article containing flammable odourless gas,which is much lighter than air. 2328 SODIUM CYANIDE SOLUTION 6.1 3414 3 Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. 2329 3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID 6.1 3428 2 Colourless solid with a pungent odour. Melting point 23oC. Insoluble in water. React with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2330 1,4-CYCLOHEXANEDIMETHANOL 9 3257* 3 NULL 2331 PAINT (including paint,lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 8 3066 3 Corrosive content. Causes burns to skin, eyes and mucous membranes. 2332 BIOLOGICAL SUBSTANCE, CATEGORY B 6.2 3373 2 Substances which are known or are reasonably expected to contain pathogens, transported in a form that, when exposure to it occurs, are not capable of causing permanent disability, life-threatening or fatal disease to humans or animals. Human or animal spe 2333 FORMIC ACID with not less than 10% but not more than 85% acid by mass 8 3412 2 Colourless liquid with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes 2334 PROPIONINC ACID with not less than 90% by mass 8 3463 2 Colourless flammable liquid with a pungent odour. Miscible with water.Corrosive to lead and most other metals. Burns skin. Vapours irritate mucous membranes. Pure PROPIONIC ACID: flashpoint 50oC c.c. 2335 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 3 3469 3 Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes 2336 PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE, (including paint thinning or reducing compound) 8 3470 2 Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes 2337 HYDROGENDIFLUORIDES SOLUTION, N.O.S 8 3471 2 When involved in a fire or in contacts with acids, evolves hydrogen fluoride an extremely irritating and corrosive gas. Corrosive to glass, other siliceous materials and most metals. Toxic if swallowed by skin contact or by inhalation. Cause burns to skin, 2338 CROTONIC ACID, LIQUID 8 3472 2 Causes burns to skins, eyes and mucous membranes 2339 FUEL CELL CARTRIDGES OR FUEL CELL CARTRIDES CONTAINED IN EQUIPMENT or FULL CELL CARTRIDGES PACKED containing flammable liquids 3 3473 2 Fuel cell cartridges containing flammable liquids including methanol or methanol/water solutions. Fuel cell cartridges may also be shipped in, or packed with equipment. 2340 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 9 3480 3 Electrical batteries containing lithium ion encased in a rigid metallic body. Lithium ion batteries may also be shpped in, or packed with, equipment. Electrical lithium batteries cause fire due to an explosive rupture of the body caused by improper contruc 2341 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUUIPMENT (including lithium ion polymer batteries) 9 3481 3 Electrical batteries containing lithium ion encased in a rigid metallic body. Lithium ion batteries may also be shpped in, or packed with, equipment. Electrical lithium batteries cause fire due to an explosive rupture of the body caused by improper contruc 2342 FORMIC ACID with not less than 5% but less than 10% acid by mass 8 3412 3 Colourless liquid with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes 2343 NULL NULL NULL NULL test 2344 AMMONIUM BROMATE (transportation prohibited) NULL NULL NULL NULL 2345 AMMONIUM BROMATE, SOLUTION (transportation prohibited) NULL NULL NULL NULL 2346 AMMONIUM CHLORATE (transportation prohibited) NULL NULL NULL NULL 2347 AMMONIUM CHLORATE, SOLUTION (transportation prohibited) NULL NULL NULL NULL 2348 AMMONIUM CHLORITE (transportation prohibited) NULL NULL NULL NULL 2349 AMMONIUM HYPOCHLORITE (transportation probihited) NULL NULL NULL NULL 2350 AMMONIUM NITRATE liable to self-heating sufficient to initiate a decomposition (transportation prohibited) NULL NULL NULL NULL 2351 AMMONIUM NITRITES AND MIXTURES of an inorganic nitrite with an ammonium salt (transportation prohibited) NULL NULL NULL NULL 2352 AMMONIUM PERMANGANATE (transportation prohibited) NULL NULL NULL NULL 2353 AMMONIUM PERMANGANATE, SOLUTION (transportation probihited) NULL NULL NULL NULL 2354 CHLORIC ACID AQUEOUS SOLUTION with a concentration exceeding 10% (transportation prohibited) NULL NULL NULL NULL 2355 ETHYL NITRITE pure (transportation prohibited) NULL NULL NULL NULL 2356 HYDROCYANIC ACID with more than 20% acid, by mass (transportation prohibited) NULL NULL NULL NULL 2357 HYDROGEN CHLORIDE, REFRIGERATED LIQUID (transportation prohibited) NULL NULL NULL NULL 2358 HYDROGEN CHLORIDE, SOLUTION with more than 45% Hydrogen Cyanide (transportation prohibited) NULL NULL NULL NULL 2359 MERCURY OXYCYANIDE pure (transportation prohibited) NULL NULL NULL NULL 2360 METHYL NITRITE (transportation prohibited) NULL NULL NULL NULL 2361 PERCHLORIC ACID with more than 72% acid, by mass (transportration prohibited) NULL NULL NULL NULL 2362 SILVER PICRATE, DRY OR WETTED with less than 30% water by mass (transportation prohibited) NULL NULL NULL NULL 2363 ZINK AMMONIUM NITRITE (transportation prohibited) NULL NULL NULL NULL 2366 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL intermediate for blasting explosives 5.1 3375 2 Non-sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. Substances shall satisfactorily pass test series 8 of 2367 FLAMMABLE LIQUID N.O.S (KEROFLUID ES 5N) 3 1993 3 FLASH POINT : >55oc , LOWER EXPLOSION LIMIT :0.20%(V) , UPPER EXPLOSION LIMIT :3.40%(V) IGNITION TEMPERATURE:>200oC 2368 FLAMMABLE LIQUID N.O.S (HEAVY AROMATIC) 3 1993 3 FLASH POINT : 58oC 2369 PETROLEUM DISTILLATES OR PETROLEUM PRODUCT N.O.S (RECYCLE FUEL OIL) 3 1268 3 FLASH POINT : 66oC , Flammability limits : LEL : 0.5 % v/v; UEL : 5.0 % v/v ,Auto ignition temperature : 250 °C Approx 2370 DI-n-PROPYL ETHER 3 2384 2 Colourless liquid. Immiscible with water. Flash point(pure product) : -21oC c.c Explosive limits : 1.7% to .... 2371 ENGINE,INTERNAL COMBUSTION or VEHICLE,FLAMMABLE GAS POWERED or VEHICLE,FLAMMABLE LIQ POWERED or ENGINE, FUEL CELL,FLAMMABLE GAS POWERED or ENGINE,FUEL CELL, FLAMMABLE LIQ POWERED or VEHICLE, FUEL CELL, FLAMMABLE LIQ POWERED 9 3166 3 Types of articles transported under this entry include, internal combustion engines, compression/ignition engines, fuel cell powered engines, motor vehicles, hybrid vehicles, motorcycles and boats 2373 FLAMMABLE LIQUID N.O.S 3 1993 3 Packing Group is III and flash point is more than 22oC 3373 BATTERIES, NICKEL-METAL HYDRIDE 9 3496 3 Nickel- metal hydriode cells or batteries packed with or contained in equipment and nickel-metal hydride button cells are not subject to the provisions of this Code. 3374 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted 8 3507 2 3375 CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3 Wh) 9 3508 3 Articles intended to store energy containing positive and negative electrodes comprised of different materials and an electrolyte. Asymetric capacitors may be transported in a charged state. 3376 ADSORBED GAS, FLAMMABLE, N.O.S 2.1 3510 2 - 3377 ADSORBED GAS, N.O.S 2.2 3511 3 - 3378 ADSORBED GAS, TOXIC, N.O.S 2.3 3512 2 - 3379 ADSORBED GAS, OXIDISING, N.O.S 2.2 3513 2 - 3380 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S 2.3 3514 2 - 3381 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S 2.3 3515 2 - 3382 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S 2.3 3516 2 - 3383 ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S 2.3 3517 2 - 3384 ADSORBED GAS,TOXIC,OXIDIZING, CORROSIVE, N.O.S 2.3 3518 2 - 3385 BORON TRIFLUORIDE, ADSORBED 2.3 3519 2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass 3386 CHLORINE, ADSORBED 2.3 3520 2 Non-flammable, toxic and corrosive yellow gas with pungent odour. Corrosive to glass and to most metals. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. 3387 SILICON TETRAFLUORIDE, ADSORBED 2.3 3521 2 Non-flammable, toxic and corrosive gas with pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. 3388 ARSINE, ADSORBED 2.3 3522 2 Flammable, toxic, colourless gas with a garlic odour. Explosive limits: 3.9% to 77.8%. Much heavier than air (2.8). 3389 GERMANE, ADSORBED 2.3 3523 2 Flammable, toxic, colourless gas with a pungent odour. Much heavier than air (2.6). 3390 PHOSPHORUS PENTAFLUORIDE, ADSORBED 2.3 3524 2 Non-flammable, toxic and corrosive gas with an irritating odour. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. 3391 PHOSPHINE, ADSORBED 2.3 3525 2 Flammable, toxic, colourless gas with a garlic odour. Ignites spontaneously in air. Heavier than air. Irritating to skin, eyes and mucous membranes. 3392 HYDROGEN SELENIDE, ADSORBED 2.3 3526 2 Flammable, toxic, colourless gas with a disagreeable odour. Much heavier than air (2.8). Highly irritating to skin, eyes and mucous membranes. 3393 KRILL MEAL 4.2 3497 1 Pink to red meal derived from Krill which is a shrimp-like marine organism. Medium odour, which may affect other sensitive cargo. Liable to self heating. Naturally rich in anti-oxidants, which lessen the risks of spontaneous heating. 3394 IODINE MONOCHLORIDE, LIQUID 8 3498 2 Red Liquid. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant: may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to mos 3395 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3 Wh) 9 3499 2 Articles intended to store energy containing a non-dangerous activated carbon and an electrolyte. Electric double layer capacitors installed in equipment may be transported in a charged state. 3396 CHEMICAL UNDER PRESSURE, N.O.S. 2.2 3500 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3397 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S 2.1 3501 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3398 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. 2.2 3503 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3399 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. 2.2 3502 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3400 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. 2.1 3504 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3401 CHEMICAL UNDER PRESSURE, FLAAMMABLE, CORROSIVE, N.O.S. 2.1 3505 2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3402 MERCURY CONTAINED IN MANUFACTURED ARTICLES 8 3506 2 Articles containing mercury (UN 2809). Carriage should be prohibited in hovercraft and other ships constructed with aluminium. 3403 POLYESTER RESIN KIT, SOLID BASE MATERIAL 4.1 3527 2 Polyester resin kit consist if two components: a base material (flammable solid) and an activator (organic peroxide), each separately packed in inner packaging 3404 ENGINE, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or ENGINE, FUEL CELL, FLAMMABLE LIQUID POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or MACHINERY, FUEL CELL, FLAMMABLE LIQUID POWERED 3 3528 2 Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion system or fuel cell (e.g. combustion engines, generators, compressor, turbines, heating unit, etc.) 3405 ENGINE, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or ENGINE, FUEL CELL, FLAMMABLE GAS POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or MACHINERY, FUEL CELL, FLAMMABLE GAS POWERED 2.1 3529 2 Types of article transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cells (e.g. combustion engines, generators, compressors, turbines, heating units, etc) 3406 ENGINE, INTERNAL COMBUSTION or MACHINERY, INTERNAL COMBUSTION 9 3530 3 Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cell (e.g. combustion engines, generators, compressors, turbines, heating units, etc.) 3407 POLYMERIZING SUBSTANCE, SOLID, STABILIZED, N.O.S 4.1 3531 3 Polymerizes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. 3408 POLYMERIZING SUBSTANCE, LIQUID, STABILIZED, N.O.S 4.1 3532 3 Polymerizes at elevated temperatures or in a fire. Burns vigorously. Immisible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. 3410 POLYMERIZING SUBSTANCE, SOLID, TEMPERATURE CONTROLLED, N.O.S 4.1 3533 3 Polymerizes at temperatures higher than the self- accelerating polymerization temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangeous polymerization. The products of combustion or self-accelerating p 3411 POLYMERIZING SUBSTANCE, LIQUID, TEMPERATURE CONTROLLED, N.O.S 4.1 3534 3 Polymerizes at temperatures higher than the self- accelerating polymerization temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerati 3412 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1.4S 0500 1 Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be the instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included. 3413 SIGNALS, DISTRESS, ship 1.4G 0505 1 Articles containing pyrotechnic substances designed to produce signals by means of sound, flame, or smoke or any combinations thereof. 3414 SAFETY DEVICES, PYROTECHNIC 1.4G 0503 1 3415 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 1.3C 0508 1 Substance. 3416 ROCKET MOTORS #6 1.4C 0510 1 Articles consisting of a solid, liquid or hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missiles. 3418 testing kama 3 1932 1 testing 4418 Testing 1.0 3159 1 testing 4425 TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S 6.1 3535 2 Toxic if swallowed, by skin contact or by dust inhalation. 4426 TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S 6.1 3535 3 Toxic if swallowed, by skin contact or by dust inhalation 4427 LITHIUM BATTERIES INSTALLED IN CARGO TRANSPORT UNIT lithium ion batteries or lithium metal batteries 9 3536 3 Cargo transport unit containing lithium metal or lithium ion batteries which is designed to serve as mobile power support unit. 4428 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S 2.1 353 2 - 4429 ARTICLES CONTAINING NON-FLAMMABLE, NON TOXIC GAS, N.O.S 2.2 3538 2 - 4430 ARTICLES CONTAINING TOXIC GAS, N.O.S 2.3 3539 2 - 4431 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S 3 3540 2 - 4432 ARTICLES CONTAINING FLAMMABLE SOLID, N.O.S 4.1 3541 2 - 4433 ARTICLES CONTAINING A SUBSTANCE LIABLE TO SPONTANEOUS COMBUSTION, N.O.S 4.2 3542 2 *F-G, S-M for pyrophoric substances, F-A, S-J for self heating substances. 4434 ARTICLES CONTAINING A SUBSTANCE WHICH EMITS FLAMMABLE GAS IN CONTACT WITH WATER, N.O.S 4.3 3543 2 - 4435 ARTICLES CONTAINING OXIDIZING SUBSTANCE, N.O.S 5.1 3544 2 - 4436 ARTICLES CONTAINING ORGANIC PEROXIDE, N.O.S 5.2 3545 2 - 4437 ARTICLES CONTAINING TOXIC SUBSTANCE, N.O.S 6.1 3546 2 Toxic if swallowed, by skin contact or by dust inhalation. *When competent authority approval is required by SP391, the stowage and handling will be specified by the competent authority. 4438 ARTICLES CONTAINING CORROSIVE SUBSTANCE, N.O.S 8 3547 3 Causes burn to skin, eyes and mucous membranes. 4439 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS GOODS, N.O.S 9 3548 3 - 4448 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS GOODS,N.O.S. 9 3548 3 - 4449 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2.3 2186 2 Transport is prohibited. 4450 LITHIUM HYDRIDE 4.3 1414 2 Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 4451 HEXAMETHHYLENEDIAMINE SOLUTION 8 1783 2 Colourless liquid. Causes burns to skin, eyes and mucous membranes. 4452 CALCIUM OXIDE 8 1910 2 Not subject to the provisions of this Code but may be subject to provision governing the transport of dangerous goods by other modes. 4453 1,2-DIBROMOBUTAN-3-ONE 6.1 2648 2 Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes tears. 4454 BATTERY-POWERED VEHICLLE or BATTERY-POWERED EQUIPMENT 9 3171 2 Types of articles transported under this entry include vehicles or equipment powered by wet batteries,sodium batteries or lithium batteries with the batteries installed,such as electrically-powered cars,lawnmowers,whellchairs and other mobility aids. 4455 AVIATION REGULATED LIQUID, N.O.S. 9 3334 2 Not subject to the provisions of this Code but may be subject to provisons govering the transport of dangerous goods by other modes. 4456 AVIATION REGULATED LIQUID, N.O.S. 9 3335 2 Not subject to the provisions of this Code but may be subject to provisons govering the transport of dangerous goods by other modes. 4457 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 6.1 3361 1 Colourless to yellow liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence o 4458 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 3362 2 Colourless to yellow liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence o 4459 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 10% water, by mass 4.1 3364 2 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin con 4460 TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10% water, by mass 4.1 3365 1 Desensitized explosive. Explosive and sensitive to shock and heat in the dry state. Reacts violently with heavy metals and their salts. 4461 TRINITROTOLUENE (TNT), WETTED with not less than 10% water, by mass 4.1 3366 2 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Reacts violently 4462 TRINITROBENZENE, WETTED with not less than 10% water, by mass 4.1 3367 2 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Reacts violently 4463 TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass 4.1 3368 2 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Reacts violently 4464 SODIUM DINITRO-o- CRESOLATE,WETTED with not less than 10% water, by mass 4.1 3369 2 Desensitized explosive. Substance in pure form consists of yellow powder. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixtu 4465 UREA NITRATE, WETTED with not less than 10% water,by mass 4.1 3370 2 Desensitized explosive. May form extremely sensitive compounds with heavy metals or their salts .Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. 4466 2-METHYLBUTANAL 4.1 3370 2 Colourless liquid. Flashpoint:-3.5oC. Explosive limits:1.3 to 13.9%. Slighly miscible with water. 4467 ACETYLENE, SOLVENT FREE 2.1 3374 2 Flammable gas with slight odour. Explosive limits:2.1 to 80%. Lighter than air (0.907). Acetylene without solvent. Rough handling and exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders shoul 4468 4-NIROPHENYLHYDRAZINE, with not less than 30% water, by mass 4.1 3376 2 Desenaitized explosive. Dark orange solid. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 4469 1-HYDROXYBENZOTRIAZOLE MONOHYDRATE 4.1 3474 2 Desensitized explosive. White to light beige powder. Explosive and sensitive to friction in the dry state. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. May form extremely sensitive 4470 ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol 3 3475 2 Colourless, volatile liquids. Miscibility with water depends on the composition. 4471 FULL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FULL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances 4.3 3476 2 Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. 4472 FULL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FULL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances 8 3477 2 Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. 4473 FULL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FULL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 2.1 3478 2 Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. 4474 FULL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FULL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride 2.1 3479 1 Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. 4475 ALKALI METAL DISPERSION, FLAMMABLE or ALKALINE EARTH METAL DISPERSION, FLAMMABLE 4.3 3482 2 Finely divided alkali or alkaline earth metal suspended in a flammable liquid. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 4476 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE 6.1 3483 1 Volatile flammable liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble with water. Highly toxic if swallowed, by skin contact or by inhalation. 4477 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass 8 3484 2 Colourless flammable liquid. Powerful reducing agent, burns readily. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 4478 CALCIUM HYPOCHLORITE DRY, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chloride (8.8% available oxygen) 5.1 3485 2 White or yellowish corrosive solid (powder, granules or tablets) with chloride- like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. 4479 CALCIUM HYPOCHLORITE MIXTURE, DRY , CORROSIVE with more than 10% but not more than 39% available chloride 5.1 3486 2 White or yellowish corrosive solid (powder, granules or tablets) with chloride- like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. 4480 CALCIUM HYPOCHLORITE HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 3487 2 White or yellowish corrosive solid (powder, granules or tablets) with chloride- like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. 4481 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equel to 200 mL50/m3 and saturated vapour concentration greater than or equel to 500LC50 6.1 3488 2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 4482 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equel to 1000 mL50/m3 and saturated vapour concentration greater than or equel to 10LC50 6.1 3489 2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 4483 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equel to 200 mL50/m3 and saturated vapour concentration greater than or equel to 500LC50 6.1 3490 2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 4484 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equel to 1000mL50/m3 and saturated vapour concentration greater than or equel to 10LC50 6.1 3491 2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 4485 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3 3494 2 Immiscible with water. Evolves hydrogen sulphide, which is a flammable, toxic gas with a foul odour, heavier than air (1.2). Toxic if swallowed, by skin contact or by inhalation. 4486 IODINE 8 3495 2 Bluish-black solid with a metallic lusture and a pungent odour. Melting point: 114oC Below its melting point, may evolve vapours which are irritating to skin, eyes and mucous membranes. Slightly soluble in water but soluble in most organic solvents. Corros 4487 PACKAGINGS, DISCARGED, EMPTY , UNCLEANED 9 3509 2 This entry shall not be used for sea transport. Discarded packaging shall meet the requirement of 4.1.1.11. Discarded packaging means packagings, large packagings or intermediate bulk container (IBC), or parts thereof, which have contained dangerous goods, 4488 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. 9 3537 2 - 4489 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. 9 3537 2 - 4490 SIGNALS, DISTRESS, ship 1 0506 2 (2379 rows affected)
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